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| Jun 17 • 13:00 | Fernando Verdasco |  | - |  | Daniil Medvedev | 0 | : | 2 |
| Jun 17 • 14:30 | Marin Čilić |  | - |  | Cristian Garín | 2 | : | 0 |
| Jun 17 • 14:30 | Diego Schwartzman |  | - |  | Alexander Bublik | 2 | : | 0 |
| Jun 17 • 15:50 | Nicolas Mahut |  | - |  | Frances Tiafoe | 2 | : | 0 |
| Jun 17 • 16:15 | Cameron Norrie |  | - |  | Kevin Anderson | 1 | : | 2 |
| Jun 17 • 17:45 | Gilles Simon | | - | | James Ward | 2 | : | 1 |
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| Jun 19 • 13:00 | Jérémy Chardy | | - | | Mikhail Kukushkin | 2 | : | 0 |
| Jun 19 • 13:00 | Juan Martín del Potro | | - |  | Denis Shapovalov | 2 | : | 0 |
| Jun 19 • 13:00 | Márton Fucsovics |  | - | | Feliciano López | 1 | : | 2 |
| Jun 19 • 14:30 | Alex De Minaur |  | - |  | Aljaž Bedene | 1 | : | 2 |
| Jun 19 • 14:45 | Stanislas Wawrinka |  | - | | Daniel Evans | 2 | : | 0 |
| Jun 19 • 15:30 | Jay Clarke | | - | | Lucas Pouille | 0 | : | 2 |
| Jun 19 • 17:00 | Marco Cecchinato |  | - | | Milos Raonic | 0 | : | 2 |
| Jun 19 • 19:45 | Stefanos Tsitsipas |  | - | | Kyle Edmund | 2 | : | 0 |
| Jun 19 • 19:50 | Nick Kyrgios | | - | | Roberto Carballés Baena | 2 | : | 0 |
| Jun 20 • 13:30 | Grigor Dimitrov |  | - | | Felix Auger Aliassime | 0 | : | 2 |
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| Jun 20 • 12:00 | Juan Martín del Potro | | - | | Feliciano López | 0 | : | 0 |
| Jun 20 • 12:00 | Marin Čilić | | - | | Diego Schwartzman | 0 | : | 2 |
| Jun 20 • 12:00 | Gilles Simon | | - | | Kevin Anderson | 2 | : | 1 |
| Jun 20 • 14:30 | Stanislas Wawrinka | | - | | Nicolas Mahut | 1 | : | 2 |
| Jun 20 • 15:20 | Lucas Pouille | | - | | Daniil Medvedev | 1 | : | 2 |
| Jun 20 • 15:40 | Aljaž Bedene | | - | | Milos Raonic | 0 | : | 2 |
| Jun 20 • 17:00 | Stefanos Tsitsipas | | - | | Jérémy Chardy | 2 | : | 1 |
| Jun 20 • 18:00 | Nick Kyrgios | | - | | Felix Auger Aliassime | 1 | : | 2 |
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| Jun 21 • 13:00 | Diego Schwartzman | | - | | Daniil Medvedev | 0 | : | 2 |
| Jun 21 • 14:00 | Nicolas Mahut | | - | | Gilles Simon | 1 | : | 2 |
| Jun 21 • 14:30 | Stefanos Tsitsipas | | - | | Felix Auger Aliassime | 0 | : | 2 |
| Jun 21 • 16:00 | Feliciano López | | - | | Milos Raonic | 2 | : | 1 |
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| Jun 22 • 14:00 | Daniil Medvedev | | - | | Gilles Simon | 1 | : | 2 |
| Jun 22 • 15:30 | Felix Auger Aliassime | | - | | Feliciano López | 1 | : | 2 |
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| Jun 23 • 12:00 | Feliciano López | | - | | Gilles Simon | 2 | : | 1 |
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