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| Oct 11 • 19:30 | CD Pradejón |  | - |  | Atlético de Lugones | 1 | : | 2 |
| Oct 11 • 20:00 | CP Mijas-Las Lagunas |  | - |  | Chiclana CF | 0 | : | 1 |
| Oct 11 • 21:00 | CD Ceuta 6 de Junio |  | - |  | CD Buñol | 0 | : | 3 |
| Oct 12 • 12:00 | CD Hernán Cortés |  | - |  | CD Sauzal | 3 | : | 1 |
| Oct 12 • 16:30 | Turégano CF |  | - |  | CD Santurtzi | 3 | : | 1 |
| Oct 12 • 17:00 | Tardienta CF |  | - |  | CD Zirauki | 2 | : | 1 |
| Oct 12 • 17:00 | UE Rubí |  | - |  | UD Rotlet Molinar | 0 | : | 0 |
| Oct 12 • 17:30 | CD Monte |  | - |  | CD Boiro | 0 | : | 1 |
| Oct 12 • 17:30 | Melilla CD |  | - |  | Deportivo Murcia | 1 | : | 3 |
| Oct 12 • 17:30 | CD Quintanar De La Orden |  | - |  | CU Zona Norte | 1 | : | 0 |
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| Oct 31 • 20:00 | CD Varea |  | - |  | Levante UD | 0 | : | 3 |
| Oct 31 • 20:00 | CD Mensajero |  | - |  | RCD Espanyol | 0 | : | 2 |
| Oct 31 • 20:45 | CP Cacereño |  | - |  | CD Castellón | 2 | : | 3 |
| Oct 31 • 21:00 | CF Talavera de la Reina |  | - |  | UD Almeria | 0 | : | 2 |
| Oct 31 • 21:00 | CE Manacor |  | - |  | UD Las Palmas | 0 | : | 3 |
| Oct 31 • 21:00 | CF Lorca Deportiva |  | - |  | SD Eibar | 0 | : | 4 |
| Nov 01 • 12:00 | Atlético de Lugones | | - |  | Rayo Vallecano | 0 | : | 6 |
| Nov 01 • 12:00 | CD San Roque de Lepe |  | - |  | Girona FC | 1 | : | 2 |
| Nov 01 • 12:00 | CF Badalona |  | - |  | Cádiz CF | 0 | : | 0 |
| Nov 01 • 12:00 | CD Azuaga |  | - |  | FC Cartagena | 0 | : | 0 |
| Nov 01 • 12:00 | SCR Peña Deportiva |  | - |  | Real Valladolid | 1 | : | 5 |
| Nov 01 • 12:00 | CDA Navalcarnero |  | - |  | AD Alcorcón | 0 | : | 1 |
| Nov 01 • 12:00 | AD Llerenense |  | - |  | CD Leganés | 0 | : | 2 |
| Nov 01 • 12:00 | SD Compostela |  | - |  | CD Tenerife | 0 | : | 1 |
| Nov 01 • 12:00 | Naxara CD |  | - |  | UD Melilla | 1 | : | 2 |
| Nov 01 • 12:00 | UD Barbastro |  | - |  | SD Ponferradina | 1 | : | 0 |
| Nov 01 • 12:00 | UCAM Murcia |  | - |  | Linares Deportivo | 0 | : | 0 |
| Nov 01 • 15:30 | CD Quintanar De La Orden | | - |  | Sevilla FC | 0 | : | 3 |
| Nov 01 • 15:30 | Turégano CF | | - |  | Celta de Vigo | 0 | : | 4 |
| Nov 01 • 16:00 | Atlético Astorga |  | - |  | FC Andorra | 1 | : | 0 |
| Nov 01 • 16:00 | CD Valle de Egüés |  | - |  | CD Teruel | 1 | : | 0 |
| Nov 01 • 16:00 | CA Antoniano |  | - |  | CD Lugo | 0 | : | 1 |
| Nov 01 • 16:30 | Real Jaén |  | - |  | CD Eldense | 2 | : | 3 |
| Nov 01 • 16:30 | Real Avilés |  | - |  | CD Arenteiro | 0 | : | 1 |
| Nov 01 • 17:00 | CD Covadonga |  | - |  | Deportivo La Coruña | 1 | : | 3 |
| Nov 01 • 17:00 | CDE Ursaria |  | - |  | CD Cayón | 1 | : | 2 |
| Nov 01 • 17:30 | CD Guijuelo |  | - |  | Sporting de Gijon | 0 | : | 3 |
| Nov 01 • 17:30 | Zamora CF |  | - |  | Racing Santander | 2 | : | 2 |
| Nov 01 • 17:30 | CD Manchego Ciudad Real |  | - |  | Antequera CF | 1 | : | 3 |
| Nov 01 • 17:30 | Arandina CF |  | - |  | Real Murcia | 1 | : | 0 |
| Nov 01 • 18:00 | Terrassa FC |  | - |  | Albacete Balompié | 1 | : | 0 |
| Nov 01 • 18:00 | Utebo FC |  | - |  | CD Mirandés | 1 | : | 2 |
