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| May 26 • 11:00 | Thomas Fabbiano |  | - |  | Marin Čilić | 0 | : | 3 |
| May 26 • 11:00 | Matteo Berrettini | | - |  | Pablo Andújar | 3 | : | 1 |
| May 26 • 11:00 | Casper Ruud |  | - |  | Ernests Gulbis | 3 | : | 0 |
| May 26 • 11:00 | Alexei Popyrin |  | - |  | Ugo Humbert | 3 | : | 1 |
| May 26 • 12:30 | Stefanos Tsitsipas |  | - |  | Maximilian Marterer | 3 | : | 0 |
| May 26 • 12:30 | Janko Tipsarević |  | - |  | Grigor Dimitrov | 2 | : | 3 |
| May 26 • 12:30 | Malek Jaziri |  | - | | Oscar Otte | 1 | : | 3 |
| May 26 • 13:30 | Marco Cecchinato | | - | | Nicolas Mahut | 2 | : | 3 |
| May 26 • 13:45 | Kei Nishikori |  | - | | Quentin Halys | 3 | : | 0 |
| May 26 • 14:50 | Lorenzo Sonego | | - |  | Roger Federer | 0 | : | 3 |
| May 26 • 15:15 | Prajnesh Gunneswaran |  | - |  | Hugo Dellien | 0 | : | 3 |
| May 26 • 15:50 | Márton Fucsovics |  | - |  | Diego Schwartzman | 2 | : | 3 |
| May 26 • 16:35 | Albert Ramos-Viñolas | | - | | Laslo Djere | 0 | : | 3 |
| May 26 • 16:55 | Jiří Veselý |  | - | | Leonardo Mayer | 0 | : | 3 |
| May 26 • 17:00 | Robin Haase |  | - | | Philipp Kohlschreiber | 1 | : | 3 |
| May 26 • 18:50 | David Goffin |  | - |  | Ričardas Berankis | 3 | : | 0 |
| May 27 • 11:00 | Filip Krajinović | | - |  | Frances Tiafoe | 3 | : | 2 |
| May 27 • 11:00 | Alex De Minaur | | - | | Bradley Klahn | 3 | : | 0 |
| May 27 • 11:00 | Pablo Carreño Busta | | - |  | João Sousa | 3 | : | 0 |
| May 27 • 11:00 | Pierre-Hugues Herbert | | - |  | Daniil Medvedev | 3 | : | 2 |
| May 27 • 11:00 | Nikoloz Basilashvili |  | - | | Juan Ignacio Londero | 0 | : | 3 |
| May 27 • 11:00 | Alexey Vatutin | | - | | Corentin Moutet | 0 | : | 3 |
| May 27 • 11:00 | Miomir Kecmanovic | | - | | Denis Kudla | 3 | : | 2 |
| May 27 • 12:30 | Yannick Maden | | - | | Kimmer Coppejans | 3 | : | 0 |
| May 27 • 12:50 | Reilly Opelka | | - |  | Cristian Garín | 0 | : | 3 |
| May 27 • 12:55 | Mischa Zverev | | - | | Richard Gasquet | 0 | : | 3 |
| May 27 • 13:05 | Roberto Carballés Baena | | - | | Alexandre Muller | 3 | : | 0 |
| May 27 • 13:30 | Yannick Hanfmann | | - | | Rafael Nadal | 0 | : | 3 |
| May 27 • 13:55 | Guido Andreozzi | | - | | Guido Pella | 1 | : | 3 |
| May 27 • 14:20 | Aljaž Bedene |  | - | | Borna Ćorić | 1 | : | 3 |
| May 27 • 14:40 | Henri Laaksonen | | - | | Pedro Martínez | 3 | : | 0 |
| May 27 • 14:55 | Stanislas Wawrinka | | - |  | Jozef Kovalík | 3 | : | 1 |
| May 27 • 15:20 | Sergiy Stakhovsky |  | - | | Gilles Simon | 0 | : | 3 |
| May 27 • 15:45 | Jo-Wilfried Tsonga | | - | | Peter Gojowczyk | 3 | : | 1 |
| May 27 • 15:50 | Novak Djokovic | | - |  | Hubert Hurkacz | 3 | : | 0 |
| May 27 • 16:00 | Jaume Munar | | - | | Salvatore Caruso | 1 | : | 3 |
| May 27 • 16:15 | Lloyd Harris |  | - | | Lukáš Rosol | 3 | : | 2 |
| May 27 • 16:40 | Benoît Paire | | - |  | Marius Copil | 3 | : | 1 |
| May 27 • 17:05 | Radu Albot |  | - | | Tennys Sandgren | 3 | : | 1 |
| May 27 • 17:25 | Denis Shapovalov |  | - | | Jan-Lennard Struff | 0 | : | 3 |
| May 27 • 17:25 | Rudolf Molleker | | - |  | Alexander Bublik | 1 | : | 3 |
| May 27 • 17:30 | Maxime Janvier | | - |  | Pablo Cuevas | 0 | : | 3 |
| May 27 • 17:30 | Jérémy Chardy | | - |  | Kyle Edmund | 2 | : | 3 |
| May 27 • 18:00 | Dominic Thiem |  | - | | Tommy Paul | 3 | : | 1 |
