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| Jun 27 • 12:00 | Nikoloz Basilashvili |  | - |  | Lukáš Rosol | 3 | : | 2 |
| Jun 27 • 12:00 | Benoît Paire |  | - | | Quentin Halys | 1 | : | 3 |
| Jun 27 • 12:00 | Casper Ruud |  | - |  | Albert Ramos-Viñolas | 3 | : | 0 |
| Jun 27 • 12:00 | Tomás Martín Etcheverry |  | - | | Ugo Humbert | 2 | : | 3 |
| Jun 27 • 12:00 | Frances Tiafoe |  | - |  | Andrea Vavassori | 3 | : | 0 |
| Jun 27 • 12:00 | Maximilian Marterer |  | - |  | Aljaž Bedene | 3 | : | 1 |
| Jun 27 • 12:00 | Cameron Norrie |  | - | | Pablo Andújar | 3 | : | 0 |
| Jun 27 • 12:00 | Thiago Moura Monteiro |  | - | | Jaume Munar | 0 | : | 3 |
| Jun 27 • 12:00 | Tommy Paul | | - | | Fernando Verdasco | 3 | : | 0 |
| Jun 27 • 12:00 | Adrian Mannarino | | - |  | Max Purcell | 3 | : | 2 |
| Jun 27 • 12:00 | Alejandro Davidovich Fokina | | - |  | Hubert Hurkacz | 3 | : | 2 |
| Jun 27 • 13:30 | Thanasi Kokkinakis | | - | | Kamil Majchrzak | 3 | : | 0 |
| Jun 27 • 13:30 | Alejandro Tabilo |  | - |  | Laslo Djere | 3 | : | 2 |
| Jun 27 • 13:30 | Enzo Couacaud | | - | | John Isner | 2 | : | 3 |
| Jun 27 • 14:00 | Federico Coria | | - | | Jiří Veselý | 0 | : | 3 |
| Jun 27 • 14:30 | Novak Djokovic | | - |  | Kwon Soon-woo | 3 | : | 1 |
| Jun 27 • 15:30 | Jan-Lennard Struff | | - | | Carlos Alcaraz | 2 | : | 3 |
| Jun 27 • 18:30 | Tim van Rijthoven |  | - | | Federico Delbonis | 3 | : | 0 |
| Jun 27 • 18:45 | Jannik Sinner | | - |  | Stanislas Wawrinka | 3 | : | 1 |
| Jun 27 • 19:15 | John Millman | | - | | Miomir Kecmanovic | 1 | : | 3 |
| Jun 27 • 19:20 | Tallon Griekspoor | | - | | Fabio Fognini | 3 | : | 1 |
| Jun 27 • 19:30 | Dušan Lajović | | - | | Pablo Carreño Busta | 1 | : | 1 |
| Jun 27 • 19:40 | Andy Murray | | - | | James Duckworth | 3 | : | 1 |
| Jun 27 • 19:55 | Carlos Taberner | | - | | Reilly Opelka | 0 | : | 3 |
| Jun 27 • 20:00 | Jay Clarke | | - | | Christian Harrison | 0 | : | 3 |
| Jun 27 • 20:10 | Alexander Bublik |  | - |  | Márton Fucsovics | 3 | : | 0 |
| Jun 27 • 20:30 | Daniel Altmaier | | - |  | Mikael Ymer | 0 | : | 3 |
| Jun 27 • 20:40 | Oscar Otte | | - | | Peter Gojowczyk | 3 | : | 0 |
| Jun 28 • 12:00 | David Goffin |  | - |  | Radu Albot | 3 | : | 0 |
| Jun 28 • 12:00 | Taro Daniel |  | - | | Sebastián Báez | 0 | : | 3 |
| Jun 28 • 12:00 | Ryan Peniston | | - | | Henri Laaksonen | 3 | : | 0 |
| Jun 28 • 12:00 | Steve Johnson | | - |  | Grigor Dimitrov | 0 | : | 0 |
| Jun 28 • 12:00 | Marc-Andrea Hüsler | | - | | Hugo Grenier | 2 | : | 3 |
| Jun 28 • 13:30 | Paul Jubb | | - | | Nick Kyrgios | 2 | : | 3 |
| Jun 28 • 13:30 | João Sousa |  | - | | Richard Gasquet | 2 | : | 3 |
| Jun 28 • 13:50 | Pedro Martínez | | - |  | Alex Molcan | 1 | : | 3 |
| Jun 28 • 13:55 | Mikhail Kukushkin | | - | | Jenson Brooksby | 0 | : | 3 |
| Jun 28 • 14:00 | Alex De Minaur | | - |  | Hugo Dellien | 3 | : | 0 |
| Jun 28 • 14:20 | Sam Querrey | | - |  | Ričardas Berankis | 0 | : | 3 |
| Jun 28 • 14:50 | Zdeněk Kolář | | - | | Benjamin Bonzi | 0 | : | 3 |
| Jun 28 • 15:05 | Elias Ymer | | - | | Cristian Garín | 0 | : | 3 |
| Jun 28 • 15:30 | Alexei Popyrin | | - | | Hugo Gaston | 2 | : | 3 |
| Jun 28 • 15:40 | Holger Rune |  | - | | Marcos Giron | 0 | : | 3 |
| Jun 28 • 15:45 | Bernabe Zapata Miralles | | - | | Jack Sock | 0 | : | 3 |
