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| May 22 • 11:00 | Marin Čilić |  | - |  | Rubén Ramírez Hidalgo | 0 | : | 3 |
| May 22 • 11:00 | Sergiy Stakhovsky |  | - |  | David Guez | 3 | : | 1 |
| May 22 • 11:00 | Kei Nishikori |  | - |  | Lu Yen-Hsun | 3 | : | 0 |
| May 22 • 12:35 | David Ferrer | | - |  | Jarkko Nieminen | 3 | : | 0 |
| May 22 • 12:45 | Vincent Millot | | - | | Maxime Teixeira | 2 | : | 3 |
| May 22 • 13:00 | Guillermo García López | | - |  | Robert Kendrick | 3 | : | 1 |
| May 22 • 13:00 | Marc Gicquel | | - | | Albert Montañés | 0 | : | 3 |
| May 22 • 13:45 | Ivan Dodig | | - | | Pere Riba | 1 | : | 3 |
| May 22 • 14:25 | Jo-Wilfried Tsonga | | - |  | Jan Hájek | 3 | : | 0 |
| May 22 • 14:25 | Ernests Gulbis |  | - |  | Blaž Kavčič | 0 | : | 3 |
| May 22 • 14:30 | Stanislas Wawrinka |  | - | | Augustin Gensse | 3 | : | 1 |
| May 22 • 16:30 | Julien Benneteau | | - |  | Rui Machado | 3 | : | 1 |
| May 22 • 17:00 | Fabio Fognini |  | - |  | Denis Istomin | 3 | : | 0 |
| May 22 • 17:00 | Teymuraz Gabashvili |  | - | | Andreas Seppi | 0 | : | 3 |
| May 22 • 18:00 | Adrian Mannarino | | - | | Guillaume Rufin | 0 | : | 3 |
| May 23 • 11:00 | Mikhail Youzhny | | - | | Go Soeda | 3 | : | 0 |
| May 23 • 11:00 | Viktor Troicki |  | - |  | Julian Reister | 3 | : | 0 |
| May 23 • 11:00 | Thomaz Bellucci |  | - |  | Andrey Golubev | 3 | : | 1 |
| May 23 • 11:00 | Juan Martín del Potro |  | - | | Ivo Karlović | 3 | : | 1 |
| May 23 • 11:00 | Tommy Haas | | - |  | Marsel İlhan | 1 | : | 3 |
| May 23 • 11:00 | Daniel Brands | | - | | Mikhail Kukushkin | 0 | : | 3 |
| May 23 • 13:00 | Novak Djokovic | | - |  | Thiemo de Bakker | 3 | : | 0 |
| May 23 • 13:00 | Tomáš Berdych | | - | | Stéphane Robert | 2 | : | 3 |
| May 23 • 13:00 | Mardy Fish | | - | | Ricardo Mello | 3 | : | 1 |
| May 23 • 13:00 | Albert Ramos-Viñolas | | - | | Javier Martí | 3 | : | 2 |
| May 23 • 13:00 | Janko Tipsarević | | - | | Brian Dabul | 3 | : | 0 |
| May 23 • 13:00 | Potito Starace | | - |  | Alejandro Falla | 0 | : | 3 |
| May 23 • 13:00 | Florent Serra | | - | | Igor Andreev | 0 | : | 3 |
| May 23 • 14:30 | Roger Federer | | - | | Feliciano López | 3 | : | 0 |
| May 23 • 14:35 | Gaël Monfils | | - | | Björn Phau | 3 | : | 1 |
| May 23 • 14:50 | Michaël Llodra | | - |  | Steve Darcis | 1 | : | 3 |
| May 23 • 15:00 | Nikolay Davydenko | | - | | Denis Gremelmayr | 3 | : | 0 |
| May 23 • 15:00 | Simone Bolelli | | - |  | Frank Dancevic | 3 | : | 1 |
| May 23 • 15:00 | Leonardo Mayer | | - | | Dustin Brown | 3 | : | 1 |
| May 23 • 15:00 | Tobias Kamke | | - | | Olivier Rochus | 3 | : | 1 |
| May 23 • 15:00 | Carlos Berlocq | | - |  | Bernard Tomic | 3 | : | 0 |
| May 23 • 15:00 | Philipp Petzschner | | - | | Mischa Zverev | 3 | : | 0 |
| May 23 • 15:00 | Thomas Schoorel | | - | | Máximo González | 3 | : | 0 |
| May 23 • 15:00 | Benoît Paire | | - |  | Victor Hănescu | 1 | : | 3 |
| May 23 • 17:00 | Richard Gasquet | | - | | Radek Štěpánek | 3 | : | 0 |
| May 23 • 17:00 | Milos Raonic | | - | | Michael Berrer | 1 | : | 3 |
| May 23 • 17:00 | Marcos Baghdatis |  | - | | Frederico Gil | 3 | : | 0 |
| May 23 • 17:00 | Pablo Cuevas |  | - | | Antonio Veić | 1 | : | 2 |
| May 23 • 17:00 | Alex Bogomolov Jr | | - | | Marcel Granollers | 1 | : | 3 |