| Nov 01 • 18:00 | CE Europa |  | - |  | Elche CF | 0 | : | 2 |
| Nov 01 • 18:00 | Barakaldo CF |  | - |  | Málaga CF | 0 | : | 0 |
| Nov 01 • 18:00 | CD Tudelano |  | - |  | Recreativo Huelva | 1 | : | 0 |
| Nov 01 • 18:00 | Gernika Club |  | - |  | Unionistas de Salamanca | 0 | : | 2 |
| Nov 01 • 18:00 | Yeclano Deportivo |  | - |  | Atlético Sanluqueño CF | 2 | : | 0 |
| Nov 01 • 18:00 | Orihuela CF |  | - |  | Gimnàstic de Tarragona | 0 | : | 0 |
| Nov 01 • 18:30 | Tardienta CF | | - |  | Getafe CF | 0 | : | 12 |
| Nov 01 • 18:30 | CD Buñol | | - |  | Real Sociedad | 0 | : | 1 |
| Nov 01 • 18:30 | CD Boiro | | - |  | RCD Mallorca | 0 | : | 4 |
| Nov 01 • 19:00 | Águilas FC |  | - |  | SD Huesca | 0 | : | 1 |
| Nov 01 • 19:30 | CE Andratx |  | - |  | SD Tarazona | 3 | : | 2 |
| Nov 01 • 20:00 | CE Manresa |  | - |  | Real Oviedo | 1 | : | 2 |
| Nov 01 • 20:00 | Marbella FC |  | - |  | Racing de Ferrol | 1 | : | 3 |
| Nov 01 • 20:30 | CD Hernán Cortés | | - |  | Real Betis | 1 | : | 12 |
| Nov 01 • 21:30 | UE Rubí | | - |  | Athletic Bilbao | 1 | : | 2 |
| Nov 02 • 19:00 | Chiclana CF | | - |  | Villarreal CF | 0 | : | 5 |
| Nov 02 • 19:00 | Arosa SC |  | - |  | Granada CF | 0 | : | 3 |
| Nov 02 • 20:00 | UD Logroñés |  | - |  | Valencia CF | 0 | : | 2 |
| Nov 02 • 20:30 | Hércules CF |  | - |  | Burgos CF | 1 | : | 2 |
| Nov 02 • 20:30 | CF Villanovense |  | - |  | UD Ibiza | 2 | : | 1 |
| Nov 02 • 21:00 | Deportivo Murcia | | - |  | Deportivo Alavés | 0 | : | 10 |
| Nov 08 • 18:00 | Gimnástica Segoviana |  | - |  | Sestao River Club | 3 | : | 4 |
| Nov 14 • 20:00 | Atzeneta UE |  | - |  | Real Zaragoza | 2 | : | 1 |
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| Nov 22 • 21:00 | Zamora CF | | - | | Villarreal CF | 1 | : | 2 |
| Dec 05 • 19:00 | Atzeneta UE | | - | | Getafe CF | 1 | : | 2 |
| Dec 05 • 21:00 | Arosa SC | | - | | Valencia CF | 0 | : | 1 |
| Dec 05 • 21:00 | RCD Espanyol | | - | | Real Valladolid | 3 | : | 1 |
| Dec 05 • 21:00 | CD Castellón | | - | | Real Oviedo | 2 | : | 1 |
| Dec 06 • 12:00 | UD Barbastro | | - | | UD Almeria | 1 | : | 0 |
| Dec 06 • 12:00 | Yeclano Deportivo | | - | | Rayo Vallecano | 0 | : | 2 |
| Dec 06 • 12:00 | Antequera CF | | - | | SD Huesca | 0 | : | 2 |
| Dec 06 • 12:00 | Deportivo La Coruña | | - | | CD Tenerife | 2 | : | 3 |
| Dec 06 • 12:00 | AD Alcorcón | | - | | FC Cartagena | 0 | : | 0 |
| Dec 06 • 16:00 | Terrassa FC | | - | | Deportivo Alavés | 0 | : | 1 |
| Dec 06 • 16:00 | CE Andratx | | - | | Real Sociedad | 0 | : | 1 |
| Dec 06 • 16:00 | CD Arenteiro | | - | | Burgos CF | 1 | : | 3 |
| Dec 06 • 16:00 | Unionistas de Salamanca | | - | | Sporting de Gijon | 2 | : | 0 |
| Dec 06 • 17:00 | Málaga CF | | - | | CD Eldense | 1 | : | 0 |
| Dec 06 • 19:00 | CF Villanovense | | - | | Real Betis | 1 | : | 2 |
| Dec 06 • 19:00 | CD Valle de Egüés | | - | | RCD Mallorca | 0 | : | 3 |
| Dec 06 • 19:00 | CD Lugo | | - | | CD Mirandés | 2 | : | 0 |
| Dec 06 • 19:00 | Levante UD | | - |  | SD Amorebieta | 0 | : | 1 |
| Dec 06 • 21:00 | Atlético Astorga | | - | | Sevilla FC | 0 | : | 2 |
| Dec 06 • 21:00 | CD Tudelano | | - | | UD Las Palmas | 1 | : | 2 |
