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| Oct 07 • 20:00 | Daniel Altmaier |  | - |  | Sam Querrey | 2 | : | 0 |
| Oct 07 • 20:00 | Philipp Kohlschreiber | | - |  | Taro Daniel | 0 | : | 2 |
| Oct 07 • 20:00 | Alexei Popyrin |  | - |  | Miomir Kecmanovic | 2 | : | 0 |
| Oct 07 • 20:00 | Carlos Taberner |  | - | | Jaume Munar | 2 | : | 0 |
| Oct 07 • 21:20 | Mackenzie McDonald | | - | | James Duckworth | 2 | : | 0 |
| Oct 07 • 21:20 | Tommy Paul | | - | | Feliciano López | 2 | : | 0 |
| Oct 07 • 21:20 | Thiago Moura Monteiro |  | - | | Tennys Sandgren | 0 | : | 2 |
| Oct 07 • 21:20 | Kwon Soon-woo |  | - |  | Guido Pella | 1 | : | 2 |
| Oct 07 • 22:30 | Kei Nishikori | | - |  | João Sousa | 2 | : | 1 |
| Oct 07 • 22:40 | Marcos Giron | | - |  | Botic van de Zandschulp | 2 | : | 1 |
| Oct 07 • 22:40 | Maxime Cressy | | - | | Laslo Djere | 2 | : | 1 |
| Oct 08 • 03:00 | Salvatore Caruso |  | - | | Zachary Svajda | 2 | : | 0 |
| Oct 08 • 03:00 | Benoît Paire |  | - | | Frances Tiafoe | 0 | : | 2 |
| Oct 08 • 03:00 | Renzo Olivo | | - | | Roberto Carballés Baena | 0 | : | 2 |
| Oct 08 • 04:15 | Alejandro Davidovich Fokina | | - | | Steve Johnson | 2 | : | 1 |
| Oct 08 • 04:20 | Vasek Pospisil |  | - | | Jeffrey John Wolf | 2 | : | 1 |
| Oct 08 • 20:00 | Denis Kudla | | - |  | Alejandro Tabilo | 0 | : | 2 |
| Oct 08 • 20:00 | Federico Delbonis | | - | | Yoshihito Nishioka | 1 | : | 2 |
| Oct 08 • 20:00 | Dominik Koepfer | | - |  | Emil Ruusuvuori | 1 | : | 2 |
| Oct 08 • 21:30 | Kevin Anderson |  | - | | Jordan Thompson | 2 | : | 0 |
| Oct 08 • 21:30 | Holger Rune |  | - | | Ernesto Escobedo | 0 | : | 2 |
| Oct 08 • 21:30 | Jan-Lennard Struff | | - |  | Daniel Elahi Galán | 2 | : | 0 |
| Oct 08 • 23:00 | Cem Ilkel |  | - | | Jenson Brooksby | 0 | : | 2 |
| Oct 08 • 23:00 | Albert Ramos-Viñolas | | - | | Lorenzo Musetti | 2 | : | 0 |
| Oct 08 • 23:00 | Facundo Bagnis | | - |  | Emilio Gómez | 0 | : | 2 |
| Oct 09 • 03:00 | Federico Coria | | - | | Brandon Nakashima | 0 | : | 2 |
| Oct 09 • 03:00 | Jack Sock | | - | | John Millman | 1 | : | 2 |
| Oct 09 • 03:00 | Aleksandar Vukic | | - | | Pablo Andújar | 2 | : | 0 |
| Oct 09 • 03:00 | Pedro Martínez | | - | | Roberto Marcora | 2 | : | 0 |
| Oct 09 • 04:30 | Márton Fucsovics |  | - | | Gianluca Mager | 1 | : | 2 |
| Oct 09 • 04:30 | Andy Murray |  | - | | Adrian Mannarino | 2 | : | 0 |
| Oct 09 • 04:30 | Egor Gerasimov |  | - | | Christopher Eubanks | 0 | : | 2 |
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| Oct 09 • 20:00 | Taro Daniel | | - | | Reilly Opelka | 0 | : | 2 |
| Oct 09 • 20:00 | Alexei Popyrin | | - |  | Hubert Hurkacz | 0 | : | 2 |
| Oct 09 • 20:00 | Diego Schwartzman | | - | | Maxime Cressy | 2 | : | 1 |
| Oct 09 • 20:00 | Kei Nishikori | | - | | Daniel Evans | 1 | : | 2 |
| Oct 09 • 21:30 | Sebastian Korda | | - | | Frances Tiafoe | 0 | : | 2 |
| Oct 09 • 21:30 | Cameron Norrie | | - | | Tennys Sandgren | 2 | : | 1 |
| Oct 09 • 21:30 | Guido Pella | | - | | Roberto Bautista-Agut | 0 | : | 2 |
| Oct 09 • 21:30 | Roberto Carballés Baena | | - |  | Casper Ruud | 0 | : | 2 |
| Oct 09 • 23:00 | Grigor Dimitrov |  | - | | Daniel Altmaier | 2 | : | 0 |
| Oct 09 • 23:00 | Denis Shapovalov | | - | | Vasek Pospisil | 0 | : | 0 |
| Oct 10 • 03:00 | Daniil Medvedev |  | - | | Mackenzie McDonald | 2 | : | 0 |
| Oct 10 • 03:00 | Salvatore Caruso | | - | | Aslan Karatsev | 0 | : | 2 |
| Oct 10 • 03:00 | Tommy Paul | | - | | Dušan Lajović | 2 | : | 0 |
| Oct 10 • 03:00 | Lloyd Harris | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Oct 10 • 04:30 | Marcos Giron | | - | | Filip Krajinović | 0 | : | 2 |
| Oct 10 • 04:30 | Andrey Rublev | | - | | Carlos Taberner | 2 | : | 0 |
| Oct 10 • 20:00 | Matteo Berrettini | | - | | Alejandro Tabilo | 2 | : | 0 |
