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| Feb 20 • 20:30 | Alex Molcan |  | - |  | Joao Fonseca | 2 | : | 0 |
| Feb 20 • 20:30 | João Sousa |  | - |  | Hugo Dellien | 0 | : | 2 |
| Feb 20 • 20:30 | Pedro Martínez |  | - |  | Cristian Garín | 2 | : | 0 |
| Feb 20 • 23:00 | Laslo Djere |  | - |  | Facundo Bagnis | 1 | : | 0 |
| Feb 20 • 23:00 | Dominic Thiem |  | - | | Thiago Moura Monteiro | 1 | : | 2 |
| Feb 21 • 00:20 | Lorenzo Musetti |  | - | | Nicolás Jarry | 0 | : | 2 |
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| Feb 21 • 20:30 | Pedro Cachín | | - |  | Daniel Elahi Galán | 0 | : | 2 |
| Feb 21 • 20:30 | Roberto Carballés Baena | | - | | Francisco Cerundolo | 1 | : | 2 |
| Feb 21 • 20:30 | Juan Manuel Cerúndolo | | - |  | Cameron Norrie | 0 | : | 2 |
| Feb 21 • 20:30 | Hugo Gaston |  | - |  | Juan Pablo Varillas | 0 | : | 2 |
| Feb 21 • 22:00 | Fabio Fognini | | - | | Tomas Barrios Vera | 2 | : | 0 |
| Feb 21 • 22:00 | Albert Ramos-Viñolas | | - | | Tomás Martín Etcheverry | 2 | : | 1 |
| Feb 21 • 23:00 | Carlos Alcaraz | | - | | Mateus Alves | 2 | : | 0 |
| Feb 22 • 20:30 | Dušan Lajović | | - | | Diego Schwartzman | 2 | : | 0 |
| Feb 22 • 20:30 | Jaume Munar | | - | | Bernabe Zapata Miralles | 0 | : | 2 |
| Feb 22 • 22:55 | Thomaz Bellucci | | - | | Sebastián Báez | 0 | : | 2 |
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| Feb 22 • 22:45 | Alex Molcan | | - | | Hugo Dellien | 1 | : | 2 |
| Feb 23 • 00:30 | Thiago Moura Monteiro | | - | | Cameron Norrie | 0 | : | 2 |
| Feb 23 • 20:30 | Albert Ramos-Viñolas | | - | | Daniel Elahi Galán | 2 | : | 0 |
| Feb 23 • 20:30 | Bernabe Zapata Miralles | | - | | Francisco Cerundolo | 2 | : | 1 |
| Feb 23 • 22:00 | Nicolás Jarry | | - | | Pedro Martínez | 2 | : | 0 |
| Feb 23 • 22:00 | Juan Pablo Varillas | | - | | Sebastián Báez | 0 | : | 2 |
| Feb 23 • 23:00 | Carlos Alcaraz | | - | | Fabio Fognini | 2 | : | 1 |
| Feb 24 • 00:30 | Laslo Djere | | - | | Dušan Lajović | 0 | : | 2 |
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| Feb 24 • 20:00 | Albert Ramos-Viñolas | | - | | Bernabe Zapata Miralles | 1 | : | 2 |
| Feb 24 • 20:30 | Hugo Dellien | | - | | Cameron Norrie | 1 | : | 2 |
| Feb 24 • 22:00 | Carlos Alcaraz | | - | | Dušan Lajović | 2 | : | 0 |
| Feb 25 • 00:20 | Nicolás Jarry | | - | | Sebastián Báez | 2 | : | 0 |
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| Feb 25 • 21:00 | Bernabe Zapata Miralles | | - | | Cameron Norrie | 1 | : | 2 |
| Feb 25 • 22:30 | Carlos Alcaraz | | - | | Nicolás Jarry | 2 | : | 1 |
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| Feb 26 • 21:30 | Carlos Alcaraz | | - | | Cameron Norrie | 1 | : | 2 |
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