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| Oct 21 • 14:00 | Diego Schwartzman |  | - |  | Pierre-Hugues Herbert | 2 | : | 0 |
| Oct 21 • 15:00 | Márton Fucsovics |  | - |  | Lorenzo Sonego | 2 | : | 0 |
| Oct 21 • 16:15 | Matteo Berrettini | | - |  | Kyle Edmund | 2 | : | 1 |
| Oct 21 • 17:30 | Grigor Dimitrov |  | - |  | Damir Džumhur | 2 | : | 0 |
| Oct 21 • 20:45 | Hubert Hurkacz |  | - |  | Karen Khachanov | 0 | : | 2 |
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| Oct 22 • 14:00 | Feliciano López |  | - | | Gilles Simon | 0 | : | 2 |
| Oct 22 • 14:30 | Guido Pella | | - |  | Aljaž Bedene | 0 | : | 2 |
| Oct 22 • 15:30 | Chung Hyeon |  | - |  | Milos Raonic | 2 | : | 0 |
| Oct 22 • 16:35 | Nikoloz Basilashvili |  | - | | Fernando Verdasco | 1 | : | 2 |
| Oct 22 • 17:55 | Dominic Thiem |  | - | | Jo-Wilfried Tsonga | 2 | : | 0 |
| Oct 22 • 20:20 | Jannik Sinner | | - |  | Philipp Kohlschreiber | 2 | : | 0 |
| Oct 23 • 12:00 | Pablo Carreño Busta | | - | | Denis Shapovalov | 2 | : | 0 |
| Oct 23 • 12:00 | Sam Querrey |  | - | | Adrian Mannarino | 2 | : | 0 |
| Oct 23 • 13:20 | Andrey Rublev | | - |  | Alexander Bublik | 2 | : | 1 |
| Oct 23 • 13:50 | Mikhail Kukushkin | | - |  | Borna Ćorić | 2 | : | 0 |
| Oct 23 • 16:15 | Dennis Novak | | - | | Gaël Monfils | 1 | : | 2 |
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| Oct 23 • 18:15 | Matteo Berrettini | | - | | Grigor Dimitrov | 2 | : | 0 |
| Oct 23 • 19:55 | Márton Fucsovics | | - | | Karen Khachanov | 1 | : | 1 |
| Oct 24 • 14:00 | Diego Schwartzman | | - | | Sam Querrey | 2 | : | 1 |
| Oct 24 • 14:30 | Pablo Carreño Busta | | - | | Mikhail Kukushkin | 2 | : | 1 |
| Oct 24 • 17:10 | Chung Hyeon | | - | | Andrey Rublev | 0 | : | 2 |
| Oct 24 • 17:10 | Aljaž Bedene | | - | | Gilles Simon | 2 | : | 1 |
| Oct 24 • 18:40 | Dominic Thiem | | - | | Fernando Verdasco | 2 | : | 1 |
| Oct 24 • 20:10 | Jannik Sinner | | - | | Gaël Monfils | 0 | : | 2 |
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| Oct 25 • 14:00 | Matteo Berrettini | | - | | Andrey Rublev | 2 | : | 0 |
| Oct 25 • 15:30 | Dominic Thiem | | - | | Pablo Carreño Busta | 0 | : | 0 |
| Oct 25 • 18:00 | Diego Schwartzman | | - | | Karen Khachanov | 2 | : | 0 |
| Oct 25 • 19:30 | Aljaž Bedene | | - | | Gaël Monfils | 0 | : | 2 |
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| Oct 26 • 14:00 | Dominic Thiem | | - | | Matteo Berrettini | 2 | : | 1 |
| Oct 26 • 15:30 | Gaël Monfils | | - | | Diego Schwartzman | 0 | : | 2 |
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| Oct 27 • 14:00 | Dominic Thiem | | - | | Diego Schwartzman | 2 | : | 1 |
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