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| Aug 29 • 17:05 | Janko Tipsarević |  | - |  | Augustin Gensse | 3 | : | 0 |
| Aug 29 • 17:05 | Marin Čilić |  | - |  | Ryan Harrison | 3 | : | 0 |
| Aug 29 • 17:05 | Fabio Fognini |  | - |  | Horacio Zeballos | 3 | : | 1 |
| Aug 29 • 17:10 | Alexandr Dolgopolov |  | - |  | Frederico Gil | 3 | : | 0 |
| Aug 29 • 17:10 | Kei Nishikori |  | - | | Flavio Cipolla | 0 | : | 2 |
| Aug 29 • 17:10 | Philipp Petzschner |  | - |  | Albert Ramos-Viñolas | 3 | : | 2 |
| Aug 29 • 17:20 | Marcel Granollers | | - |  | Xavier Malisse | 3 | : | 0 |
| Aug 29 • 18:00 | Tomáš Berdych |  | - | | Romain Jouan | 3 | : | 0 |
| Aug 29 • 18:55 | Mikhail Kukushkin |  | - | | Albert Montañés | 3 | : | 1 |
| Aug 29 • 19:15 | Mardy Fish | | - | | Tobias Kamke | 3 | : | 0 |
| Aug 29 • 19:15 | Richard Gasquet | | - | | Sergiy Stakhovsky | 3 | : | 0 |
| Aug 29 • 19:25 | Michaël Llodra | | - |  | Victor Hănescu | 3 | : | 2 |
| Aug 29 • 19:30 | Michael Yani | | - |  | Bernard Tomic | 0 | : | 3 |
| Aug 29 • 19:30 | Juan Mónaco | | - | | Andreas Seppi | 3 | : | 0 |
| Aug 29 • 20:05 | Ivo Karlović | | - |  | Fernando Gonzalez | 3 | : | 0 |
| Aug 29 • 20:45 | Kevin Anderson |  | - | | Go Soeda | 3 | : | 0 |
| Aug 29 • 21:30 | Tommy Haas | | - | | Jonathan Dasnières de Veigy | 3 | : | 1 |
| Aug 29 • 21:35 | Malek Jaziri |  | - |  | Thiemo de Bakker | 3 | : | 1 |
| Aug 29 • 21:40 | Radek Štěpánek | | - | | Philipp Kohlschreiber | 3 | : | 0 |
| Aug 29 • 22:00 | Viktor Troicki | | - |  | Alejandro Falla | 2 | : | 3 |
| Aug 29 • 22:15 | Dudi Sela |  | - |  | Thomaz Bellucci | 3 | : | 2 |
| Aug 30 • 00:45 | Pablo Andújar | | - | | Juan Carlos Ferrero | 2 | : | 3 |
| Aug 30 • 01:00 | Gaël Monfils | | - |  | Grigor Dimitrov | 3 | : | 0 |
| Aug 30 • 03:00 | Roger Federer |  | - | | Santiago Giraldo | 3 | : | 0 |
| Aug 30 • 17:10 | David Ferrer | | - |  | Igor Andreev | 3 | : | 1 |
| Aug 30 • 17:10 | Jo-Wilfried Tsonga | | - |  | Lu Yen-Hsun | 3 | : | 0 |
| Aug 30 • 17:10 | Potito Starace | | - | | Michael Berrer | 3 | : | 1 |
| Aug 30 • 17:10 | Matthias Bachinger | | - | | Igor Kunitsyn | 2 | : | 3 |
| Aug 30 • 17:15 | Andreas Haider-Maurer |  | - | | Sergei Bubka | 1 | : | 3 |
| Aug 30 • 18:20 | Mikhail Youzhny | | - |  | Ernests Gulbis | 0 | : | 3 |
| Aug 30 • 18:40 | Donald Young | | - |  | Lukáš Lacko | 3 | : | 0 |
| Aug 30 • 18:50 | Jürgen Melzer | | - | | Éric Prodon | 3 | : | 0 |
| Aug 30 • 19:00 | Stanislas Wawrinka | | - | | Máximo González | 3 | : | 1 |
| Aug 30 • 19:00 | Ivan Dodig | | - | | Nikolay Davydenko | 2 | : | 3 |
| Aug 30 • 19:20 | Marsel İlhan |  | - |  | Frank Dancevic | 2 | : | 0 |
| Aug 30 • 19:30 | Édouard Roger-Vasselin | | - |  | Gilles Müller | 0 | : | 3 |
| Aug 30 • 19:45 | Dmitry Tursunov | | - | | Steve Darcis | 2 | : | 3 |
| Aug 30 • 20:10 | Olivier Rochus | | - |  | Jean-René Lisnard | 0 | : | 3 |
| Aug 30 • 20:50 | Novak Djokovic | | - |  | Conor Niland | 1 | : | 0 |
| Aug 30 • 21:00 | Fernando Verdasco | | - |  | Jarkko Nieminen | 3 | : | 1 |
| Aug 30 • 21:00 | Florian Mayer | | - | | Adrian Mannarino | 3 | : | 0 |
| Aug 30 • 21:15 | Juan Ignacio Chela | | - | | Marinko Matosevic | 0 | : | 0 |
| Aug 30 • 23:00 | Ivan Ljubičić | | - |  | Blaž Kavčič | 3 | : | 1 |
