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| Aug 26 • 17:00 | Jan Choinski |  | - |  | Roberto Carballés Baena | 2 | : | 3 |
| Aug 26 • 17:00 | Shang Juncheng |  | - |  | Alexander Bublik | 3 | : | 2 |
| Aug 26 • 17:00 | Ugo Humbert |  | - |  | Thiago Moura Monteiro | 3 | : | 0 |
| Aug 26 • 17:00 | Dominic Stricker |  | - |  | Francisco Comesana | 1 | : | 3 |
| Aug 26 • 17:00 | Maximilian Marterer |  | - | | Alexander Zverev | 1 | : | 3 |
| Aug 26 • 17:00 | Hugo Grenier | | - |  | Mitchell Krueger | 1 | : | 3 |
| Aug 26 • 17:00 | Luca Nardi |  | - | | Roberto Bautista-Agut | 0 | : | 3 |
| Aug 26 • 18:00 | Ben Shelton | | - |  | Dominic Thiem | 3 | : | 0 |
| Aug 26 • 18:15 | Casper Ruud |  | - | | Bu Yunchaokete | 3 | : | 0 |
| Aug 26 • 18:15 | Albert Ramos-Viñolas | | - | | Matteo Berrettini | 0 | : | 3 |
| Aug 26 • 18:15 | Alexei Popyrin |  | - |  | Kwon Soon-woo | 3 | : | 0 |
| Aug 26 • 19:30 | Pedro Martínez | | - |  | Maks Kaśnikowski | 3 | : | 2 |
| Aug 26 • 19:45 | Camilo Ugo Carabelli | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Aug 26 • 19:45 | Alexandre Muller | | - | | Adam Walton | 3 | : | 1 |
| Aug 26 • 19:45 | Andrey Rublev |  | - | | Thiago Seyboth Wild | 3 | : | 0 |
| Aug 26 • 19:45 | Márton Fucsovics |  | - |  | Jiří Lehečka | 1 | : | 2 |
| Aug 26 • 20:15 | Reilly Opelka | | - | | Lorenzo Musetti | 1 | : | 3 |
| Aug 26 • 20:15 | Christopher Eubanks | | - | | Arthur Rinderknech | 2 | : | 3 |
| Aug 26 • 20:15 | Rinky Hijikata | | - | | Alejandro Davidovich Fokina | 3 | : | 1 |
| Aug 26 • 20:15 | Kyrian Jacquet | | - |  | Grigor Dimitrov | 0 | : | 3 |
| Aug 26 • 20:15 | Alexander Shevchenko | | - | | Dominik Koepfer | 3 | : | 1 |
| Aug 26 • 20:45 | Yoshihito Nishioka |  | - |  | Miomir Kecmanovic | 2 | : | 2 |
| Aug 26 • 21:00 | Francisco Cerundolo | | - | | Sebastian Ofner | 3 | : | 1 |
| Aug 26 • 21:15 | Gaël Monfils | | - | | Diego Schwartzman | 3 | : | 1 |
| Aug 26 • 21:15 | Giovanni Mpetshi Perricard | | - | | Tomás Martín Etcheverry | 0 | : | 3 |
| Aug 26 • 21:30 | Arthur Cazaux | | - | | Pablo Carreño Busta | 3 | : | 0 |
| Aug 26 • 21:30 | Sebastián Báez | | - | | Luciano Darderi | 3 | : | 1 |
| Aug 26 • 21:30 | Sumit Nagal |  | - |  | Tallon Griekspoor | 0 | : | 3 |
| Aug 26 • 21:30 | Laslo Djere | | - | | Jan-Lennard Struff | 3 | : | 2 |
| Aug 26 • 23:00 | Holger Rune |  | - | | Brandon Nakashima | 0 | : | 3 |
| Aug 27 • 01:00 | Aleksandar Kovacevic | | - | | Frances Tiafoe | 1 | : | 3 |
| Aug 27 • 02:15 | Radu Albot |  | - | | Novak Djokovic | 0 | : | 3 |
| Aug 27 • 17:00 | Stefanos Tsitsipas |  | - | | Thanasi Kokkinakis | 1 | : | 3 |
| Aug 27 • 17:00 | Tristan Schoolkate | | - | | Taro Daniel | 3 | : | 2 |
| Aug 27 • 17:00 | Jakub Mensik | | - |  | Felix Auger Aliassime | 3 | : | 0 |
| Aug 27 • 17:00 | Alejandro Tabilo |  | - |  | David Goffin | 0 | : | 3 |
| Aug 27 • 17:00 | Mariano Navone | | - | | Daniel Altmaier | 3 | : | 1 |
| Aug 27 • 17:00 | Constant Lestienne | | - | | Jordan Thompson | 0 | : | 3 |
| Aug 27 • 17:00 | Timofey Skatov | | - | | Hubert Hurkacz | 0 | : | 3 |
| Aug 27 • 18:15 | Eliot Spizzirri | | - | | Alex Michelsen | 0 | : | 3 |
| Aug 27 • 18:15 | Borna Ćorić |  | - | | Adrian Mannarino | 0 | : | 3 |
| Aug 27 • 18:15 | Fabio Fognini | | - | | Tomáš Macháč | 0 | : | 3 |
