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| Oct 04 • 06:30 | Daniel Altmaier |  | - |  | Yoshihito Nishioka | 1 | : | 2 |
| Oct 04 • 06:30 | Dušan Lajović |  | - |  | Stanislas Wawrinka | 2 | : | 0 |
| Oct 04 • 06:30 | Brandon Nakashima |  | - |  | Bernabe Zapata Miralles | 2 | : | 0 |
| Oct 04 • 06:30 | Miomir Kecmanovic | | - |  | Bu Yunchaokete | 1 | : | 1 |
| Oct 04 • 08:30 | Dane Sweeny |  | - | | Taro Daniel | 2 | : | 0 |
| Oct 04 • 08:45 | Thanasi Kokkinakis | | - |  | Fabio Fognini | 2 | : | 0 |
| Oct 04 • 09:00 | Arthur Rinderknech |  | - |  | Fábián Marozsán | 0 | : | 2 |
| Oct 04 • 09:00 | Jaume Munar | | - | | Te Rigele | 2 | : | 0 |
| Oct 04 • 10:30 | James Duckworth | | - | | Yannick Hanfmann | 1 | : | 2 |
| Oct 04 • 11:15 | Corentin Moutet | | - | | Mackenzie McDonald | 0 | : | 2 |
| Oct 04 • 11:50 | Denis Yevseyev |  | - | | Márton Fucsovics | 0 | : | 2 |
| Oct 04 • 12:25 | Max Purcell | | - |  | Hsu Yu-hsiou | 1 | : | 2 |
| Oct 04 • 12:25 | Zhang Zhizhen | | - | | Richard Gasquet | 2 | : | 0 |
| Oct 04 • 12:45 | Marcos Giron | | - |  | Daniel Elahi Galán | 2 | : | 0 |
| Oct 04 • 13:15 | Aleksandar Kovacevic | | - |  | Cristian Garín | 0 | : | 2 |
| Oct 04 • 14:00 | Roman Safiullin |  | - |  | Andy Murray | 2 | : | 0 |
| Oct 05 • 06:30 | Nuno Borges |  | - | | Gregoire Barrere | 0 | : | 2 |
| Oct 05 • 06:30 | Mikhail Kukushkin | | - | | Alexandre Muller | 2 | : | 1 |
| Oct 05 • 06:30 | Philip Sekulic | | - | | Lorenzo Sonego | 0 | : | 2 |
| Oct 05 • 06:30 | Alexander Shevchenko | | - | | Tseng Chun-hsin | 1 | : | 2 |
| Oct 05 • 08:00 | Aleksandar Vukic | | - | | Roberto Carballés Baena | 2 | : | 0 |
| Oct 05 • 08:00 | Beibit Zhukayev | | - | | Stefano Napolitano | 2 | : | 0 |
| Oct 05 • 08:00 | Rinky Hijikata | | - | | Laslo Djere | 2 | : | 0 |
| Oct 05 • 08:00 | Pavel Kotov | | - | | Arthur Fils | 0 | : | 2 |
| Oct 05 • 09:55 | Jordan Thompson | | - | | Terence Atmane | 1 | : | 2 |
| Oct 05 • 11:15 | Alexei Popyrin | | - | | Matteo Arnaldi | 1 | : | 2 |
| Oct 05 • 11:30 | Aslan Karatsev | | - | | Quentin Halys | 1 | : | 2 |
| Oct 05 • 12:15 | Botic van de Zandschulp |  | - | | Christopher O'Connell | 2 | : | 1 |
| Oct 05 • 12:30 | Diego Schwartzman |  | - | | Luca Van Assche | 2 | : | 1 |
| Oct 05 • 13:30 | Juan Pablo Varillas |  | - |  | Sebastian Ofner | 0 | : | 2 |
| Oct 05 • 13:45 | Jeffrey John Wolf | | - | | Pedro Cachín | 2 | : | 1 |
| Oct 05 • 14:00 | Yosuke Watanuki | | - | | Shang Juncheng | 2 | : | 1 |