| May 28 • 11:00 | Fabio Fognini | | - | | Andreas Seppi | 3 | : | 1 |
| May 28 • 11:00 | Guillermo García López | | - | | Federico Delbonis | 1 | : | 3 |
| May 28 • 11:00 | Taylor Harry Fritz | | - | | Bernard Tomic | 3 | : | 0 |
| May 28 • 11:00 | Cameron Norrie | | - |  | Elliot Benchetrit | 0 | : | 3 |
| May 28 • 11:00 | Mikael Ymer |  | - | | Blaž Rola | 3 | : | 0 |
| May 28 • 11:00 | John Millman | | - | | Alexander Zverev | 2 | : | 3 |
| May 28 • 11:00 | Yoshihito Nishioka | | - | | Mackenzie McDonald | 3 | : | 2 |
| May 28 • 11:00 | Nicolás Jarry | | - | | Juan Martín del Potro | 1 | : | 3 |
| May 28 • 12:30 | Ivo Karlović | | - | | Feliciano López | 3 | : | 1 |
| May 28 • 12:40 | Dušan Lajović | | - |  | Thiago Moura Monteiro | 3 | : | 0 |
| May 28 • 13:00 | Steve Johnson | | - | | Roberto Bautista-Agut | 0 | : | 3 |
| May 28 • 14:00 | Alejandro Davidovich Fokina | | - | | Jordan Thompson | 0 | : | 3 |
| May 28 • 14:45 | Martin Kližan | | - | | Mikhail Kukushkin | 3 | : | 2 |
| May 28 • 15:05 | Karen Khachanov | | - | | Cedrik-Marcel Stebe | 3 | : | 0 |
| May 28 • 15:10 | Fernando Verdasco | | - | | Daniel Evans | 3 | : | 1 |
| May 28 • 15:10 | Simone Bolelli | | - | | Lucas Pouille | 0 | : | 3 |
| May 28 • 15:15 | Antoine Hoang | | - |  | Damir Džumhur | 3 | : | 1 |
| May 28 • 15:40 | Gregoire Barrere | | - | | Matthew Ebden | 3 | : | 1 |
| May 28 • 17:50 | Stefano Travaglia | | - | | Adrian Mannarino | 2 | : | 3 |
| May 28 • 18:30 | Taro Daniel | | - | | Gaël Monfils | 0 | : | 3 |
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| May 29 • 11:00 | Stefanos Tsitsipas | | - | | Hugo Dellien | 3 | : | 1 |
| May 29 • 11:00 | Corentin Moutet | | - | | Guido Pella | 3 | : | 1 |
| May 29 • 12:30 | Roberto Carballés Baena | | - | | Filip Krajinović | 2 | : | 3 |
| May 29 • 12:30 | Kei Nishikori | | - | | Jo-Wilfried Tsonga | 3 | : | 1 |
| May 29 • 12:30 | Alexei Popyrin | | - | | Laslo Djere | 0 | : | 3 |
| May 29 • 12:30 | Juan Ignacio Londero | | - | | Richard Gasquet | 3 | : | 1 |
| May 29 • 12:30 | David Goffin | | - | | Miomir Kecmanovic | 3 | : | 0 |
| May 29 • 12:30 | Yannick Maden | | - | | Rafael Nadal | 0 | : | 3 |
| May 29 • 14:00 | Grigor Dimitrov | | - | | Marin Čilić | 3 | : | 2 |
| May 29 • 14:00 | Matteo Berrettini | | - | | Casper Ruud | 0 | : | 3 |
| May 29 • 14:30 | Stanislas Wawrinka | | - | | Cristian Garín | 3 | : | 0 |
| May 29 • 14:30 | Nicolas Mahut | | - | | Philipp Kohlschreiber | 3 | : | 0 |
| May 29 • 16:15 | Oscar Otte | | - | | Roger Federer | 0 | : | 3 |
| May 29 • 16:30 | Benoît Paire | | - | | Pierre-Hugues Herbert | 3 | : | 2 |
| May 29 • 16:50 | Alex De Minaur | | - | | Pablo Carreño Busta | 0 | : | 3 |
| May 29 • 18:15 | Leonardo Mayer | | - | | Diego Schwartzman | 3 | : | 1 |
| May 30 • 11:00 | Dominic Thiem | | - | | Alexander Bublik | 3 | : | 1 |
| May 30 • 11:00 | Pablo Cuevas | | - | | Kyle Edmund | 2 | : | 0 |
| May 30 • 12:30 | Novak Djokovic | | - | | Henri Laaksonen | 3 | : | 0 |
| May 30 • 12:30 | Salvatore Caruso | | - | | Gilles Simon | 3 | : | 0 |
| May 30 • 12:30 | Dušan Lajović | | - | | Elliot Benchetrit | 3 | : | 0 |
| May 30 • 12:30 | Mikael Ymer | | - | | Alexander Zverev | 0 | : | 3 |
| May 30 • 14:00 | Jan-Lennard Struff | | - | | Radu Albot | 3 | : | 1 |
