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| Aug 27 • 17:00 | Kei Nishikori |  | - |  | Guido Andreozzi | 3 | : | 0 |
| Aug 27 • 17:00 | Marcel Granollers |  | - |  | Denis Kudla | 3 | : | 1 |
| Aug 27 • 17:00 | Lukáš Lacko |  | - | | James Blake | 1 | : | 3 |
| Aug 27 • 17:00 | Tim Smyczek | | - | | Bobby Reynolds | 3 | : | 2 |
| Aug 27 • 18:20 | Hiroki Moriya | | - |  | Ivan Dodig | 0 | : | 3 |
| Aug 27 • 19:00 | Andy Murray |  | - |  | Alex Bogomolov Jr | 3 | : | 0 |
| Aug 27 • 21:30 | Florian Mayer |  | - | | Jack Sock | 0 | : | 2 |
| Aug 27 • 22:00 | Albert Ramos-Viñolas | | - | | Robby Ginepri | 3 | : | 1 |
| Aug 27 • 22:10 | Nikolay Davydenko | | - | | Guido Pella | 3 | : | 1 |
| Aug 27 • 22:10 | Paul-Henri Mathieu |  | - | | Igor Andreev | 3 | : | 2 |
| Aug 27 • 22:40 | Blaž Kavčič |  | - |  | Flavio Cipolla | 1 | : | 3 |
| Aug 27 • 23:45 | Tatsuma Ito | | - |  | Matthew Ebden | 0 | : | 3 |
| Aug 27 • 23:50 | Jérémy Chardy | | - | | Filippo Volandri | 3 | : | 0 |
| Aug 28 • 00:00 | Mardy Fish | | - | | Go Soeda | 3 | : | 0 |
| Aug 28 • 00:00 | Daniel Brands | | - |  | Adrian Ungur | 3 | : | 0 |
| Aug 28 • 00:25 | Fernando Verdasco | | - |  | Rui Machado | 3 | : | 0 |
| Aug 28 • 01:00 | Roger Federer |  | - | | Donald Young | 3 | : | 0 |
| Aug 28 • 01:30 | Gilles Simon | | - | | Michael Russell | 3 | : | 2 |
| Aug 28 • 01:30 | Feliciano López | | - |  | Robin Haase | 3 | : | 0 |
| Aug 28 • 01:30 | Maxime Authom |  | - | | Björn Phau | 1 | : | 3 |
| Aug 28 • 02:00 | Rubén Ramírez Hidalgo | | - |  | Somdev Devvarman | 3 | : | 1 |
| Aug 28 • 02:15 | Marin Čilić | | - | | Marinko Matosevic | 3 | : | 2 |
| Aug 28 • 02:30 | Martin Kližan | | - |  | Alejandro Falla | 3 | : | 0 |
| Aug 28 • 03:00 | Denis Istomin |  | - |  | Jurgen Zopp | 1 | : | 3 |
| Aug 28 • 17:10 | Ivo Karlović | | - |  | Jimmy Wang | 1 | : | 3 |
| Aug 28 • 17:15 | Tomáš Berdych |  | - | | David Goffin | 3 | : | 0 |
| Aug 28 • 17:15 | Thomaz Bellucci |  | - | | Pablo Andújar | 1 | : | 3 |
| Aug 28 • 17:20 | Milos Raonic |  | - | | Santiago Giraldo | 3 | : | 2 |
| Aug 28 • 17:25 | Nicolás Almagro | | - | | Radek Štěpánek | 3 | : | 1 |
| Aug 28 • 18:40 | Jo-Wilfried Tsonga | | - | | Karol Beck | 3 | : | 0 |
| Aug 28 • 18:40 | Nicolas Mahut | | - | | Philipp Petzschner | 2 | : | 3 |
| Aug 28 • 18:45 | Steve Darcis | | - |  | Malek Jaziri | 3 | : | 1 |
| Aug 28 • 19:10 | Andy Roddick | | - | | Rhyne Williams | 3 | : | 0 |
| Aug 28 • 20:15 | Sam Querrey | | - | | Lu Yen-Hsun | 3 | : | 1 |
| Aug 28 • 20:45 | Dennis Novikov | | - |  | Jerzy Janowicz | 3 | : | 1 |
| Aug 28 • 21:00 | Stanislas Wawrinka | | - |  | Sergiy Stakhovsky | 3 | : | 1 |
| Aug 28 • 21:10 | Juan Mónaco | | - | | Guillermo García López | 2 | : | 3 |
| Aug 28 • 21:55 | Édouard Roger-Vasselin | | - | | Fabio Fognini | 2 | : | 3 |
| Aug 28 • 23:00 | Julien Benneteau | | - | | Olivier Rochus | 3 | : | 0 |
| Aug 28 • 23:15 | Marcos Baghdatis |  | - | | Matthias Bachinger | 3 | : | 2 |