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| Oct 06 • 06:30 | Casper Ruud |  | - | | Yoshihito Nishioka | 2 | : | 0 |
| Oct 06 • 06:30 | Yannick Hanfmann | | - | | Christopher Eubanks | 1 | : | 2 |
| Oct 06 • 06:30 | Tallon Griekspoor | | - | | Dušan Lajović | 0 | : | 1 |
| Oct 06 • 06:30 | Fábián Marozsán | | - | | Alex De Minaur | 2 | : | 0 |
| Oct 06 • 07:50 | Hsu Yu-hsiou | | - | | Lorenzo Musetti | 2 | : | 0 |
| Oct 06 • 07:50 | Brandon Nakashima | | - |  | Holger Rune | 2 | : | 0 |
| Oct 06 • 07:50 | Felix Auger Aliassime |  | - | | Márton Fucsovics | 1 | : | 2 |
| Oct 06 • 07:50 | Mackenzie McDonald | | - | | Francisco Cerundolo | 0 | : | 2 |
| Oct 06 • 11:00 | Hubert Hurkacz |  | - | | Thanasi Kokkinakis | 2 | : | 0 |
| Oct 06 • 11:00 | Ben Shelton | | - | | Jaume Munar | 2 | : | 0 |
| Oct 06 • 12:40 | Tomás Martín Etcheverry | | - | | Zhang Zhizhen | 1 | : | 2 |
| Oct 06 • 12:45 | Sebastian Korda | | - | | Bu Yunchaokete | 2 | : | 0 |
| Oct 06 • 13:30 | Dane Sweeny | | - | | Sebastián Báez | 0 | : | 2 |
| Oct 06 • 13:50 | Roman Safiullin | | - | | Alexander Zverev | 2 | : | 0 |
| Oct 07 • 06:30 | Terence Atmane | | - | | Nicolás Jarry | 0 | : | 2 |
| Oct 07 • 06:30 | Stefanos Tsitsipas |  | - | | Rinky Hijikata | 2 | : | 0 |
| Oct 07 • 06:30 | Jan-Lennard Struff | | - | | Matteo Arnaldi | 1 | : | 2 |
| Oct 07 • 06:30 | Jeffrey John Wolf | | - | | Cameron Norrie | 2 | : | 1 |
| Oct 07 • 06:30 | Tommy Paul | | - | | Sebastian Ofner | 2 | : | 0 |
| Oct 07 • 07:50 | Frances Tiafoe | | - | | Lorenzo Sonego | 1 | : | 2 |
| Oct 07 • 07:50 | Botic van de Zandschulp | | - | | Ugo Humbert | 1 | : | 2 |
| Oct 07 • 07:50 | Cristian Garín | | - | | Daniil Medvedev | 0 | : | 2 |
| Oct 07 • 09:30 | Jannik Sinner | | - | | Marcos Giron | 2 | : | 0 |
| Oct 07 • 12:30 | Carlos Alcaraz | | - | | Gregoire Barrere | 2 | : | 0 |
| Oct 07 • 13:50 | Yosuke Watanuki | | - | | Taylor Harry Fritz | 1 | : | 2 |
| Oct 08 • 06:30 | Arthur Fils | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Oct 08 • 07:00 | Mikhail Kukushkin | | - | | Daniel Evans | 0 | : | 1 |
| Oct 08 • 07:00 | Grigor Dimitrov |  | - | | Aleksandar Vukic | 2 | : | 0 |
| Oct 08 • 08:00 | Beibit Zhukayev | | - | | Karen Khachanov | 1 | : | 2 |
| Oct 08 • 08:00 | Jiří Lehečka |  | - | | Diego Schwartzman | 1 | : | 2 |
| Oct 08 • 08:30 | Quentin Halys | | - | | Andrey Rublev | 0 | : | 2 |
| Oct 08 • 09:30 | Adrian Mannarino | | - | | Tseng Chun-hsin | 2 | : | 0 |
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| Oct 08 • 06:30 | Casper Ruud | | - | | Christopher Eubanks | 2 | : | 0 |