| May 30 • 14:00 | Fernando Verdasco | | - | | Antoine Hoang | 1 | : | 3 |
| May 30 • 14:00 | Jordan Thompson | | - | | Ivo Karlović | 3 | : | 1 |
| May 30 • 14:30 | Lloyd Harris | | - | | Borna Ćorić | 0 | : | 3 |
| May 30 • 14:30 | Adrian Mannarino | | - | | Gaël Monfils | 0 | : | 3 |
| May 30 • 14:30 | Yoshihito Nishioka | | - | | Juan Martín del Potro | 2 | : | 3 |
| May 30 • 16:00 | Fabio Fognini | | - | | Federico Delbonis | 3 | : | 1 |
| May 30 • 16:00 | Taylor Harry Fritz | | - | | Roberto Bautista-Agut | 0 | : | 3 |
| May 30 • 16:00 | Karen Khachanov | | - | | Gregoire Barrere | 3 | : | 1 |
| May 30 • 16:00 | Martin Kližan | | - | | Lucas Pouille | 3 | : | 2 |
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| May 31 • 12:30 | Casper Ruud | | - | | Roger Federer | 0 | : | 3 |
| May 31 • 12:30 | Kei Nishikori | | - | | Laslo Djere | 3 | : | 2 |
| May 31 • 12:30 | Pablo Carreño Busta | | - | | Benoît Paire | 1 | : | 2 |
| May 31 • 14:00 | Juan Ignacio Londero | | - | | Corentin Moutet | 3 | : | 2 |
| May 31 • 14:30 | Nicolas Mahut | | - | | Leonardo Mayer | 1 | : | 3 |
| May 31 • 15:00 | David Goffin | | - | | Rafael Nadal | 1 | : | 3 |
| May 31 • 16:00 | Stanislas Wawrinka | | - | | Grigor Dimitrov | 3 | : | 0 |
| May 31 • 17:00 | Stefanos Tsitsipas | | - | | Filip Krajinović | 3 | : | 1 |
| Jun 01 • 11:00 | Fabio Fognini | | - | | Roberto Bautista-Agut | 3 | : | 1 |
| Jun 01 • 11:00 | Dušan Lajović | | - | | Alexander Zverev | 2 | : | 3 |
| Jun 01 • 12:30 | Novak Djokovic | | - | | Salvatore Caruso | 3 | : | 0 |
| Jun 01 • 12:30 | Jan-Lennard Struff | | - | | Borna Ćorić | 3 | : | 2 |
| Jun 01 • 14:30 | Dominic Thiem | | - | | Pablo Cuevas | 3 | : | 1 |
| Jun 01 • 14:30 | Antoine Hoang | | - | | Gaël Monfils | 0 | : | 3 |
| Jun 01 • 14:30 | Jordan Thompson | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jun 01 • 15:00 | Karen Khachanov | | - | | Martin Kližan | 3 | : | 0 |
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| Jun 02 • 12:30 | Leonardo Mayer | | - | | Roger Federer | 0 | : | 3 |
| Jun 02 • 14:00 | Stefanos Tsitsipas | | - | | Stanislas Wawrinka | 2 | : | 3 |
| Jun 02 • 14:30 | Juan Ignacio Londero | | - | | Rafael Nadal | 0 | : | 3 |
| Jun 02 • 16:00 | Kei Nishikori | | - | | Benoît Paire | 3 | : | 2 |
| Jun 03 • 12:30 | Novak Djokovic | | - | | Jan-Lennard Struff | 3 | : | 0 |
| Jun 03 • 14:00 | Fabio Fognini | | - | | Alexander Zverev | 1 | : | 3 |
| Jun 03 • 14:30 | Dominic Thiem | | - | | Gaël Monfils | 3 | : | 0 |
| Jun 03 • 16:00 | Karen Khachanov | | - | | Juan Martín del Potro | 3 | : | 1 |
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| Jun 04 • 14:00 | Stanislas Wawrinka | | - | | Roger Federer | 1 | : | 3 |
| Jun 04 • 15:30 | Kei Nishikori | | - | | Rafael Nadal | 0 | : | 3 |
| Jun 06 • 14:30 | Novak Djokovic | | - | | Alexander Zverev | 3 | : | 0 |
| Jun 06 • 14:30 | Dominic Thiem | | - | | Karen Khachanov | 3 | : | 0 |
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| Jun 07 • 12:50 | Roger Federer | | - | | Rafael Nadal | 0 | : | 3 |
| Jun 07 • 14:50 | Novak Djokovic | | - | | Dominic Thiem | 2 | : | 3 |
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| Jun 09 • 15:00 | Dominic Thiem | | - | | Rafael Nadal | 1 | : | 3 |
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