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| Feb 17 • 20:30 | Pablo Andújar |  | - | | Fernando Verdasco | 2 | : | 0 |
| Feb 17 • 20:30 | Roberto Carballés Baena | | - |  | Federico Delbonis | 0 | : | 2 |
| Feb 17 • 20:30 | Andrej Martin |  | - |  | Cristian Garín | 1 | : | 2 |
| Feb 17 • 22:00 | Pedro Martínez | | - |  | Hugo Dellien | 2 | : | 1 |
| Feb 17 • 22:00 | Corentin Moutet |  | - | | Federico Coria | 1 | : | 2 |
| Feb 17 • 23:00 | Alejandro Davidovich Fokina | | - |  | Thiago Seyboth Wild | 1 | : | 2 |
| Feb 18 • 00:30 | Albert Ramos-Viñolas | | - | | Carlos Alcaraz | 1 | : | 2 |
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| Feb 18 • 20:30 | Jaume Munar | | - |  | Salvatore Caruso | 2 | : | 0 |
| Feb 18 • 20:30 | Attila Balazs |  | - |  | Pablo Cuevas | 2 | : | 0 |
| Feb 18 • 20:30 | Borna Ćorić |  | - | | Juan Ignacio Londero | 2 | : | 0 |
| Feb 18 • 20:30 | Marco Cecchinato | | - |  | Dušan Lajović | 1 | : | 2 |
| Feb 18 • 22:00 | Gianluca Mager | | - |  | Casper Ruud | 2 | : | 0 |
| Feb 18 • 22:00 | Leonardo Mayer | | - | | Lorenzo Sonego | 1 | : | 2 |
| Feb 18 • 22:55 | João Domingues |  | - | | Federico Gaio | 2 | : | 0 |
| Feb 18 • 23:00 | Dominic Thiem |  | - | | Felipe Meligeni Alves | 2 | : | 1 |
| Feb 19 • 00:30 | Guido Pella | | - | | Thiago Moura Monteiro | 1 | : | 2 |
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| Feb 19 • 20:30 | Federico Delbonis | | - | | Cristian Garín | 0 | : | 2 |
| Feb 19 • 22:00 | Pedro Martínez | | - | | Pablo Andújar | 2 | : | 0 |
| Feb 19 • 22:40 | Thiago Moura Monteiro | | - | | Attila Balazs | 1 | : | 2 |
| Feb 20 • 00:30 | Carlos Alcaraz | | - | | Federico Coria | 1 | : | 2 |
| Feb 20 • 20:30 | João Domingues | | - | | Gianluca Mager | 0 | : | 2 |
| Feb 20 • 20:30 | Lorenzo Sonego | | - | | Dušan Lajović | 2 | : | 0 |
| Feb 20 • 23:00 | Borna Ćorić | | - | | Thiago Seyboth Wild | 2 | : | 1 |
| Feb 21 • 00:30 | Dominic Thiem | | - | | Jaume Munar | 2 | : | 1 |
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| Feb 21 • 19:00 | Federico Coria | | - | | Cristian Garín | 1 | : | 2 |
| Feb 21 • 22:45 | Borna Ćorić | | - | | Lorenzo Sonego | 2 | : | 0 |
| Feb 21 • 23:15 | Dominic Thiem | | - | | Gianluca Mager | 0 | : | 2 |
| Feb 21 • 23:45 | Attila Balazs | | - | | Pedro Martínez | 2 | : | 1 |
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| Feb 22 • 21:00 | Cristian Garín | | - | | Borna Ćorić | 2 | : | 0 |
| Feb 22 • 22:30 | Gianluca Mager | | - | | Attila Balazs | 2 | : | 1 |
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| Feb 23 • 21:30 | Gianluca Mager | | - | | Cristian Garín | 0 | : | 2 |
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