| Aug 30 • 23:00 | Pere Riba | | - | | Carlos Berlocq | 0 | : | 3 |
| Aug 30 • 23:00 | Bobby Reynolds | | - | | David Nalbandian | 1 | : | 3 |
| Aug 30 • 23:00 | Nicolas Mahut | | - | | Robert Farah | 3 | : | 2 |
| Aug 30 • 23:30 | James Blake | | - | | Jesse Huta Galung | 3 | : | 1 |
| Aug 31 • 01:00 | Rafael Nadal | | - | | Andrey Golubev | 3 | : | 0 |
| Aug 31 • 17:05 | Rogério Dutra da Silva | | - | | Louk Sorensen | 2 | : | 1 |
| Aug 31 • 17:05 | Nicolás Almagro | | - | | Julien Benneteau | 0 | : | 3 |
| Aug 31 • 17:05 | Feliciano López | | - | | Tatsuma Ito | 3 | : | 0 |
| Aug 31 • 17:05 | Vasek Pospisil | | - | | Lukáš Rosol | 3 | : | 0 |
| Aug 31 • 17:10 | Guillermo García López | | - | | Daniel Gimeno-Traver | 3 | : | 2 |
| Aug 31 • 18:30 | Rui Machado | | - | | Robin Haase | 0 | : | 3 |
| Aug 31 • 18:35 | Denis Istomin |  | - | | Ryan Sweeting | 3 | : | 1 |
| Aug 31 • 18:50 | Diego Junqueira | | - | | Karol Beck | 1 | : | 0 |
| Aug 31 • 19:30 | Alex Bogomolov Jr | | - | | Steve Johnson | 3 | : | 2 |
| Aug 31 • 19:50 | Andy Murray |  | - |  | Somdev Devvarman | 3 | : | 0 |
| Aug 31 • 19:50 | Juan Martín del Potro | | - | | Filippo Volandri | 3 | : | 0 |
| Aug 31 • 20:25 | Gilles Simon | | - | | Ricardo Mello | 3 | : | 2 |
| Aug 31 • 22:15 | Robby Ginepri | | - | | João Souza | 3 | : | 1 |
| Aug 31 • 23:00 | John Isner | | - |  | Marcos Baghdatis | 3 | : | 1 |
| Aug 31 • 23:00 | Jack Sock | | - | | Marc Gicquel | 3 | : | 1 |
| Sep 01 • 01:00 | Andy Roddick | | - | | Michael Russell | 3 | : | 1 |
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| Sep 01 • 17:00 | Tomáš Berdych | | - | | Fabio Fognini | 3 | : | 0 |
| Sep 01 • 17:10 | Philipp Petzschner | | - | | Janko Tipsarević | 1 | : | 3 |
| Sep 01 • 17:10 | Radek Štěpánek | | - | | Juan Mónaco | 0 | : | 2 |
| Sep 01 • 17:20 | Michaël Llodra | | - | | Kevin Anderson | 0 | : | 3 |
| Sep 01 • 18:45 | Juan Carlos Ferrero | | - | | Gaël Monfils | 3 | : | 2 |
| Sep 01 • 18:45 | Tommy Haas | | - | | Alejandro Falla | 3 | : | 0 |
| Sep 01 • 19:10 | Roger Federer | | - | | Dudi Sela | 3 | : | 0 |
| Sep 01 • 20:15 | Marcel Granollers | | - | | Mikhail Kukushkin | 3 | : | 0 |
| Sep 01 • 21:25 | Jo-Wilfried Tsonga | | - | | Sergei Bubka | 3 | : | 0 |
| Sep 01 • 22:10 | Bernard Tomic | | - | | Marin Čilić | 0 | : | 3 |
| Sep 01 • 22:50 | Potito Starace | | - | | Nikolay Davydenko | 0 | : | 3 |
| Sep 01 • 23:00 | Alexandr Dolgopolov | | - | | Flavio Cipolla | 3 | : | 2 |
| Sep 01 • 23:15 | Marsel İlhan | | - | | Fernando Verdasco | 0 | : | 3 |
| Sep 01 • 23:40 | Ivo Karlović | | - | | Richard Gasquet | 3 | : | 1 |
| Sep 02 • 00:00 | Malek Jaziri | | - | | Mardy Fish | 0 | : | 3 |
| Sep 02 • 01:00 | Novak Djokovic | | - | | Carlos Berlocq | 3 | : | 0 |
| Sep 02 • 17:10 | Denis Istomin | | - | | Julien Benneteau | 0 | : | 3 |
| Sep 02 • 17:10 | Juan Martín del Potro | | - | | Diego Junqueira | 3 | : | 0 |
| Sep 02 • 18:35 | Ernests Gulbis | | - | | Gilles Müller | 1 | : | 3 |
| Sep 02 • 18:55 | Stanislas Wawrinka | | - | | Donald Young | 2 | : | 3 |
| Sep 02 • 19:05 | Steve Darcis | | - | | Juan Ignacio Chela | 0 | : | 3 |
| Sep 02 • 19:10 | John Isner | | - | | Robby Ginepri | 3 | : | 0 |
| Sep 02 • 19:40 | Guillermo García López | | - | | Gilles Simon | 1 | : | 3 |