| Jun 28 • 15:45 | Nuno Borges | | - | | Mackenzie McDonald | 0 | : | 3 |
| Jun 28 • 16:20 | Zizou Bergs | | - | | Jack Draper | 0 | : | 3 |
| Jun 28 • 16:20 | Lorenzo Sonego | | - | | Denis Kudla | 3 | : | 2 |
| Jun 28 • 16:20 | Francisco Cerundolo | | - | | Rafael Nadal | 1 | : | 3 |
| Jun 28 • 16:30 | Filip Krajinović | | - | | Jiří Lehečka | 3 | : | 2 |
| Jun 28 • 16:35 | Roberto Carballés Baena | | - | | Jordan Thompson | 0 | : | 3 |
| Jun 28 • 16:40 | Felix Auger Aliassime |  | - | | Maxime Cressy | 1 | : | 3 |
| Jun 28 • 17:15 | Feliciano López | | - | | Botic van de Zandschulp | 0 | : | 3 |
| Jun 28 • 17:25 | Alastair Gray | | - |  | Tseng Chun-hsin | 3 | : | 0 |
| Jun 28 • 17:25 | Emil Ruusuvuori |  | - | | Yoshihito Nishioka | 3 | : | 1 |
| Jun 28 • 17:45 | Stefan Kozlov | | - | | Diego Schwartzman | 0 | : | 3 |
| Jun 28 • 17:45 | Brandon Nakashima | | - | | Nicola Kuhn | 3 | : | 1 |
| Jun 28 • 18:05 | Liam Broady | | - | | Lukáš Klein | 3 | : | 2 |
| Jun 28 • 18:05 | Denis Shapovalov | | - | | Arthur Rinderknech | 3 | : | 2 |
| Jun 28 • 18:20 | Dennis Novak |  | - | | Facundo Bagnis | 3 | : | 1 |
| Jun 28 • 18:25 | Alexander Ritschard | | - |  | Stefanos Tsitsipas | 1 | : | 3 |
| Jun 28 • 18:30 | Daniel Elahi Galán |  | - | | Dominik Koepfer | 3 | : | 0 |
| Jun 28 • 18:45 | Attila Balazs | | - | | Roberto Bautista-Agut | 0 | : | 3 |
| Jun 28 • 18:45 | Jason Kubler | | - | | Daniel Evans | 3 | : | 0 |
| Jun 28 • 18:45 | Lorenzo Musetti | | - | | Taylor Harry Fritz | 0 | : | 3 |
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| Jun 29 • 12:00 | Alejandro Tabilo | | - | | Miomir Kecmanovic | 1 | : | 3 |
| Jun 29 • 12:00 | Casper Ruud | | - | | Ugo Humbert | 1 | : | 3 |
| Jun 29 • 12:00 | David Goffin | | - | | Sebastián Báez | 3 | : | 0 |
| Jun 29 • 12:00 | Frances Tiafoe | | - | | Maximilian Marterer | 3 | : | 0 |
| Jun 29 • 12:00 | Ryan Peniston | | - | | Steve Johnson | 0 | : | 3 |
| Jun 29 • 13:30 | Oscar Otte | | - | | Christian Harrison | 0 | : | 0 |
| Jun 29 • 14:00 | Alexander Bublik | | - | | Dušan Lajović | 3 | : | 0 |
| Jun 29 • 14:30 | Novak Djokovic | | - | | Thanasi Kokkinakis | 3 | : | 0 |
| Jun 29 • 15:45 | Cameron Norrie | | - | | Jaume Munar | 3 | : | 2 |
| Jun 29 • 16:15 | Nikoloz Basilashvili | | - | | Quentin Halys | 3 | : | 1 |
| Jun 29 • 17:15 | Jannik Sinner | | - | | Mikael Ymer | 3 | : | 1 |
| Jun 29 • 17:15 | Jiří Veselý | | - | | Alejandro Davidovich Fokina | 3 | : | 2 |
| Jun 29 • 18:10 | Tommy Paul | | - | | Adrian Mannarino | 3 | : | 0 |
| Jun 29 • 18:40 | Tim van Rijthoven | | - | | Reilly Opelka | 3 | : | 1 |
| Jun 29 • 18:45 | Andy Murray | | - | | John Isner | 1 | : | 3 |
| Jun 29 • 18:45 | Tallon Griekspoor | | - | | Carlos Alcaraz | 0 | : | 3 |
| Jun 30 • 12:00 | Marcos Giron | | - | | Alex Molcan | 0 | : | 3 |
| Jun 30 • 12:00 | Alastair Gray | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Jun 30 • 12:00 | Mackenzie McDonald | | - | | Richard Gasquet | 1 | : | 3 |
| Jun 30 • 12:00 | Emil Ruusuvuori | | - | | Botic van de Zandschulp | 1 | : | 3 |
| Jun 30 • 13:15 | Liam Broady | | - | | Diego Schwartzman | 3 | : | 2 |
| Jun 30 • 13:15 | Filip Krajinović | | - | | Nick Kyrgios | 0 | : | 3 |
| Jun 30 • 13:30 | Lorenzo Sonego | | - | | Hugo Gaston | 3 | : | 0 |