| Aug 27 • 18:15 | Otto Virtanen |  | - | | Quentin Halys | 3 | : | 1 |
| Aug 27 • 18:15 | Daniel Evans | | - | | Karen Khachanov | 3 | : | 2 |
| Aug 27 • 19:00 | Zhang Zhizhen | | - | | Jack Draper | 0 | : | 2 |
| Aug 27 • 19:55 | Jannik Sinner | | - | | Mackenzie McDonald | 3 | : | 1 |
| Aug 27 • 20:00 | Matthew Forbes | | - | | Roman Safiullin | 0 | : | 3 |
| Aug 27 • 20:15 | Arthur Fils | | - | | Learner Tien | 3 | : | 1 |
| Aug 27 • 20:15 | Max Purcell | | - | | Aleksandar Vukic | 3 | : | 0 |
| Aug 27 • 20:15 | Denis Shapovalov | | - | | Botic van de Zandschulp | 0 | : | 3 |
| Aug 27 • 20:15 | Facundo Díaz Acosta | | - | | Hugo Gaston | 3 | : | 0 |
| Aug 27 • 20:15 | Corentin Moutet | | - | | Sebastian Korda | 0 | : | 3 |
| Aug 27 • 20:15 | Matteo Arnaldi | | - | | Zachary Svajda | 3 | : | 0 |
| Aug 27 • 20:30 | Nuno Borges |  | - | | Federico Coria | 3 | : | 0 |
| Aug 27 • 21:15 | Dušan Lajović | | - | | Daniil Medvedev | 1 | : | 3 |
| Aug 27 • 21:15 | Alex De Minaur | | - | | Marcos Giron | 3 | : | 1 |
| Aug 27 • 21:30 | Christopher O'Connell | | - | | Nicolás Jarry | 3 | : | 1 |
| Aug 27 • 21:30 | Jaume Munar | | - | | Gabriel Diallo | 1 | : | 3 |
| Aug 27 • 21:30 | Flavio Cobolli | | - | | James Duckworth | 3 | : | 1 |
| Aug 27 • 21:30 | Zizou Bergs | | - | | Pavel Kotov | 3 | : | 2 |
| Aug 27 • 21:30 | Fábián Marozsán | | - | | Hamad Medjedovic | 3 | : | 2 |
| Aug 27 • 23:00 | Mattia Bellucci | | - | | Stanislas Wawrinka | 3 | : | 0 |
| Aug 28 • 01:00 | Carlos Alcaraz | | - | | Li Tu | 3 | : | 1 |
| Aug 28 • 02:15 | Lorenzo Sonego | | - | | Tommy Paul | 1 | : | 3 |
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| Aug 28 • 17:00 | Francisco Cerundolo | | - | | Tomás Martín Etcheverry | 2 | : | 3 |
| Aug 28 • 17:00 | Mitchell Krueger | | - | | Jiří Lehečka | 2 | : | 3 |
| Aug 28 • 17:00 | Rinky Hijikata | | - | | Grigor Dimitrov | 0 | : | 3 |
| Aug 28 • 18:15 | Brandon Nakashima | | - | | Arthur Cazaux | 3 | : | 0 |
| Aug 28 • 18:15 | Alexandre Muller | | - | | Alexander Zverev | 0 | : | 3 |
| Aug 28 • 18:15 | Sebastián Báez | | - | | Tallon Griekspoor | 0 | : | 1 |
| Aug 28 • 19:00 | Andrey Rublev | | - | | Arthur Rinderknech | 3 | : | 2 |
| Aug 28 • 19:15 | Alexander Shevchenko | | - | | Frances Tiafoe | 0 | : | 2 |
| Aug 28 • 19:30 | Roberto Carballés Baena | | - | | Shang Juncheng | 0 | : | 3 |
| Aug 28 • 19:30 | Ben Shelton | | - | | Roberto Bautista-Agut | 3 | : | 0 |
| Aug 28 • 20:15 | Ugo Humbert | | - | | Francisco Comesana | 1 | : | 3 |
| Aug 28 • 20:15 | Miomir Kecmanovic | | - | | Lorenzo Musetti | 2 | : | 3 |
| Aug 28 • 20:15 | Alexei Popyrin | | - | | Pedro Martínez | 3 | : | 0 |
| Aug 28 • 23:00 | Casper Ruud | | - | | Gaël Monfils | 3 | : | 1 |
| Aug 29 • 02:15 | Matteo Berrettini | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Aug 29 • 02:15 | Laslo Djere | | - | | Novak Djokovic | 0 | : | 2 |
| Aug 29 • 17:00 | Mattia Bellucci | | - | | Christopher O'Connell | 1 | : | 3 |
| Aug 29 • 17:00 | Tomáš Macháč | | - | | Sebastian Korda | 3 | : | 0 |
| Aug 29 • 17:00 | Matteo Arnaldi | | - | | Roman Safiullin | 3 | : | 0 |
| Aug 29 • 17:00 | Jordan Thompson | | - | | Hubert Hurkacz | 3 | : | 0 |
| Aug 29 • 18:00 | Jannik Sinner | | - | | Alex Michelsen | 3 | : | 0 |
| Aug 29 • 18:30 | Thanasi Kokkinakis | | - | | Nuno Borges | 0 | : | 3 |
