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| Jun 25 • 12:30 | Mikhail Youzhny |  | - |  | Donald Young | 3 | : | 1 |
| Jun 25 • 12:35 | Julien Benneteau |  | - |  | Gilles Müller | 3 | : | 0 |
| Jun 25 • 12:40 | Fernando Verdasco |  | - |  | Jimmy Wang | 3 | : | 0 |
| Jun 25 • 12:40 | Richard Gasquet | | - |  | Tobias Kamke | 3 | : | 0 |
| Jun 25 • 12:40 | Carlos Berlocq |  | - |  | Ruben Bemelmans | 1 | : | 3 |
| Jun 25 • 12:40 | Adrián Menéndez-Maceiras | | - | | Michael Russell | 0 | : | 3 |
| Jun 25 • 12:40 | Ryan Sweeting | | - |  | Potito Starace | 1 | : | 0 |
| Jun 25 • 13:55 | Grega Žemlja |  | - |  | Josh Goodall | 3 | : | 1 |
| Jun 25 • 14:00 | Novak Djokovic |  | - | | Juan Carlos Ferrero | 3 | : | 0 |
| Jun 25 • 14:00 | Janko Tipsarević | | - | | David Nalbandian | 3 | : | 0 |
| Jun 25 • 14:10 | Benjamin Becker | | - | | James Blake | 3 | : | 1 |
| Jun 25 • 14:10 | Martin Kližan |  | - | | Juan Ignacio Chela | 3 | : | 2 |
| Jun 25 • 14:10 | Inigo Cervantes | | - | | Flavio Cipolla | 3 | : | 2 |
| Jun 25 • 14:15 | Fabio Fognini | | - | | Michaël Llodra | 3 | : | 1 |
| Jun 25 • 14:25 | Marcel Granollers | | - | | Viktor Troicki | 2 | : | 3 |
| Jun 25 • 15:30 | Gilles Simon | | - | | Paul-Henri Mathieu | 1 | : | 0 |
| Jun 25 • 16:00 | Philipp Petzschner | | - | | Blaž Kavčič | 3 | : | 0 |
| Jun 25 • 16:15 | Radek Štěpánek |  | - |  | Sergiy Stakhovsky | 1 | : | 0 |
| Jun 25 • 16:20 | Juan Mónaco | | - | | Leonardo Mayer | 3 | : | 0 |
| Jun 25 • 16:45 | John Isner | | - |  | Alejandro Falla | 2 | : | 3 |
| Jun 25 • 16:50 | Jérémy Chardy | | - | | Filippo Volandri | 2 | : | 0 |
| Jun 25 • 16:55 | Florian Mayer | | - | | Dmitry Tursunov | 3 | : | 0 |
| Jun 25 • 17:00 | Roger Federer |  | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| Jun 25 • 17:00 | Ryan Harrison | | - | | Lu Yen-Hsun | 3 | : | 1 |
| Jun 25 • 17:15 | Igor Andreev | | - | | Oliver Golding | 3 | : | 1 |
| Jun 25 • 17:35 | Tomáš Berdych | | - |  | Ernests Gulbis | 0 | : | 3 |
| Jun 25 • 18:20 | Xavier Malisse | | - |  | Marinko Matosevic | 3 | : | 0 |
| Jun 25 • 18:30 | Andreas Seppi | | - |  | Denis Istomin | 2 | : | 3 |
| Jun 25 • 18:30 | Guillaume Rufin | | - | | Steve Darcis | 3 | : | 2 |
| Jun 25 • 18:45 | Simone Bolelli | | - |  | Jerzy Janowicz | 1 | : | 3 |
| Jun 25 • 18:50 | Paolo Lorenzi | | - | | Nicolas Mahut | 2 | : | 3 |
| Jun 25 • 19:10 | Nicolás Almagro | | - | | Olivier Rochus | 3 | : | 2 |
| Jun 26 • 12:30 | Mardy Fish | | - | | Rubén Ramírez Hidalgo | 3 | : | 0 |
| Jun 26 • 12:30 | Feliciano López | | - |  | Jarkko Nieminen | 1 | : | 3 |
| Jun 26 • 12:30 | Kei Nishikori |  | - |  | Mikhail Kukushkin | 3 | : | 0 |
| Jun 26 • 12:30 | Alexandr Dolgopolov | | - | | Alex Bogomolov Jr | 3 | : | 0 |
| Jun 26 • 12:30 | Brian Baker | | - |  | Rui Machado | 3 | : | 0 |
| Jun 26 • 12:30 | Matthew Ebden | | - | | Benoît Paire | 1 | : | 3 |
| Jun 26 • 12:30 | Jurgen Zopp |  | - |  | Malek Jaziri | 2 | : | 3 |
| Jun 26 • 12:45 | Bernard Tomic | | - | | David Goffin | 1 | : | 3 |
| Jun 26 • 12:45 | Édouard Roger-Vasselin | | - | | Guillermo García López | 2 | : | 3 |
| Jun 26 • 12:45 | Jesse Levine | | - | | Karol Beck | 3 | : | 1 |
| Jun 26 • 14:45 | Andrey Kuznetsov | | - | | Florent Serra | 2 | : | 3 |