| Oct 10 • 20:00 | John Millman | | - | | Jannik Sinner | 0 | : | 2 |
| Oct 10 • 20:00 | Gaël Monfils | | - | | Gianluca Mager | 2 | : | 0 |
| Oct 10 • 20:00 | Kevin Anderson | | - | | Lorenzo Sonego | 2 | : | 0 |
| Oct 10 • 21:30 | Brandon Nakashima | | - | | Taylor Harry Fritz | 0 | : | 2 |
| Oct 10 • 21:30 | Carlos Alcaraz | | - | | Andy Murray | 1 | : | 2 |
| Oct 10 • 21:30 | Cristian Garín | | - | | Ernesto Escobedo | 2 | : | 0 |
| Oct 10 • 21:30 | Fabio Fognini | | - | | Jan-Lennard Struff | 2 | : | 1 |
| Oct 10 • 23:00 | Jenson Brooksby | | - | | Alexander Zverev | 1 | : | 2 |
| Oct 10 • 23:00 | Felix Auger Aliassime | | - | | Albert Ramos-Viñolas | 0 | : | 2 |
| Oct 10 • 23:00 | Emilio Gómez | | - | | Pablo Carreño Busta | 0 | : | 2 |
| Oct 10 • 23:00 | Aleksandar Vukic | | - | | Alex De Minaur | 0 | : | 2 |
| Oct 11 • 03:00 | Christopher Eubanks | | - |  | Nikoloz Basilashvili | 0 | : | 2 |
| Oct 11 • 03:00 | Karen Khachanov | | - | | Emil Ruusuvuori | 2 | : | 0 |
| Oct 11 • 03:00 | Pedro Martínez | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
| Oct 11 • 04:30 | John Isner | | - | | Yoshihito Nishioka | 2 | : | 0 |
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| Oct 11 • 20:00 | Diego Schwartzman | | - | | Daniel Evans | 2 | : | 1 |
| Oct 11 • 20:00 | Lloyd Harris | | - | | Casper Ruud | 1 | : | 2 |
| Oct 11 • 21:20 | Grigor Dimitrov | | - | | Reilly Opelka | 2 | : | 0 |
| Oct 11 • 22:30 | Denis Shapovalov | | - | | Aslan Karatsev | 0 | : | 2 |
| Oct 12 • 03:00 | Frances Tiafoe | | - | | Hubert Hurkacz | 0 | : | 2 |
| Oct 12 • 03:00 | Cameron Norrie | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| Oct 12 • 04:15 | Daniil Medvedev | | - | | Filip Krajinović | 2 | : | 0 |
| Oct 12 • 04:20 | Andrey Rublev | | - | | Tommy Paul | 1 | : | 2 |
| Oct 12 • 20:00 | Matteo Berrettini | | - | | Taylor Harry Fritz | 0 | : | 2 |
| Oct 12 • 20:00 | John Isner | | - | | Jannik Sinner | 0 | : | 0 |
| Oct 12 • 21:30 | Albert Ramos-Viñolas | | - | | Nikoloz Basilashvili | 1 | : | 2 |
| Oct 12 • 21:30 | Karen Khachanov | | - | | Pablo Carreño Busta | 2 | : | 0 |
| Oct 12 • 23:00 | Andy Murray | | - | | Alexander Zverev | 0 | : | 2 |
| Oct 13 • 03:00 | Gaël Monfils | | - | | Kevin Anderson | 2 | : | 0 |
| Oct 13 • 04:30 | Cristian Garín | | - | | Alex De Minaur | 0 | : | 2 |
| Oct 13 • 04:30 | Fabio Fognini | | - | | Stefanos Tsitsipas | 1 | : | 2 |
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| Oct 13 • 20:00 | Aslan Karatsev | | - | | Hubert Hurkacz | 0 | : | 2 |
| Oct 13 • 20:00 | Diego Schwartzman | | - | | Casper Ruud | 2 | : | 0 |
| Oct 13 • 21:20 | Daniil Medvedev | | - | | Grigor Dimitrov | 1 | : | 2 |
| Oct 13 • 21:20 | Tommy Paul | | - | | Cameron Norrie | 1 | : | 2 |
| Oct 13 • 22:40 | Taylor Harry Fritz | | - | | Jannik Sinner | 2 | : | 0 |
| Oct 13 • 23:15 | Nikoloz Basilashvili | | - | | Karen Khachanov | 2 | : | 0 |
| Oct 14 • 03:00 | Alex De Minaur | | - | | Stefanos Tsitsipas | 1 | : | 2 |
| Oct 14 • 04:15 | Gaël Monfils | | - | | Alexander Zverev | 0 | : | 2 |
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| Oct 14 • 20:00 | Cameron Norrie | | - | | Diego Schwartzman | 2 | : | 0 |
| Oct 14 • 21:30 | Grigor Dimitrov | | - | | Hubert Hurkacz | 2 | : | 1 |
| Oct 15 • 20:00 | Nikoloz Basilashvili | | - | | Stefanos Tsitsipas | 2 | : | 1 |
| Oct 15 • 21:20 | Taylor Harry Fritz | | - | | Alexander Zverev | 2 | : | 1 |
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| Oct 16 • 22:30 | Grigor Dimitrov | | - | | Cameron Norrie | 0 | : | 2 |
| Oct 16 • 23:50 | Taylor Harry Fritz | | - | | Nikoloz Basilashvili | 0 | : | 2 |
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| Oct 18 • 01:00 | Cameron Norrie | | - | | Nikoloz Basilashvili | 2 | : | 1 |
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