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| Sep 14 • 11:00 | Elena Rybakina |  | - |  | Ekaterina Alexandrova | 2 | : | 0 |
| Sep 14 • 11:00 | Anastasia Pavlyuchenkova | | - |  | Shuai Zhang | 2 | : | 1 |
| Sep 14 • 12:30 | Amanda Anisimova |  | - |  | Donna Vekic | 2 | : | 0 |
| Sep 14 • 12:30 | Marie Bouzkova |  | - |  | Ajla Tomljanović | 2 | : | 0 |
| Sep 14 • 13:30 | Barbora Strýcová | | - | | Veronika Kudermetova | 2 | : | 0 |
| Sep 14 • 14:00 | Magda Linette |  | - |  | Jeļena Ostapenko | 2 | : | 0 |
| Sep 14 • 14:30 | Anastasija Sevastova | | - |  | Jasmine Paolini | 0 | : | 2 |
| Sep 14 • 15:00 | Anna Blinkova | | - |  | Jil Belen Teichmann | 2 | : | 0 |
| Sep 14 • 16:30 | Alison Riske-Amritraj | | - |  | Aliona Bolsova | 1 | : | 2 |
| Sep 14 • 16:45 | Su-Wei Hsieh |  | - |  | Elise Mertens | 0 | : | 2 |
| Sep 14 • 17:15 | Julia Görges |  | - |  | Danka Kovinić | 0 | : | 2 |
| Sep 14 • 19:00 | Camila Giorgi | | - |  | Dayana Yastremska | 1 | : | 2 |
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| Sep 15 • 11:00 | Kateřina Siniaková | | - | | Angelique Kerber | 2 | : | 0 |
| Sep 15 • 11:00 | Misaki Doi |  | - | | Markéta Vondroušová | 1 | : | 2 |
| Sep 15 • 11:45 | Iga Świątek | | - |  | Arantxa Rus | 0 | : | 2 |
| Sep 15 • 12:30 | Elisabetta Cocciaretto | | - |  | Irina-Camelia Begu | 0 | : | 2 |
| Sep 15 • 12:30 | Kaja Juvan |  | - | | Polona Hercog | 1 | : | 2 |
| Sep 15 • 14:00 | Anett Kontaveit |  | - |  | Caroline Garcia | 2 | : | 0 |
| Sep 15 • 14:00 | Bernarda Pera | | - | | Svetlana Kuznetsova | 1 | : | 2 |
| Sep 15 • 14:30 | Yulia Putintseva | | - |  | Rebecca Peterson | 2 | : | 0 |
| Sep 15 • 15:30 | Daria Kasatkina | | - | | Vera Zvonareva | 2 | : | 0 |
| Sep 15 • 15:30 | Ons Jabeur |  | - | | Cori Gauff | 0 | : | 2 |
| Sep 15 • 19:10 | Garbine Muguruza | | - | | Sloane Stephens | 2 | : | 0 |
| Sep 16 • 14:00 | Victoria Azarenka |  | - | | Venus Williams | 2 | : | 0 |
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| Sep 16 • 11:00 | Belinda Bencic | | - | | Danka Kovinić | 0 | : | 2 |
| Sep 16 • 11:00 | Magda Linette | | - | | Elise Mertens | 0 | : | 2 |
| Sep 16 • 12:30 | Simona Halep | | - | | Jasmine Paolini | 2 | : | 0 |
| Sep 16 • 12:30 | Aliona Bolsova | | - | | Anna Blinkova | 1 | : | 2 |
| Sep 16 • 14:00 | Dayana Yastremska | | - | | Amanda Anisimova | 2 | : | 1 |
| Sep 16 • 14:00 | Elena Rybakina | | - | | Marie Bouzkova | 2 | : | 0 |
| Sep 16 • 19:00 | Barbora Strýcová | | - | | Karolina Pliskova | 0 | : | 2 |
| Sep 16 • 20:30 | Anastasia Pavlyuchenkova | | - | | Elina Svitolina | 0 | : | 2 |
| Sep 17 • 11:00 | Daria Kasatkina | | - | | Kateřina Siniaková | 2 | : | 0 |
| Sep 17 • 11:00 | Anett Kontaveit | | - | | Svetlana Kuznetsova | 1 | : | 2 |
| Sep 17 • 12:30 | Yulia Putintseva | | - | | Petra Martic | 2 | : | 1 |
| Sep 17 • 12:30 | Garbine Muguruza | | - | | Cori Gauff | 2 | : | 1 |
| Sep 17 • 12:30 | Arantxa Rus | | - | | Markéta Vondroušová | 0 | : | 2 |
| Sep 17 • 15:30 | Irina-Camelia Begu | | - |  | Johanna Konta | 0 | : | 2 |
| Sep 17 • 18:15 | Kiki Bertens | | - | | Polona Hercog | 0 | : | 2 |
| Sep 17 • 19:00 | Sofia Kenin | | - | | Victoria Azarenka | 0 | : | 2 |
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| Sep 18 • 11:00 | Danka Kovinić | | - | | Elise Mertens | 0 | : | 2 |
| Sep 18 • 11:00 | Anna Blinkova | | - | | Karolina Pliskova | 0 | : | 2 |
| Sep 18 • 12:30 | Elena Rybakina | | - | | Yulia Putintseva | 1 | : | 2 |
| Sep 18 • 13:00 | Simona Halep | | - | | Dayana Yastremska | 2 | : | 0 |
| Sep 18 • 14:00 | Garbine Muguruza | | - | | Johanna Konta | 2 | : | 0 |
| Sep 18 • 15:30 | Victoria Azarenka | | - | | Daria Kasatkina | 0 | : | 0 |
| Sep 18 • 19:00 | Svetlana Kuznetsova | | - | | Elina Svitolina | 0 | : | 2 |
| Sep 18 • 20:30 | Polona Hercog | | - | | Markéta Vondroušová | 1 | : | 2 |
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| Sep 19 • 12:00 | Simona Halep | | - | | Yulia Putintseva | 1 | : | 0 |
| Sep 19 • 14:00 | Victoria Azarenka | | - | | Garbine Muguruza | 1 | : | 2 |
| Sep 19 • 15:30 | Markéta Vondroušová | | - | | Elina Svitolina | 2 | : | 0 |
| Sep 19 • 19:00 | Elise Mertens | | - | | Karolina Pliskova | 1 | : | 2 |
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| Sep 20 • 12:00 | Simona Halep | | - | | Garbine Muguruza | 2 | : | 1 |
| Sep 20 • 16:00 | Markéta Vondroušová | | - | | Karolina Pliskova | 0 | : | 2 |
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| Sep 21 • 14:30 | Simona Halep | | - | | Karolina Pliskova | 1 | : | 0 |
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