| May 24 • 11:00 | Andy Murray |  | - | | Éric Prodon | 3 | : | 0 |
| May 24 • 11:00 | Florian Mayer | | - | | Igor Kunitsyn | 3 | : | 1 |
| May 24 • 11:00 | Alexandr Dolgopolov | | - | | Rainer Schüttler | 3 | : | 0 |
| May 24 • 11:00 | Ivan Ljubičić | | - |  | Somdev Devvarman | 3 | : | 0 |
| May 24 • 11:00 | Andreas Haider-Maurer |  | - | | Ryan Sweeting | 3 | : | 1 |
| May 24 • 12:45 | Arnaud Clément | | - | | Filippo Volandri | 3 | : | 1 |
| May 24 • 13:00 | Daniel Gimeno-Traver | | - | | Robin Haase | 0 | : | 3 |
| May 24 • 13:10 | Nicolás Almagro | | - |  | Łukasz Kubot | 2 | : | 3 |
| May 24 • 13:10 | Juan Ignacio Chela | | - | | Tim Smyczek | 3 | : | 0 |
| May 24 • 13:55 | Jürgen Melzer | | - | | Andreas Beck | 3 | : | 0 |
| May 24 • 13:55 | Sam Querrey | | - | | Philipp Kohlschreiber | 3 | : | 1 |
| May 24 • 13:55 | Santiago Giraldo | | - | | Pablo Andújar | 0 | : | 3 |
| May 24 • 14:00 | Rafael Nadal | | - | | John Isner | 3 | : | 2 |
| May 24 • 15:00 | Kevin Anderson |  | - | | Nicolas Mahut | 3 | : | 1 |
| May 24 • 15:00 | Dmitry Tursunov | | - | | Xavier Malisse | 2 | : | 3 |
| May 24 • 15:15 | Robin Söderling |  | - | | Ryan Harrison | 3 | : | 1 |
| May 24 • 15:30 | Fernando Verdasco | | - | | Juan Mónaco | 3 | : | 1 |
| May 24 • 15:30 | Édouard Roger-Vasselin | | - | | Lukáš Rosol | 2 | : | 3 |
| May 24 • 17:00 | Gilles Simon | | - | | Michael Russell | 3 | : | 1 |
| May 24 • 17:00 | Jérémy Chardy | | - |  | Grigor Dimitrov | 3 | : | 0 |
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| May 25 • 11:00 | Kei Nishikori | | - | | Sergiy Stakhovsky | 1 | : | 3 |
| May 25 • 11:00 | Maxime Teixeira | | - | | Roger Federer | 0 | : | 3 |
| May 25 • 11:00 | Janko Tipsarević | | - | | Pere Riba | 3 | : | 0 |
| May 25 • 13:00 | David Ferrer | | - | | Julien Benneteau | 3 | : | 0 |
| May 25 • 13:00 | Guillaume Rufin | | - | | Gaël Monfils | 1 | : | 3 |
| May 25 • 14:15 | Steve Darcis | | - | | Philipp Petzschner | 3 | : | 0 |
| May 25 • 14:35 | Juan Martín del Potro | | - | | Blaž Kavčič | 3 | : | 0 |
| May 25 • 14:50 | Rubén Ramírez Hidalgo | | - | | Albert Montañés | 1 | : | 3 |
| May 25 • 14:55 | Richard Gasquet | | - | | Marcel Granollers | 3 | : | 1 |
| May 25 • 15:10 | Mikhail Kukushkin | | - | | Mikhail Youzhny | 0 | : | 3 |
| May 25 • 16:00 | Andreas Seppi | | - | | Thomaz Bellucci | 0 | : | 3 |
| May 25 • 16:30 | Victor Hănescu | | - | | Novak Djokovic | 0 | : | 2 |
| May 25 • 16:50 | Marsel İlhan | | - | | Guillermo García López | 2 | : | 3 |
| May 25 • 17:05 | Stéphane Robert | | - | | Fabio Fognini | 0 | : | 3 |
| May 25 • 17:45 | Igor Andreev | | - | | Jo-Wilfried Tsonga | 0 | : | 3 |
| May 25 • 18:00 | Stanislas Wawrinka | | - | | Thomas Schoorel | 3 | : | 0 |
| May 26 • 11:00 | Albert Ramos-Viñolas | | - | | Robin Söderling | 0 | : | 3 |
| May 26 • 11:00 | Alejandro Falla | | - | | Florian Mayer | 3 | : | 1 |
| May 26 • 11:00 | Sam Querrey | | - | | Ivan Ljubičić | 0 | : | 3 |
| May 26 • 11:50 | Łukasz Kubot | | - | | Carlos Berlocq | 3 | : | 0 |
| May 26 • 12:45 | Mardy Fish | | - | | Robin Haase | 3 | : | 0 |
| May 26 • 12:50 | Xavier Malisse | | - | | Fernando Verdasco | 1 | : | 3 |
| May 26 • 13:30 | Andy Murray | | - | | Simone Bolelli | 3 | : | 0 |