| Sep 02 • 20:05 | Igor Kunitsyn | | - | | Jürgen Melzer | 3 | : | 2 |
| Sep 02 • 20:55 | Feliciano López | | - | | Vasek Pospisil | 3 | : | 1 |
| Sep 02 • 21:30 | Robin Haase | | - | | Andy Murray | 2 | : | 3 |
| Sep 02 • 21:50 | Ivan Ljubičić | | - | | David Nalbandian | 1 | : | 3 |
| Sep 02 • 22:40 | Nicolas Mahut | | - | | Rafael Nadal | 0 | : | 2 |
| Sep 02 • 23:15 | David Ferrer | | - | | James Blake | 3 | : | 0 |
| Sep 02 • 23:30 | Rogério Dutra da Silva | | - | | Alex Bogomolov Jr | 0 | : | 3 |
| Sep 03 • 01:45 | Jean-René Lisnard | | - | | Florian Mayer | 0 | : | 3 |
| Sep 03 • 03:00 | Andy Roddick | | - | | Jack Sock | 3 | : | 0 |
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| Sep 03 • 17:10 | Tomáš Berdych | | - | | Janko Tipsarević | 0 | : | 1 |
| Sep 03 • 18:45 | Marcel Granollers | | - | | Juan Carlos Ferrero | 0 | : | 1 |
| Sep 03 • 19:20 | Roger Federer | | - | | Marin Čilić | 3 | : | 1 |
| Sep 03 • 20:20 | Alexandr Dolgopolov | | - | | Ivo Karlović | 3 | : | 1 |
| Sep 03 • 20:55 | Kevin Anderson | | - | | Mardy Fish | 0 | : | 3 |
| Sep 03 • 21:55 | Juan Mónaco | | - | | Tommy Haas | 3 | : | 1 |
| Sep 03 • 23:55 | Jo-Wilfried Tsonga | | - | | Fernando Verdasco | 3 | : | 0 |
| Sep 04 • 02:15 | Novak Djokovic | | - | | Nikolay Davydenko | 3 | : | 0 |
| Sep 04 • 17:10 | David Nalbandian | | - | | Rafael Nadal | 0 | : | 3 |
| Sep 04 • 18:05 | Gilles Müller | | - | | Igor Kunitsyn | 3 | : | 0 |
| Sep 04 • 19:00 | David Ferrer | | - | | Florian Mayer | 3 | : | 0 |
| Sep 04 • 20:05 | Juan Martín del Potro | | - | | Gilles Simon | 1 | : | 3 |
| Sep 04 • 20:15 | Andy Roddick | | - | | Julien Benneteau | 3 | : | 0 |
| Sep 04 • 20:40 | Donald Young | | - | | Juan Ignacio Chela | 3 | : | 0 |
| Sep 05 • 00:20 | Alex Bogomolov Jr | | - | | John Isner | 0 | : | 3 |
| Sep 05 • 01:00 | Feliciano López | | - | | Andy Murray | 0 | : | 3 |
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| Sep 05 • 17:00 | Janko Tipsarević | | - | | Juan Carlos Ferrero | 3 | : | 1 |
| Sep 05 • 21:15 | Novak Djokovic | | - | | Alexandr Dolgopolov | 3 | : | 0 |
| Sep 05 • 22:00 | Jo-Wilfried Tsonga | | - | | Mardy Fish | 3 | : | 2 |
| Sep 06 • 03:00 | Roger Federer | | - | | Juan Mónaco | 3 | : | 0 |
| Sep 07 • 18:00 | David Ferrer | | - | | Andy Roddick | 1 | : | 3 |
| Sep 07 • 18:00 | Gilles Müller | | - | | Rafael Nadal | 0 | : | 3 |
| Sep 07 • 18:00 | Donald Young | | - | | Andy Murray | 0 | : | 3 |
| Sep 08 • 17:00 | John Isner | | - | | Gilles Simon | 3 | : | 1 |
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| Sep 08 • 21:00 | Novak Djokovic | | - | | Janko Tipsarević | 2 | : | 1 |
| Sep 09 • 01:00 | Roger Federer | | - | | Jo-Wilfried Tsonga | 3 | : | 0 |
| Sep 09 • 18:40 | John Isner | | - | | Andy Murray | 1 | : | 3 |
| Sep 09 • 22:30 | Andy Roddick | | - | | Rafael Nadal | 0 | : | 3 |
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| Sep 10 • 18:00 | Novak Djokovic | | - | | Roger Federer | 3 | : | 2 |
| Sep 10 • 18:00 | Andy Murray | | - | | Rafael Nadal | 1 | : | 3 |
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| Sep 12 • 22:00 | Novak Djokovic | | - | | Rafael Nadal | 3 | : | 1 |
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