| Jun 26 • 14:50 | Go Soeda | | - | | Igor Kunitsyn | 3 | : | 0 |
| Jun 26 • 15:00 | Jo-Wilfried Tsonga | | - | | Lleyton Hewitt | 3 | : | 0 |
| Jun 26 • 15:05 | Kevin Anderson |  | - |  | Grigor Dimitrov | 1 | : | 3 |
| Jun 26 • 15:15 | James Ward | | - | | Pablo Andújar | 3 | : | 2 |
| Jun 26 • 16:20 | Lukáš Lacko | | - |  | Adrian Ungur | 3 | : | 0 |
| Jun 26 • 16:25 | Rafael Nadal | | - |  | Thomaz Bellucci | 3 | : | 0 |
| Jun 26 • 16:35 | Philipp Kohlschreiber | | - | | Tommy Haas | 3 | : | 2 |
| Jun 26 • 16:50 | Lukáš Rosol | | - |  | Ivan Dodig | 3 | : | 1 |
| Jun 26 • 17:20 | Albert Montañés | | - |  | Marcos Baghdatis | 0 | : | 3 |
| Jun 26 • 17:45 | Marin Čilić | | - | | Cedrik-Marcel Stebe | 3 | : | 1 |
| Jun 26 • 17:45 | Stanislas Wawrinka | | - |  | Jürgen Melzer | 2 | : | 3 |
| Jun 26 • 18:00 | Juan Martín del Potro | | - |  | Robin Haase | 3 | : | 1 |
| Jun 26 • 18:20 | Kenny de Schepper | | - | | Matthias Bachinger | 3 | : | 0 |
| Jun 26 • 18:25 | Wayne Odesnik | | - | | Björn Phau | 2 | : | 3 |
| Jun 26 • 18:30 | Vasek Pospisil |  | - | | Sam Querrey | 1 | : | 3 |
| Jun 26 • 19:00 | Andy Murray | | - | | Nikolay Davydenko | 3 | : | 0 |
| Jun 26 • 19:15 | Tatsuma Ito | | - | | Łukasz Kubot | 0 | : | 3 |
| Jun 26 • 19:35 | Andy Roddick | | - | | Jamie Baker | 3 | : | 0 |
| Jun 26 • 19:45 | David Ferrer | | - | | Dustin Brown | 3 | : | 0 |
| Jun 26 • 19:50 | Milos Raonic | | - | | Santiago Giraldo | 3 | : | 0 |
| Jun 26 • 20:10 | Ivo Karlović | | - |  | Dudi Sela | 3 | : | 0 |
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| Jun 27 • 12:25 | Florian Mayer | | - | | Philipp Petzschner | 3 | : | 2 |
| Jun 27 • 12:30 | Jérémy Chardy | | - | | Juan Mónaco | 1 | : | 3 |
| Jun 27 • 14:00 | Roger Federer | | - | | Fabio Fognini | 3 | : | 0 |
| Jun 27 • 14:05 | Viktor Troicki | | - | | Martin Kližan | 3 | : | 2 |
| Jun 27 • 14:15 | Ryan Sweeting | | - | | Janko Tipsarević | 1 | : | 3 |
| Jun 27 • 15:15 | Jerzy Janowicz | | - | | Ernests Gulbis | 3 | : | 2 |
| Jun 27 • 15:15 | Igor Andreev | | - | | Denis Istomin | 1 | : | 3 |
| Jun 27 • 15:50 | Michael Russell | | - | | Julien Benneteau | 1 | : | 3 |
| Jun 27 • 20:00 | Alejandro Falla | | - | | Nicolas Mahut | 3 | : | 2 |
| Jun 27 • 20:00 | Mikhail Youzhny | | - | | Inigo Cervantes | 3 | : | 0 |
| Jun 27 • 20:00 | Nicolás Almagro | | - | | Guillaume Rufin | 3 | : | 1 |
| Jun 27 • 20:20 | Ruben Bemelmans | | - | | Richard Gasquet | 0 | : | 3 |
| Jun 27 • 20:45 | Benjamin Becker | | - | | Radek Štěpánek | 0 | : | 3 |
| Jun 27 • 21:00 | Novak Djokovic | | - | | Ryan Harrison | 3 | : | 0 |
| Jun 28 • 12:30 | Xavier Malisse | | - | | Gilles Simon | 3 | : | 0 |
| Jun 28 • 12:30 | Jarkko Nieminen | | - | | Brian Baker | 0 | : | 3 |
| Jun 28 • 12:30 | Kei Nishikori | | - | | Florent Serra | 3 | : | 0 |
| Jun 28 • 12:30 | David Goffin | | - | | Jesse Levine | 3 | : | 1 |
| Jun 28 • 12:45 | Fernando Verdasco | | - | | Grega Žemlja | 3 | : | 1 |
| Jun 28 • 14:00 | David Ferrer | | - | | Kenny de Schepper | 3 | : | 0 |
| Jun 28 • 14:15 | Lukáš Lacko | | - | | Jürgen Melzer | 3 | : | 2 |
| Jun 28 • 15:30 | Ivo Karlović | | - | | Andy Murray | 1 | : | 3 |
| Jun 28 • 15:35 | James Ward | | - | | Mardy Fish | 2 | : | 3 |
