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| Oct 26 • 14:00 | Borna Ćorić |  | - |  | Taylor Harry Fritz | 2 | : | 0 |
| Oct 26 • 14:00 | Dennis Novak |  | - |  | Kevin Anderson | 1 | : | 2 |
| Oct 26 • 15:45 | Gaël Monfils |  | - |  | Pablo Carreño Busta | 0 | : | 1 |
| Oct 26 • 18:15 | Andrey Rublev |  | - |  | Norbert Gombos | 2 | : | 0 |
| Oct 26 • 19:30 | Jurij Rodionov | | - |  | Denis Shapovalov | 2 | : | 0 |
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| Oct 27 • 14:00 | Grigor Dimitrov |  | - | | Karen Khachanov | 2 | : | 0 |
| Oct 27 • 14:30 | Hubert Hurkacz |  | - |  | Attila Balazs | 2 | : | 0 |
| Oct 27 • 15:30 | Novak Djokovic |  | - | | Filip Krajinović | 2 | : | 0 |
| Oct 27 • 16:00 | Aljaž Bedene |  | - |  | Daniel Evans | 0 | : | 1 |
| Oct 27 • 17:30 | Dušan Lajović | | - |  | Lorenzo Sonego | 0 | : | 2 |
| Oct 27 • 17:30 | Vitaliy Sachko |  | - | | Dominic Thiem | 0 | : | 2 |
| Oct 27 • 19:00 | Cristian Garín |  | - |  | Stanislas Wawrinka | 2 | : | 1 |
| Oct 28 • 14:00 | Jason Jung |  | - | | Daniil Medvedev | 0 | : | 2 |
| Oct 28 • 14:30 | Casper Ruud |  | - | | Jannik Sinner | 0 | : | 2 |
| Oct 28 • 15:30 | Stefanos Tsitsipas |  | - |  | Jan-Lennard Struff | 2 | : | 1 |
| Oct 28 • 16:00 | Felix Auger Aliassime | | - | | Vasek Pospisil | 0 | : | 2 |
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| Oct 28 • 17:45 | Novak Djokovic | | - | | Borna Ćorić | 2 | : | 0 |
| Oct 28 • 19:15 | Pablo Carreño Busta | | - | | Kevin Anderson | 0 | : | 2 |
| Oct 29 • 14:00 | Daniel Evans | | - | | Jurij Rodionov | 2 | : | 0 |
| Oct 29 • 14:30 | Hubert Hurkacz | | - | | Lorenzo Sonego | 0 | : | 2 |
| Oct 29 • 15:30 | Vasek Pospisil | | - | | Daniil Medvedev | 1 | : | 2 |
| Oct 29 • 16:00 | Andrey Rublev | | - | | Jannik Sinner | 0 | : | 0 |
| Oct 29 • 17:30 | Cristian Garín | | - | | Dominic Thiem | 0 | : | 2 |
| Oct 29 • 19:00 | Stefanos Tsitsipas | | - | | Grigor Dimitrov | 1 | : | 2 |
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| Oct 30 • 14:00 | Kevin Anderson | | - | | Daniil Medvedev | 2 | : | 0 |
| Oct 30 • 15:30 | Andrey Rublev | | - | | Dominic Thiem | 2 | : | 0 |
| Oct 30 • 17:30 | Novak Djokovic | | - | | Lorenzo Sonego | 0 | : | 2 |
| Oct 30 • 19:30 | Grigor Dimitrov | | - | | Daniel Evans | 1 | : | 2 |
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| Oct 31 • 14:00 | Kevin Anderson | | - | | Andrey Rublev | 0 | : | 1 |
| Oct 31 • 15:30 | Lorenzo Sonego | | - | | Daniel Evans | 2 | : | 0 |
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| Nov 01 • 14:00 | Lorenzo Sonego | | - | | Andrey Rublev | 0 | : | 2 |
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