| Dec 07 • 19:00 | Arandina CF | | - | | Cádiz CF | 2 | : | 1 |
| Dec 07 • 20:00 | Linares Deportivo | | - | | Elche CF | 1 | : | 3 |
| Dec 07 • 20:00 | Racing de Ferrol | | - | | CD Leganés | 1 | : | 0 |
| Dec 07 • 20:00 | UD Melilla | | - | | SD Eibar | 1 | : | 1 |
| Dec 07 • 21:00 | Orihuela CF | | - | | Girona FC | 2 | : | 5 |
| Dec 07 • 21:00 | CD Cayón | | - | | Athletic Bilbao | 0 | : | 3 |
| Dec 07 • 21:00 | Sestao River Club | | - | | Celta de Vigo | 1 | : | 2 |
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| Jan 06 • 16:00 | CD Lugo | | - |  | Atlético Madrid | 1 | : | 3 |
| Jan 06 • 17:00 | RCD Espanyol | | - | | Getafe CF | 0 | : | 1 |
| Jan 06 • 18:00 | Elche CF | | - | | Girona FC | 0 | : | 2 |
| Jan 06 • 19:00 | SD Huesca | | - | | Rayo Vallecano | 0 | : | 2 |
| Jan 06 • 20:00 | Deportivo Alavés | | - | | Real Betis | 1 | : | 0 |
| Jan 06 • 21:30 | Arandina CF | | - |  | Real Madrid | 1 | : | 3 |
| Jan 07 • 12:00 | SD Amorebieta | | - | | Celta de Vigo | 2 | : | 4 |
| Jan 07 • 12:00 | Burgos CF | | - | | RCD Mallorca | 0 | : | 3 |
| Jan 07 • 16:00 | CD Castellón | | - |  | CA Osasuna | 0 | : | 1 |
| Jan 07 • 16:00 | Racing de Ferrol | | - | | Sevilla FC | 1 | : | 2 |
| Jan 07 • 18:00 | Unionistas de Salamanca | | - | | Villarreal CF | 1 | : | 1 |
| Jan 07 • 19:00 | FC Cartagena | | - | | Valencia CF | 1 | : | 2 |
| Jan 07 • 19:00 | SD Eibar | | - | | Athletic Bilbao | 0 | : | 3 |
| Jan 07 • 21:00 | UD Barbastro | | - |  | FC Barcelona | 2 | : | 3 |
| Jan 07 • 21:00 | Málaga CF | | - | | Real Sociedad | 0 | : | 1 |
| Jan 07 • 22:00 | CD Tenerife | | - | | UD Las Palmas | 2 | : | 0 |
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| Jan 16 • 20:00 | Getafe CF | | - | | Sevilla FC | 1 | : | 3 |
| Jan 16 • 21:00 | Athletic Bilbao | | - | | Deportivo Alavés | 2 | : | 0 |
| Jan 16 • 22:00 | CD Tenerife | | - | | RCD Mallorca | 0 | : | 1 |
| Jan 17 • 20:00 | Valencia CF | | - | | Celta de Vigo | 1 | : | 3 |
| Jan 17 • 21:00 | CA Osasuna | | - | | Real Sociedad | 0 | : | 2 |
| Jan 17 • 21:30 | Girona FC | | - | | Rayo Vallecano | 3 | : | 1 |
| Jan 18 • 19:30 | Unionistas de Salamanca | | - | | FC Barcelona | 1 | : | 3 |
| Jan 18 • 21:30 | Atlético Madrid | | - | | Real Madrid | 4 | : | 2 |
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| Jan 23 • 21:30 | Celta de Vigo | | - | | Real Sociedad | 1 | : | 2 |
| Jan 24 • 19:30 | RCD Mallorca | | - | | Girona FC | 3 | : | 2 |
| Jan 24 • 21:30 | Athletic Bilbao | | - | | FC Barcelona | 4 | : | 2 |
| Jan 25 • 21:00 | Atlético Madrid | | - | | Sevilla FC | 1 | : | 0 |
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| Feb 06 • 21:00 | RCD Mallorca | | - | | Real Sociedad | 0 | : | 0 |
| Feb 07 • 21:30 | Atlético Madrid | | - | | Athletic Bilbao | 0 | : | 1 |
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| Feb 27 • 21:30 | Real Sociedad | | - | | RCD Mallorca | 1 | : | 1 |
| Feb 29 • 21:30 | Athletic Bilbao | | - | | Atlético Madrid | 3 | : | 0 |
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| Apr 06 • 22:00 | Athletic Bilbao | | - | | RCD Mallorca | 1 | : | 1 |
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