| Jun 30 • 14:00 | Jordan Thompson | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Jun 30 • 14:45 | Cristian Garín | | - | | Hugo Grenier | 3 | : | 0 |
| Jun 30 • 15:15 | Benjamin Bonzi | | - | | Jenson Brooksby | 0 | : | 3 |
| Jun 30 • 15:15 | Denis Shapovalov | | - | | Brandon Nakashima | 1 | : | 3 |
| Jun 30 • 15:15 | Daniel Elahi Galán | | - | | Roberto Bautista-Agut | 0 | : | 0 |
| Jun 30 • 15:15 | Dennis Novak | | - | | Jason Kubler | 0 | : | 3 |
| Jun 30 • 15:30 | Maxime Cressy | | - | | Jack Sock | 1 | : | 3 |
| Jun 30 • 15:45 | Ričardas Berankis | | - | | Rafael Nadal | 1 | : | 3 |
| Jun 30 • 18:00 | Alex De Minaur | | - | | Jack Draper | 3 | : | 1 |
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| Jul 01 • 12:00 | Nikoloz Basilashvili | | - | | Tim van Rijthoven | 0 | : | 3 |
| Jul 01 • 12:00 | Frances Tiafoe | | - | | Alexander Bublik | 3 | : | 1 |
| Jul 01 • 14:30 | Tommy Paul | | - | | Jiří Veselý | 3 | : | 0 |
| Jul 01 • 15:00 | Novak Djokovic | | - | | Miomir Kecmanovic | 3 | : | 0 |
| Jul 01 • 15:00 | Ugo Humbert | | - | | David Goffin | 1 | : | 3 |
| Jul 01 • 16:00 | Oscar Otte | | - | | Carlos Alcaraz | 0 | : | 3 |
| Jul 01 • 16:30 | Jannik Sinner | | - | | John Isner | 3 | : | 0 |
| Jul 01 • 18:00 | Cameron Norrie | | - | | Steve Johnson | 3 | : | 0 |
| Jul 02 • 12:00 | Cristian Garín | | - | | Jenson Brooksby | 3 | : | 1 |
| Jul 02 • 12:00 | Jack Sock | | - | | Jason Kubler | 2 | : | 3 |
| Jul 02 • 13:15 | Richard Gasquet | | - | | Botic van de Zandschulp | 1 | : | 3 |
| Jul 02 • 14:00 | Alex De Minaur | | - | | Liam Broady | 3 | : | 0 |
| Jul 02 • 14:30 | Brandon Nakashima | | - | | Daniel Elahi Galán | 3 | : | 0 |
| Jul 02 • 15:20 | Alex Molcan | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Jul 02 • 18:20 | Nick Kyrgios | | - | | Stefanos Tsitsipas | 3 | : | 1 |
| Jul 02 • 18:30 | Lorenzo Sonego | | - | | Rafael Nadal | 0 | : | 3 |
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| Jul 03 • 13:30 | David Goffin | | - | | Frances Tiafoe | 3 | : | 2 |
| Jul 03 • 16:30 | Cameron Norrie | | - | | Tommy Paul | 3 | : | 0 |
| Jul 03 • 16:50 | Jannik Sinner | | - | | Carlos Alcaraz | 3 | : | 1 |
| Jul 03 • 19:30 | Novak Djokovic | | - | | Tim van Rijthoven | 3 | : | 1 |
| Jul 04 • 12:00 | Cristian Garín | | - | | Alex De Minaur | 3 | : | 2 |
| Jul 04 • 14:30 | Brandon Nakashima | | - | | Nick Kyrgios | 2 | : | 3 |
| Jul 04 • 15:15 | Jason Kubler | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Jul 04 • 17:45 | Botic van de Zandschulp | | - | | Rafael Nadal | 0 | : | 3 |
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| Jul 05 • 14:30 | Novak Djokovic | | - | | Jannik Sinner | 3 | : | 2 |
| Jul 05 • 15:15 | David Goffin | | - | | Cameron Norrie | 2 | : | 3 |
| Jul 06 • 14:30 | Cristian Garín | | - | | Nick Kyrgios | 0 | : | 3 |
| Jul 06 • 16:00 | Taylor Harry Fritz | | - | | Rafael Nadal | 2 | : | 3 |
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| Jul 08 • 12:00 | Nick Kyrgios | | - | | Rafael Nadal | 0 | : | 0 |
| Jul 08 • 15:30 | Novak Djokovic | | - | | Cameron Norrie | 3 | : | 1 |
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| Jul 10 • 15:00 | Novak Djokovic | | - | | Nick Kyrgios | 3 | : | 1 |
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