| May 26 • 14:30 | Marcos Baghdatis | | - | | Leonardo Mayer | 0 | : | 3 |
| May 26 • 15:35 | Antonio Veić | | - | | Nikolay Davydenko | 3 | : | 2 |
| May 26 • 15:40 | Rafael Nadal | | - | | Pablo Andújar | 3 | : | 0 |
| May 26 • 16:30 | Kevin Anderson | | - | | Juan Ignacio Chela | 2 | : | 3 |
| May 26 • 16:55 | Lukáš Rosol | | - | | Jürgen Melzer | 3 | : | 2 |
| May 26 • 17:05 | Tobias Kamke | | - | | Viktor Troicki | 0 | : | 3 |
| May 26 • 17:20 | Arnaud Clément | | - | | Michael Berrer | 1 | : | 3 |
| May 26 • 19:00 | Jérémy Chardy | | - | | Gilles Simon | 1 | : | 3 |
| May 26 • 19:15 | Alexandr Dolgopolov | | - | | Andreas Haider-Maurer | 3 | : | 0 |
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| May 27 • 11:00 | David Ferrer | | - | | Sergiy Stakhovsky | 3 | : | 0 |
| May 27 • 13:00 | Janko Tipsarević | | - | | Roger Federer | 0 | : | 3 |
| May 27 • 13:15 | Fabio Fognini | | - | | Guillermo García López | 3 | : | 1 |
| May 27 • 13:55 | Albert Montañés | | - | | Mikhail Youzhny | 3 | : | 0 |
| May 27 • 14:15 | Steve Darcis | | - | | Gaël Monfils | 0 | : | 3 |
| May 27 • 15:55 | Stanislas Wawrinka | | - | | Jo-Wilfried Tsonga | 3 | : | 2 |
| May 27 • 16:30 | Richard Gasquet | | - | | Thomaz Bellucci | 3 | : | 1 |
| May 27 • 19:40 | Juan Martín del Potro | | - | | Novak Djokovic | 1 | : | 3 |
| May 28 • 11:00 | Alexandr Dolgopolov | | - | | Viktor Troicki | 1 | : | 3 |
| May 28 • 12:30 | Andy Murray | | - | | Michael Berrer | 3 | : | 0 |
| May 28 • 12:40 | Rafael Nadal | | - | | Antonio Veić | 3 | : | 0 |
| May 28 • 12:55 | Juan Ignacio Chela | | - | | Lukáš Rosol | 3 | : | 1 |
| May 28 • 14:45 | Mardy Fish | | - | | Gilles Simon | 0 | : | 3 |
| May 28 • 14:50 | Łukasz Kubot | | - | | Alejandro Falla | 1 | : | 3 |
| May 28 • 16:35 | Ivan Ljubičić | | - | | Fernando Verdasco | 3 | : | 0 |
| May 28 • 18:05 | Leonardo Mayer | | - | | Robin Söderling | 0 | : | 3 |
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| May 29 • 11:00 | Fabio Fognini | | - | | Albert Montañés | 3 | : | 2 |
| May 29 • 14:00 | Stanislas Wawrinka | | - | | Roger Federer | 0 | : | 3 |
| May 29 • 16:10 | Richard Gasquet | | - | | Novak Djokovic | 0 | : | 3 |
| May 29 • 18:30 | David Ferrer | | - | | Gaël Monfils | 2 | : | 3 |
| May 30 • 11:00 | Alejandro Falla | | - | | Juan Ignacio Chela | 2 | : | 3 |
| May 30 • 13:15 | Rafael Nadal | | - | | Ivan Ljubičić | 3 | : | 0 |
| May 30 • 16:00 | Gilles Simon | | - | | Robin Söderling | 0 | : | 3 |
| May 30 • 18:00 | Andy Murray | | - | | Viktor Troicki | 3 | : | 2 |
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| May 31 • 16:00 | Fabio Fognini | | - | | Novak Djokovic | 0 | : | 0 |
| May 31 • 17:10 | Gaël Monfils | | - | | Roger Federer | 0 | : | 3 |
| Jun 01 • 16:00 | Andy Murray | | - | | Juan Ignacio Chela | 3 | : | 0 |
| Jun 01 • 16:00 | Rafael Nadal | | - | | Robin Söderling | 3 | : | 0 |
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| Jun 03 • 14:15 | Rafael Nadal | | - | | Andy Murray | 3 | : | 0 |
| Jun 03 • 18:00 | Roger Federer | | - | | Novak Djokovic | 3 | : | 1 |
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| Jun 05 • 15:00 | Rafael Nadal | | - | | Roger Federer | 3 | : | 1 |
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