| Jun 28 • 16:00 | Benoît Paire | | - | | Alexandr Dolgopolov | 3 | : | 0 |
| Jun 28 • 16:05 | Marin Čilić | | - | | Łukasz Kubot | 3 | : | 0 |
| Jun 28 • 16:20 | Björn Phau | | - | | Andy Roddick | 0 | : | 3 |
| Jun 28 • 17:05 | Philipp Kohlschreiber | | - | | Malek Jaziri | 3 | : | 0 |
| Jun 28 • 17:10 | Jo-Wilfried Tsonga | | - | | Guillermo García López | 3 | : | 1 |
| Jun 28 • 17:20 | Go Soeda | | - | | Juan Martín del Potro | 1 | : | 3 |
| Jun 28 • 17:50 | Grigor Dimitrov | | - | | Marcos Baghdatis | 0 | : | 1 |
| Jun 28 • 18:30 | Lukáš Rosol | | - | | Rafael Nadal | 3 | : | 2 |
| Jun 28 • 18:30 | Sam Querrey | | - | | Milos Raonic | 3 | : | 1 |
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| Jun 29 • 12:30 | Viktor Troicki | | - | | Juan Mónaco | 3 | : | 0 |
| Jun 29 • 14:20 | Novak Djokovic | | - | | Radek Štěpánek | 3 | : | 1 |
| Jun 29 • 16:25 | Fernando Verdasco | | - | | Xavier Malisse | 2 | : | 3 |
| Jun 29 • 16:30 | Alejandro Falla | | - | | Denis Istomin | 1 | : | 3 |
| Jun 29 • 18:20 | Florian Mayer | | - | | Jerzy Janowicz | 3 | : | 2 |
| Jun 29 • 18:45 | Roger Federer | | - | | Julien Benneteau | 3 | : | 2 |
| Jun 29 • 18:45 | Mikhail Youzhny | | - | | Janko Tipsarević | 3 | : | 1 |
| Jun 29 • 19:05 | Nicolás Almagro | | - | | Richard Gasquet | 0 | : | 3 |
| Jun 30 • 12:30 | Brian Baker | | - | | Benoît Paire | 3 | : | 1 |
| Jun 30 • 14:10 | Philipp Kohlschreiber | | - | | Lukáš Rosol | 3 | : | 0 |
| Jun 30 • 15:25 | Kei Nishikori | | - | | Juan Martín del Potro | 0 | : | 3 |
| Jun 30 • 16:00 | David Ferrer | | - | | Andy Roddick | 3 | : | 1 |
| Jun 30 • 16:30 | David Goffin | | - | | Mardy Fish | 0 | : | 3 |
| Jun 30 • 16:30 | Marin Čilić | | - | | Sam Querrey | 3 | : | 2 |
| Jun 30 • 18:10 | Jo-Wilfried Tsonga | | - | | Lukáš Lacko | 3 | : | 0 |
| Jun 30 • 20:10 | Marcos Baghdatis | | - | | Andy Murray | 1 | : | 3 |
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| Jul 02 • 13:00 | Denis Istomin | | - | | Mikhail Youzhny | 2 | : | 3 |
| Jul 02 • 14:00 | Roger Federer | | - | | Xavier Malisse | 3 | : | 1 |
| Jul 02 • 16:30 | Marin Čilić | | - | | Andy Murray | 0 | : | 3 |
| Jul 02 • 17:00 | Jo-Wilfried Tsonga | | - | | Mardy Fish | 3 | : | 1 |
| Jul 02 • 17:15 | Richard Gasquet | | - | | Florian Mayer | 1 | : | 3 |
| Jul 02 • 18:00 | Brian Baker | | - | | Philipp Kohlschreiber | 0 | : | 3 |
| Jul 02 • 19:20 | Novak Djokovic | | - | | Viktor Troicki | 3 | : | 0 |
| Jul 02 • 19:30 | David Ferrer | | - | | Juan Martín del Potro | 3 | : | 0 |
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| Jul 04 • 14:10 | Roger Federer | | - | | Mikhail Youzhny | 3 | : | 0 |
| Jul 04 • 14:10 | Novak Djokovic | | - | | Florian Mayer | 3 | : | 0 |
| Jul 04 • 16:00 | David Ferrer | | - | | Andy Murray | 1 | : | 3 |
| Jul 04 • 16:00 | Jo-Wilfried Tsonga | | - | | Philipp Kohlschreiber | 3 | : | 1 |
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| Jul 06 • 14:00 | Novak Djokovic | | - | | Roger Federer | 1 | : | 3 |
| Jul 06 • 17:00 | Andy Murray | | - | | Jo-Wilfried Tsonga | 3 | : | 1 |
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| Jul 08 • 15:00 | Roger Federer | | - | | Andy Murray | 3 | : | 1 |
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