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| Apr 22 • 11:00 | Marius Copil |  | - |  | Leonardo Mayer | 1 | : | 2 |
| Apr 22 • 11:00 | Márton Fucsovics |  | - |  | Denis Kudla | 2 | : | 0 |
| Apr 22 • 11:00 | Mackenzie McDonald | | - |  | Taro Daniel | 2 | : | 0 |
| Apr 22 • 12:30 | Hugo Dellien |  | - |  | Jan-Lennard Struff | 0 | : | 2 |
| Apr 22 • 12:45 | Pedro Sousa |  | - |  | Jaume Munar | 1 | : | 2 |
| Apr 22 • 13:00 | Taylor Harry Fritz | | - | | Reilly Opelka | 2 | : | 0 |
| Apr 22 • 15:00 | Feliciano López | | - | | Fernando Verdasco | 0 | : | 2 |
| Apr 22 • 15:35 | Nicolás Jarry |  | - | | Marcel Granollers | 2 | : | 1 |
| Apr 22 • 16:35 | Yoshihito Nishioka | | - | | Diego Schwartzman | 1 | : | 2 |
| Apr 22 • 17:00 | Juan Ignacio Londero | | - |  | Benoît Paire | 0 | : | 2 |
| Apr 23 • 11:00 | Nicola Kuhn | | - | | Federico Delbonis | 2 | : | 1 |
| Apr 23 • 11:00 | Malek Jaziri |  | - | | Guido Andreozzi | 2 | : | 1 |
| Apr 23 • 14:00 | David Ferrer | | - | | Mischa Zverev | 2 | : | 0 |
| Apr 23 • 14:00 | Albert Ramos-Viñolas | | - |  | Cameron Norrie | 2 | : | 0 |
| Apr 23 • 15:20 | Martin Kližan |  | - | | Cristian Garín | 0 | : | 2 |
| Apr 23 • 16:45 | Guido Pella | | - | | João Sousa | 2 | : | 1 |
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| Apr 23 • 11:00 | Taylor Harry Fritz | | - | | Kei Nishikori | 0 | : | 2 |
| Apr 23 • 15:30 | Nicolás Jarry | | - | | Alexander Zverev | 2 | : | 1 |
| Apr 23 • 16:30 | Jaume Munar | | - | | Frances Tiafoe | 2 | : | 0 |
| Apr 23 • 17:55 | Dominic Thiem |  | - | | Diego Schwartzman | 2 | : | 0 |
| Apr 23 • 18:00 | David Goffin |  | - | | Jan-Lennard Struff | 0 | : | 2 |
| Apr 23 • 20:05 | Márton Fucsovics | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
| Apr 24 • 11:00 | Felix Auger Aliassime |  | - | | Malek Jaziri | 2 | : | 0 |
| Apr 24 • 11:00 | Daniil Medvedev |  | - | | Albert Ramos-Viñolas | 2 | : | 1 |
| Apr 24 • 12:30 | David Ferrer | | - | | Lucas Pouille | 2 | : | 0 |
| Apr 24 • 12:30 | Fabio Fognini |  | - | | Nicola Kuhn | 0 | : | 0 |
| Apr 24 • 12:30 | Mackenzie McDonald | | - | | Gilles Simon | 2 | : | 0 |
| Apr 24 • 14:00 | Rafael Nadal | | - | | Leonardo Mayer | 2 | : | 1 |
| Apr 24 • 14:00 | Guido Pella | | - | | Karen Khachanov | 2 | : | 0 |
| Apr 24 • 15:30 | Pablo Carreño Busta | | - | | Benoît Paire | 1 | : | 2 |
| Apr 24 • 15:30 | Grigor Dimitrov |  | - | | Fernando Verdasco | 2 | : | 1 |
| Apr 24 • 17:00 | Cristian Garín | | - | | Denis Shapovalov | 2 | : | 0 |
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| Apr 25 • 11:00 | Felix Auger Aliassime | | - | | Kei Nishikori | 0 | : | 2 |
| Apr 25 • 11:00 | Daniil Medvedev | | - | | Mackenzie McDonald | 2 | : | 0 |
| Apr 25 • 12:30 | Dominic Thiem | | - | | Jaume Munar | 2 | : | 0 |
| Apr 25 • 14:05 | Grigor Dimitrov | | - | | Nicolás Jarry | 1 | : | 2 |
| Apr 25 • 14:45 | Rafael Nadal | | - | | David Ferrer | 2 | : | 0 |
| Apr 25 • 15:45 | Roberto Carballés Baena | | - | | Cristian Garín | 2 | : | 0 |
| Apr 25 • 16:15 | Jan-Lennard Struff | | - | | Stefanos Tsitsipas | 2 | : | 1 |
| Apr 25 • 18:40 | Benoît Paire | | - | | Guido Pella | 0 | : | 2 |
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| Apr 26 • 12:30 | Daniil Medvedev | | - | | Nicolás Jarry | 2 | : | 0 |
| Apr 26 • 14:00 | Roberto Carballés Baena | | - | | Kei Nishikori | 0 | : | 2 |
| Apr 26 • 16:30 | Rafael Nadal | | - | | Jan-Lennard Struff | 2 | : | 0 |
| Apr 26 • 18:15 | Dominic Thiem | | - | | Guido Pella | 2 | : | 0 |
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| Apr 27 • 13:30 | Kei Nishikori | | - | | Daniil Medvedev | 1 | : | 2 |
| Apr 27 • 16:00 | Rafael Nadal | | - | | Dominic Thiem | 0 | : | 2 |
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| Apr 28 • 16:00 | Dominic Thiem | | - | | Daniil Medvedev | 2 | : | 0 |
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