| Aug 28 • 23:20 | Rogério Dutra da Silva | | - | | Teymuraz Gabashvili | 3 | : | 2 |
| Aug 29 • 00:30 | Alexandr Dolgopolov | | - | | Jesse Levine | 3 | : | 2 |
| Aug 29 • 01:00 | Novak Djokovic |  | - | | Paolo Lorenzi | 3 | : | 0 |
| Aug 29 • 01:00 | Carlos Berlocq | | - | | Bernard Tomic | 1 | : | 3 |
| Aug 29 • 17:05 | David Ferrer | | - |  | Kevin Anderson | 3 | : | 0 |
| Aug 29 • 17:05 | Janko Tipsarević | | - | | Guillaume Rufin | 3 | : | 2 |
| Aug 29 • 17:05 | Mikhail Youzhny | | - |  | Gilles Müller | 2 | : | 3 |
| Aug 29 • 17:05 | Viktor Troicki | | - | | Cedrik-Marcel Stebe | 1 | : | 3 |
| Aug 29 • 17:05 | Grega Žemlja | | - | | Ricardo Mello | 3 | : | 0 |
| Aug 29 • 17:05 | Igor Sijsling | | - | | Daniel Gimeno-Traver | 3 | : | 0 |
| Aug 29 • 18:25 | Łukasz Kubot | | - | | Leonardo Mayer | 0 | : | 3 |
| Aug 29 • 18:45 | Brian Baker | | - | | Jan Hájek | 3 | : | 0 |
| Aug 29 • 18:45 | Grigor Dimitrov |  | - | | Benoît Paire | 1 | : | 3 |
| Aug 29 • 18:45 | Tobias Kamke | | - | | Lleyton Hewitt | 1 | : | 3 |
| Aug 29 • 19:10 | John Isner | | - | | Xavier Malisse | 3 | : | 1 |
| Aug 29 • 20:05 | Mikhail Kukushkin |  | - |  | Jarkko Nieminen | 0 | : | 2 |
| Aug 29 • 20:10 | Tommy Haas | | - |  | Ernests Gulbis | 2 | : | 3 |
| Aug 29 • 21:00 | Richard Gasquet | | - | | Albert Montañés | 3 | : | 1 |
| Aug 29 • 21:30 | Juan Martín del Potro | | - | | Florent Serra | 3 | : | 0 |
| Aug 29 • 21:45 | Steve Johnson | | - | | Rajeev Ram | 3 | : | 0 |
| Aug 29 • 21:50 | Andreas Seppi | | - | | Tommy Robredo | 0 | : | 3 |
| Aug 29 • 23:25 | Philipp Kohlschreiber | | - | | Michaël Llodra | 3 | : | 1 |
| Aug 30 • 00:10 | Jürgen Melzer |  | - | | Bradley Klahn | 2 | : | 3 |
| Aug 30 • 01:00 | Benjamin Becker | | - | | Ryan Harrison | 0 | : | 3 |
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| Aug 30 • 03:00 | Andy Murray | | - | | Ivan Dodig | 3 | : | 0 |
| Aug 30 • 17:05 | Tim Smyczek | | - | | Kei Nishikori | 0 | : | 3 |
| Aug 30 • 17:05 | Pablo Andújar | | - | | Feliciano López | 2 | : | 3 |
| Aug 30 • 17:05 | Nicolás Almagro | | - | | Philipp Petzschner | 3 | : | 2 |
| Aug 30 • 18:55 | Martin Kližan | | - | | Jo-Wilfried Tsonga | 3 | : | 1 |
| Aug 30 • 19:10 | Mardy Fish | | - | | Nikolay Davydenko | 3 | : | 2 |
| Aug 30 • 19:25 | Flavio Cipolla | | - | | Jack Sock | 0 | : | 3 |
| Aug 30 • 19:30 | Marin Čilić | | - | | Daniel Brands | 3 | : | 2 |
| Aug 30 • 21:20 | Albert Ramos-Viñolas | | - | | Fernando Verdasco | 1 | : | 3 |
| Aug 30 • 21:30 | Jérémy Chardy | | - | | Matthew Ebden | 3 | : | 0 |
| Aug 30 • 21:45 | Paul-Henri Mathieu | | - | | Milos Raonic | 0 | : | 3 |
| Aug 30 • 23:05 | Sam Querrey | | - | | Rubén Ramírez Hidalgo | 3 | : | 0 |
| Aug 30 • 23:25 | Jurgen Zopp | | - | | Tomáš Berdych | 0 | : | 3 |
| Aug 30 • 23:30 | Jimmy Wang | | - | | Gilles Simon | 1 | : | 3 |
| Aug 31 • 00:00 | Marcel Granollers | | - | | James Blake | 0 | : | 3 |
| Aug 31 • 01:00 | Roger Federer | | - | | Björn Phau | 3 | : | 0 |
