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| May 10 • 11:00 | Luca Van Assche |  | - |  | Tomás Martín Etcheverry | 0 | : | 2 |
| May 10 • 11:00 | Ilya Ivashka |  | - |  | Stanislas Wawrinka | 0 | : | 2 |
| May 10 • 11:00 | Filip Krajinović |  | - |  | Márton Fucsovics | 0 | : | 2 |
| May 10 • 11:00 | Sebastián Báez | | - |  | Juan Pablo Varillas | 2 | : | 0 |
| May 10 • 14:10 | Constant Lestienne | | - | | Laslo Djere | 0 | : | 1 |
| May 10 • 14:10 | Pedro Cachín | | - |  | Cristian Garín | 1 | : | 2 |
| May 10 • 15:00 | Richard Gasquet | | - |  | Yibing Wu | 1 | : | 2 |
| May 10 • 15:55 | Kyle Edmund |  | - | | Alexandre Muller | 0 | : | 2 |
| May 10 • 15:55 | Pedro Martínez |  | - |  | Alexander Bublik | 0 | : | 2 |
| May 10 • 16:15 | Juan Manuel Cerúndolo | | - | | Arthur Fils | 1 | : | 2 |
| May 10 • 16:30 | Alexei Popyrin |  | - | | Christopher O'Connell | 2 | : | 0 |
| May 10 • 17:15 | Jaume Munar | | - | | Thanasi Kokkinakis | 0 | : | 0 |
| May 10 • 17:45 | Roman Safiullin |  | - |  | Marcos Giron | 2 | : | 0 |
| May 10 • 18:00 | Flavio Cobolli |  | - | | Arthur Rinderknech | 0 | : | 2 |
| May 10 • 18:45 | Brandon Nakashima | | - | | Gregoire Barrere | 0 | : | 2 |
| May 10 • 19:00 | Fabio Fognini | | - | | Andy Murray | 2 | : | 1 |
| May 11 • 11:00 | Marc-Andrea Hüsler | | - | | Jason Kubler | 1 | : | 2 |
| May 11 • 11:00 | Giulio Zeppieri | | - |  | Daniel Altmaier | 1 | : | 2 |
| May 11 • 11:00 | Hugo Dellien |  | - | | Roberto Carballés Baena | 0 | : | 2 |
| May 11 • 12:30 | Marco Cecchinato | | - | | Mackenzie McDonald | 2 | : | 0 |
| May 11 • 12:30 | Ugo Humbert | | - |  | Emil Ruusuvuori | 1 | : | 2 |
| May 11 • 12:30 | Adrian Mannarino | | - |  | Thiago Moura Monteiro | 0 | : | 2 |
| May 11 • 13:00 | Luca Nardi | | - |  | David Goffin | 1 | : | 2 |
| May 11 • 14:00 | Guido Pella | | - | | Maxime Cressy | 2 | : | 0 |
| May 11 • 14:00 | Dušan Lajović | | - |  | Nuno Borges | 0 | : | 2 |
| May 11 • 14:30 | Lorenzo Sonego | | - | | Jérémy Chardy | 2 | : | 0 |
| May 11 • 14:30 | Albert Ramos-Viñolas | | - | | Francesco Passaro | 2 | : | 1 |
| May 11 • 15:30 | Nicolás Jarry | | - | | Yannick Hanfmann | 0 | : | 2 |
| May 11 • 15:30 | Corentin Moutet | | - | | Fábián Marozsán | 1 | : | 2 |
| May 11 • 18:20 | Hugo Grenier | | - | | Jeffrey John Wolf | 0 | : | 2 |
| May 11 • 19:00 | Stefano Napolitano | | - |  | Alex Molcan | 1 | : | 2 |
| May 11 • 20:30 | Matteo Arnaldi | | - | | Diego Schwartzman | 2 | : | 1 |
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| May 12 • 11:00 | Alexandre Muller | | - | | Cameron Norrie | 0 | : | 2 |
| May 12 • 11:00 | Felix Auger Aliassime |  | - | | Alexei Popyrin | 1 | : | 2 |
| May 12 • 11:00 | Yibing Wu | | - | | Francisco Cerundolo | 1 | : | 2 |
| May 12 • 11:00 | Thanasi Kokkinakis | | - | | Jannik Sinner | 0 | : | 2 |
| May 12 • 12:30 | Alex De Minaur | | - | | Márton Fucsovics | 0 | : | 2 |
| May 12 • 13:25 | Alexander Shevchenko | | - | | Sebastián Báez | 2 | : | 0 |
| May 12 • 13:45 | Stanislas Wawrinka | | - |  | Grigor Dimitrov | 0 | : | 2 |
| May 12 • 14:00 | Roman Safiullin | | - | | Sebastian Korda | 2 | : | 0 |
| May 12 • 15:30 | Miomir Kecmanovic | | - | | Fabio Fognini | 0 | : | 2 |
| May 12 • 15:30 | Botic van de Zandschulp |  | - | | Laslo Djere | 0 | : | 2 |
| May 12 • 15:30 | Karen Khachanov | | - | | Gregoire Barrere | 1 | : | 2 |
| May 12 • 17:15 | Alexander Bublik | | - | | Ben Shelton | 2 | : | 1 |
| May 12 • 17:15 | Cristian Garín | | - | | Tommy Paul | 2 | : | 1 |
| May 12 • 19:05 | Novak Djokovic | | - | | Tomás Martín Etcheverry | 2 | : | 0 |
| May 12 • 19:15 | Arthur Fils | | - |  | Holger Rune | 0 | : | 2 |
| May 12 • 19:40 | Casper Ruud |  | - | | Arthur Rinderknech | 2 | : | 0 |
| May 13 • 11:00 | Andrey Rublev | | - | | Alex Molcan | 2 | : | 0 |