| Oct 08 • 08:00 | Sebastian Korda | | - | | Daniil Medvedev | 2 | : | 0 |
| Oct 08 • 08:30 | Hubert Hurkacz | | - | | Hsu Yu-hsiou | 2 | : | 0 |
| Oct 08 • 09:30 | Dušan Lajović | | - | | Fábián Marozsán | 0 | : | 2 |
| Oct 08 • 10:00 | Ben Shelton | | - | | Roman Safiullin | 2 | : | 1 |
| Oct 08 • 10:00 | Márton Fucsovics | | - | | Francisco Cerundolo | 1 | : | 2 |
| Oct 08 • 12:40 | Jannik Sinner | | - | | Sebastián Báez | 2 | : | 1 |
| Oct 08 • 14:00 | Zhang Zhizhen | | - | | Brandon Nakashima | 2 | : | 0 |
| Oct 09 • 06:30 | Grigor Dimitrov | | - | | Karen Khachanov | 2 | : | 0 |
| Oct 09 • 06:30 | Tommy Paul | | - | | Arthur Fils | 2 | : | 1 |
| Oct 09 • 08:30 | Adrian Mannarino | | - | | Andrey Rublev | 0 | : | 2 |
| Oct 09 • 08:40 | Diego Schwartzman | | - | | Taylor Harry Fritz | 2 | : | 1 |
| Oct 09 • 10:00 | Lorenzo Sonego | | - | | Nicolás Jarry | 0 | : | 2 |
| Oct 09 • 13:00 | Carlos Alcaraz | | - | | Daniel Evans | 2 | : | 0 |
| Oct 09 • 13:30 | Matteo Arnaldi | | - | | Jeffrey John Wolf | 1 | : | 2 |
| Oct 09 • 14:30 | Stefanos Tsitsipas | | - | | Ugo Humbert | 1 | : | 2 |
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| Oct 10 • 06:30 | Casper Ruud | | - | | Fábián Marozsán | 1 | : | 2 |
| Oct 10 • 07:50 | Francisco Cerundolo | | - | | Sebastian Korda | 0 | : | 2 |
| Oct 10 • 12:30 | Jannik Sinner | | - | | Ben Shelton | 1 | : | 2 |
| Oct 10 • 13:50 | Hubert Hurkacz | | - | | Zhang Zhizhen | 2 | : | 1 |
| Oct 11 • 06:30 | Nicolás Jarry | | - | | Diego Schwartzman | 2 | : | 1 |
| Oct 11 • 07:50 | Ugo Humbert | | - | | Jeffrey John Wolf | 2 | : | 0 |
| Oct 11 • 12:30 | Carlos Alcaraz | | - | | Grigor Dimitrov | 1 | : | 2 |
| Oct 11 • 13:50 | Tommy Paul | | - | | Andrey Rublev | 0 | : | 2 |
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| Oct 12 • 09:00 | Fábián Marozsán | | - | | Hubert Hurkacz | 1 | : | 2 |
| Oct 12 • 12:30 | Ben Shelton | | - | | Sebastian Korda | 1 | : | 2 |
| Oct 13 • 10:30 | Grigor Dimitrov | | - | | Nicolás Jarry | 2 | : | 0 |
| Oct 13 • 14:00 | Ugo Humbert | | - | | Andrey Rublev | 0 | : | 2 |
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| Oct 14 • 10:30 | Hubert Hurkacz | | - | | Sebastian Korda | 2 | : | 0 |
| Oct 14 • 14:00 | Grigor Dimitrov | | - | | Andrey Rublev | 0 | : | 2 |
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| Oct 15 • 10:30 | Andrey Rublev | | - | | Hubert Hurkacz | 1 | : | 2 |
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