| Aug 29 • 20:00 | Flavio Cobolli | | - | | Zizou Bergs | 3 | : | 1 |
| Aug 29 • 20:00 | Facundo Díaz Acosta | | - | | Jack Draper | 0 | : | 3 |
| Aug 29 • 20:00 | Alex De Minaur | | - | | Otto Virtanen | 3 | : | 0 |
| Aug 29 • 20:30 | Arthur Fils | | - | | Gabriel Diallo | 1 | : | 3 |
| Aug 29 • 20:30 | Tristan Schoolkate | | - | | Jakub Mensik | 2 | : | 3 |
| Aug 29 • 20:45 | David Goffin | | - | | Adrian Mannarino | 3 | : | 1 |
| Aug 29 • 21:00 | Mariano Navone | | - | | Daniel Evans | 0 | : | 3 |
| Aug 29 • 23:00 | Max Purcell | | - | | Tommy Paul | 0 | : | 2 |
| Aug 30 • 01:00 | Fábián Marozsán | | - | | Daniil Medvedev | 0 | : | 3 |
| Aug 30 • 02:30 | Carlos Alcaraz | | - | | Botic van de Zandschulp | 0 | : | 3 |
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| Aug 30 • 20:15 | Andrey Rublev | | - | | Jiří Lehečka | 3 | : | 0 |
| Aug 30 • 20:30 | Ben Shelton | | - | | Frances Tiafoe | 2 | : | 3 |
| Aug 30 • 21:00 | Francisco Comesana | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Aug 30 • 21:15 | Tallon Griekspoor | | - | | Grigor Dimitrov | 0 | : | 3 |
| Aug 30 • 22:00 | Brandon Nakashima | | - | | Lorenzo Musetti | 3 | : | 1 |
| Aug 30 • 23:00 | Casper Ruud | | - | | Shang Juncheng | 3 | : | 2 |
| Aug 31 • 01:00 | Alexei Popyrin | | - | | Novak Djokovic | 3 | : | 1 |
| Aug 31 • 02:30 | Tomás Martín Etcheverry | | - | | Alexander Zverev | 1 | : | 3 |
| Aug 31 • 17:00 | David Goffin | | - | | Tomáš Macháč | 0 | : | 3 |
| Aug 31 • 18:15 | Botic van de Zandschulp | | - | | Jack Draper | 0 | : | 3 |
| Aug 31 • 19:15 | Jannik Sinner | | - | | Christopher O'Connell | 3 | : | 0 |
| Aug 31 • 19:30 | Gabriel Diallo | | - | | Tommy Paul | 1 | : | 3 |
| Aug 31 • 21:35 | Nuno Borges | | - | | Jakub Mensik | 3 | : | 2 |
| Aug 31 • 23:00 | Matteo Arnaldi | | - | | Jordan Thompson | 0 | : | 3 |
| Sep 01 • 01:00 | Alex De Minaur | | - | | Daniel Evans | 3 | : | 1 |
| Sep 01 • 02:15 | Flavio Cobolli | | - | | Daniil Medvedev | 0 | : | 3 |
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| Sep 01 • 18:00 | Andrey Rublev | | - | | Grigor Dimitrov | 2 | : | 3 |
| Sep 01 • 19:00 | Casper Ruud | | - | | Taylor Harry Fritz | 1 | : | 3 |
| Sep 01 • 22:30 | Brandon Nakashima | | - | | Alexander Zverev | 1 | : | 3 |
| Sep 02 • 01:00 | Frances Tiafoe | | - | | Alexei Popyrin | 3 | : | 1 |
| Sep 02 • 18:15 | Jack Draper | | - | | Tomáš Macháč | 3 | : | 0 |
| Sep 02 • 19:15 | Nuno Borges | | - | | Daniil Medvedev | 0 | : | 3 |
| Sep 02 • 23:00 | Alex De Minaur | | - | | Jordan Thompson | 3 | : | 1 |
| Sep 03 • 02:15 | Jannik Sinner | | - | | Tommy Paul | 3 | : | 0 |
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| Sep 03 • 19:30 | Taylor Harry Fritz | | - | | Alexander Zverev | 3 | : | 1 |
| Sep 04 • 02:30 | Grigor Dimitrov | | - | | Frances Tiafoe | 1 | : | 2 |
| Sep 04 • 19:30 | Jack Draper | | - | | Alex De Minaur | 3 | : | 0 |
| Sep 05 • 02:30 | Jannik Sinner | | - | | Daniil Medvedev | 3 | : | 1 |
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| Sep 06 • 21:00 | Jannik Sinner | | - | | Jack Draper | 3 | : | 0 |
| Sep 07 • 01:00 | Taylor Harry Fritz | | - | | Frances Tiafoe | 3 | : | 2 |
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| Sep 08 • 20:00 | Jannik Sinner | | - | | Taylor Harry Fritz | 3 | : | 0 |
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