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| May 09 • 11:00 | Filip Krajinović |  | - |  | Felix Auger Aliassime | 1 | : | 2 |
| May 09 • 12:30 | Laslo Djere | | - |  | Pablo Carreño Busta | 1 | : | 2 |
| May 09 • 14:00 | Salvatore Caruso |  | - |  | David Goffin | 0 | : | 2 |
| May 09 • 14:00 | Richard Gasquet |  | - |  | Reilly Opelka | 0 | : | 2 |
| May 10 • 10:00 | Daniel Evans |  | - | | Taylor Harry Fritz | 0 | : | 2 |
| May 10 • 10:00 | Yoshihito Nishioka |  | - |  | Márton Fucsovics | 0 | : | 2 |
| May 10 • 10:00 | Stefano Travaglia | | - | | Benoît Paire | 2 | : | 0 |
| May 10 • 11:20 | Miomir Kecmanovic | | - |  | Aslan Karatsev | 0 | : | 2 |
| May 10 • 11:30 | Kei Nishikori | | - | | Fabio Fognini | 2 | : | 0 |
| May 10 • 12:50 | Karen Khachanov | | - |  | Federico Delbonis | 1 | : | 2 |
| May 10 • 13:00 | Lloyd Harris |  | - |  | Cristian Garín | 0 | : | 2 |
| May 10 • 13:00 | Ugo Humbert | | - | | Jannik Sinner | 0 | : | 2 |
| May 10 • 14:50 | Hugo Dellien |  | - | | Adrian Mannarino | 2 | : | 1 |
| May 10 • 16:00 | Aljaž Bedene |  | - |  | Jan-Lennard Struff | 0 | : | 2 |
| May 10 • 16:20 | Gianluca Mager | | - |  | Alex De Minaur | 2 | : | 0 |
| May 10 • 17:50 | Marin Čilić |  | - |  | Alexander Bublik | 2 | : | 1 |
| May 10 • 19:00 | Hubert Hurkacz |  | - | | Lorenzo Musetti | 0 | : | 1 |
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| May 11 • 10:00 | Alejandro Davidovich Fokina | | - |  | Grigor Dimitrov | 2 | : | 0 |
| May 11 • 10:00 | John Millman | | - | | Dušan Lajović | 2 | : | 0 |
| May 11 • 10:00 | Roberto Bautista-Agut | | - | | Tommy Paul | 2 | : | 0 |
| May 11 • 11:30 | Roberto Carballés Baena | | - | | Cameron Norrie | 0 | : | 2 |
| May 11 • 11:30 | Matteo Berrettini | | - |  | Nikoloz Basilashvili | 2 | : | 1 |
| May 11 • 11:30 | Lorenzo Sonego | | - | | Gaël Monfils | 2 | : | 1 |
| May 11 • 11:30 | Denis Shapovalov | | - | | Kamil Majchrzak | 2 | : | 0 |
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| May 11 • 13:30 | Lorenzo Musetti | | - | | Reilly Opelka | 0 | : | 2 |
| May 11 • 13:30 | Kei Nishikori | | - | | Pablo Carreño Busta | 0 | : | 0 |
| May 11 • 14:20 | Novak Djokovic | | - | | Taylor Harry Fritz | 2 | : | 0 |
| May 11 • 15:40 | Diego Schwartzman | | - | | Felix Auger Aliassime | 0 | : | 2 |
| May 12 • 10:00 | Cameron Norrie | | - | | Alejandro Davidovich Fokina | 0 | : | 2 |
| May 12 • 10:00 | Dominic Thiem |  | - | | Márton Fucsovics | 2 | : | 1 |
| May 12 • 10:00 | Roberto Bautista-Agut | | - | | Cristian Garín | 2 | : | 0 |
| May 12 • 11:30 | Gianluca Mager | | - | | Lorenzo Sonego | 0 | : | 2 |
| May 12 • 11:45 | Jan-Lennard Struff | | - | | Andrey Rublev | 1 | : | 2 |
| May 12 • 13:00 | Federico Delbonis | | - | | David Goffin | 2 | : | 0 |
| May 12 • 13:25 | Alexander Zverev | | - | | Hugo Dellien | 2 | : | 0 |
| May 12 • 14:00 | Aslan Karatsev | | - | | Daniil Medvedev | 2 | : | 0 |
| May 12 • 14:30 | Marin Čilić | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
| May 12 • 15:30 | Matteo Berrettini | | - | | John Millman | 2 | : | 0 |
| May 12 • 16:00 | Denis Shapovalov | | - | | Stefano Travaglia | 2 | : | 0 |
| May 12 • 18:50 | Jannik Sinner | | - | | Rafael Nadal | 0 | : | 2 |
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| May 13 • 10:00 | Novak Djokovic | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| May 13 • 10:00 | Reilly Opelka | | - | | Aslan Karatsev | 2 | : | 0 |
| May 13 • 11:00 | Denis Shapovalov | | - | | Rafael Nadal | 1 | : | 2 |
| May 13 • 12:00 | Matteo Berrettini | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| May 13 • 13:00 | Felix Auger Aliassime | | - | | Federico Delbonis | 0 | : | 2 |
| May 13 • 14:30 | Alexander Zverev | | - | | Kei Nishikori | 2 | : | 1 |
| May 13 • 19:00 | Dominic Thiem | | - | | Lorenzo Sonego | 1 | : | 2 |
| May 13 • 19:00 | Roberto Bautista-Agut | | - | | Andrey Rublev | 0 | : | 2 |
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| May 14 • 10:00 | Federico Delbonis | | - | | Reilly Opelka | 0 | : | 2 |
| May 14 • 12:00 | Alexander Zverev | | - | | Rafael Nadal | 0 | : | 2 |
| May 14 • 13:30 | Novak Djokovic | | - | | Stefanos Tsitsipas | 2 | : | 1 |
| May 15 • 11:00 | Lorenzo Sonego | | - | | Andrey Rublev | 2 | : | 1 |
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| May 15 • 15:40 | Reilly Opelka | | - | | Rafael Nadal | 0 | : | 2 |
| May 15 • 18:30 | Novak Djokovic | | - | | Lorenzo Sonego | 2 | : | 1 |
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| May 16 • 17:00 | Novak Djokovic | | - | | Rafael Nadal | 1 | : | 2 |
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