| May 13 • 11:00 | Borna Ćorić |  | - | | Thiago Moura Monteiro | 2 | : | 1 |
| May 13 • 11:00 | Roberto Carballés Baena | | - | | Daniel Evans | 2 | : | 1 |
| May 13 • 14:30 | Hubert Hurkacz |  | - | | Jeffrey John Wolf | 0 | : | 2 |
| May 13 • 14:30 | Bernabe Zapata Miralles | | - | | Jason Kubler | 2 | : | 0 |
| May 13 • 15:00 | Albert Ramos-Viñolas | | - | | Carlos Alcaraz | 0 | : | 2 |
| May 13 • 17:45 | Lorenzo Sonego | | - |  | Yoshihito Nishioka | 2 | : | 0 |
| May 13 • 18:10 | Guido Pella | | - | | Alejandro Davidovich Fokina | 0 | : | 2 |
| May 13 • 18:15 | Daniel Altmaier | | - | | Frances Tiafoe | 1 | : | 2 |
| May 13 • 18:25 | Jiří Lehečka |  | - | | Fábián Marozsán | 1 | : | 2 |
| May 13 • 18:45 | Stefanos Tsitsipas |  | - | | Nuno Borges | 2 | : | 0 |
| May 14 • 11:00 | Roberto Bautista-Agut | | - | | Marco Cecchinato | 0 | : | 2 |
| May 14 • 12:55 | Emil Ruusuvuori | | - | | Daniil Medvedev | 0 | : | 2 |
| May 14 • 13:00 | Yannick Hanfmann | | - | | Taylor Harry Fritz | 2 | : | 0 |
| May 14 • 14:30 | Lorenzo Musetti | | - | | Matteo Arnaldi | 2 | : | 0 |
| May 14 • 19:05 | David Goffin | | - | | Alexander Zverev | 1 | : | 2 |
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| May 14 • 11:00 | Alexei Popyrin | | - | | Roman Safiullin | 2 | : | 0 |
| May 14 • 11:00 | Gregoire Barrere | | - | | Francisco Cerundolo | 1 | : | 2 |
| May 14 • 12:40 | Fabio Fognini | | - | | Holger Rune | 0 | : | 2 |
| May 14 • 13:00 | Laslo Djere | | - | | Cristian Garín | 1 | : | 0 |
| May 14 • 14:00 | Novak Djokovic | | - | | Grigor Dimitrov | 2 | : | 1 |
| May 14 • 16:30 | Casper Ruud | | - | | Alexander Bublik | 2 | : | 1 |
| May 14 • 18:00 | Márton Fucsovics | | - | | Cameron Norrie | 0 | : | 2 |
| May 14 • 20:30 | Alexander Shevchenko | | - | | Jannik Sinner | 1 | : | 2 |
| May 15 • 11:00 | Marco Cecchinato | | - | | Yannick Hanfmann | 1 | : | 2 |
| May 15 • 11:00 | Borna Ćorić | | - | | Roberto Carballés Baena | 2 | : | 0 |
| May 15 • 13:30 | Fábián Marozsán | | - | | Carlos Alcaraz | 2 | : | 0 |
| May 15 • 13:55 | Andrey Rublev | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| May 15 • 15:15 | Bernabe Zapata Miralles | | - | | Daniil Medvedev | 1 | : | 2 |
| May 15 • 17:00 | Lorenzo Musetti | | - | | Frances Tiafoe | 2 | : | 1 |
| May 15 • 17:30 | Jeffrey John Wolf | | - | | Alexander Zverev | 0 | : | 2 |
| May 15 • 19:00 | Stefanos Tsitsipas | | - | | Lorenzo Sonego | 2 | : | 0 |
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| May 16 • 11:00 | Novak Djokovic | | - | | Cameron Norrie | 2 | : | 0 |
| May 16 • 11:00 | Alexei Popyrin | | - | | Holger Rune | 1 | : | 2 |
| May 16 • 15:10 | Casper Ruud | | - | | Laslo Djere | 2 | : | 0 |
| May 16 • 16:15 | Francisco Cerundolo | | - | | Jannik Sinner | 2 | : | 1 |
| May 16 • 16:45 | Andrey Rublev | | - | | Yannick Hanfmann | 1 | : | 2 |
| May 16 • 18:15 | Alexander Zverev | | - | | Daniil Medvedev | 0 | : | 2 |
| May 16 • 21:00 | Borna Ćorić | | - | | Fábián Marozsán | 2 | : | 1 |
| May 16 • 23:30 | Stefanos Tsitsipas | | - | | Lorenzo Musetti | 2 | : | 0 |
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| May 17 • 13:00 | Novak Djokovic | | - | | Holger Rune | 1 | : | 2 |
| May 17 • 19:00 | Casper Ruud | | - | | Francisco Cerundolo | 2 | : | 0 |
| May 18 • 15:00 | Yannick Hanfmann | | - | | Daniil Medvedev | 0 | : | 2 |
| May 18 • 20:30 | Stefanos Tsitsipas | | - | | Borna Ćorić | 2 | : | 0 |
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| May 20 • 13:00 | Holger Rune | | - | | Casper Ruud | 2 | : | 1 |
| May 20 • 14:20 | Daniil Medvedev | | - | | Stefanos Tsitsipas | 2 | : | 0 |
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| May 21 • 15:00 | Holger Rune | | - | | Daniil Medvedev | 0 | : | 2 |
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