| Aug 31 • 17:00 | Igor Sijsling | | - | | David Ferrer | 0 | : | 3 |
| Aug 31 • 17:00 | Steve Johnson | | - | | Ernests Gulbis | 3 | : | 1 |
| Aug 31 • 18:35 | Leonardo Mayer | | - | | Tommy Robredo | 3 | : | 1 |
| Aug 31 • 18:45 | Richard Gasquet | | - | | Bradley Klahn | 3 | : | 0 |
| Aug 31 • 19:00 | Gilles Müller | | - | | Lleyton Hewitt | 2 | : | 3 |
| Aug 31 • 19:10 | Rogério Dutra da Silva | | - | | Novak Djokovic | 0 | : | 3 |
| Aug 31 • 19:55 | Juan Martín del Potro | | - | | Ryan Harrison | 3 | : | 1 |
| Aug 31 • 20:45 | Steve Darcis | | - | | Stanislas Wawrinka | 2 | : | 3 |
| Aug 31 • 21:05 | Alexandr Dolgopolov | | - | | Marcos Baghdatis | 3 | : | 1 |
| Aug 31 • 22:50 | Jarkko Nieminen | | - | | John Isner | 1 | : | 3 |
| Aug 31 • 23:00 | Janko Tipsarević | | - | | Brian Baker | 3 | : | 0 |
| Aug 31 • 23:10 | Fabio Fognini | | - | | Guillermo García López | 3 | : | 0 |
| Aug 31 • 23:10 | Grega Žemlja | | - | | Cedrik-Marcel Stebe | 3 | : | 1 |
| Sep 01 • 00:00 | Julien Benneteau | | - | | Dennis Novikov | 3 | : | 1 |
| Sep 01 • 00:30 | Philipp Kohlschreiber | | - | | Benoît Paire | 3 | : | 2 |
| Sep 01 • 01:20 | Andy Roddick | | - | | Bernard Tomic | 3 | : | 0 |
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| Sep 01 • 17:05 | Nicolás Almagro | | - | | Jack Sock | 3 | : | 1 |
| Sep 01 • 17:15 | Marin Čilić | | - | | Kei Nishikori | 3 | : | 1 |
| Sep 01 • 18:55 | Jérémy Chardy | | - | | Martin Kližan | 0 | : | 3 |
| Sep 01 • 19:25 | Andy Murray | | - | | Feliciano López | 3 | : | 1 |
| Sep 01 • 21:00 | Roger Federer | | - | | Fernando Verdasco | 3 | : | 0 |
| Sep 01 • 23:45 | James Blake | | - | | Milos Raonic | 0 | : | 3 |
| Sep 02 • 01:00 | Sam Querrey | | - | | Tomáš Berdych | 1 | : | 3 |
| Sep 02 • 03:00 | Mardy Fish | | - | | Gilles Simon | 3 | : | 1 |
| Sep 02 • 17:10 | Lleyton Hewitt | | - | | David Ferrer | 1 | : | 3 |
| Sep 02 • 17:20 | Julien Benneteau | | - | | Novak Djokovic | 0 | : | 3 |
| Sep 02 • 18:50 | Juan Martín del Potro | | - | | Leonardo Mayer | 3 | : | 0 |
| Sep 02 • 19:30 | Andy Roddick | | - | | Fabio Fognini | 3 | : | 1 |
| Sep 02 • 20:50 | Alexandr Dolgopolov | | - | | Stanislas Wawrinka | 0 | : | 3 |
| Sep 02 • 21:30 | Janko Tipsarević | | - | | Grega Žemlja | 3 | : | 0 |
| Sep 02 • 22:35 | Richard Gasquet | | - | | Steve Johnson | 3 | : | 0 |
| Sep 03 • 03:00 | Philipp Kohlschreiber | | - | | John Isner | 3 | : | 2 |
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| Sep 03 • 17:10 | Nicolás Almagro | | - | | Tomáš Berdych | 0 | : | 3 |
| Sep 03 • 19:00 | Roger Federer | | - | | Mardy Fish | 0 | : | 0 |
| Sep 03 • 21:00 | Marin Čilić | | - | | Martin Kližan | 3 | : | 0 |
| Sep 04 • 01:30 | Andy Murray | | - | | Milos Raonic | 3 | : | 0 |
| Sep 04 • 18:50 | Richard Gasquet | | - | | David Ferrer | 0 | : | 3 |
| Sep 04 • 23:15 | Janko Tipsarević | | - | | Philipp Kohlschreiber | 3 | : | 0 |
| Sep 05 • 01:00 | Stanislas Wawrinka | | - | | Novak Djokovic | 0 | : | 2 |
| Sep 05 • 01:00 | Juan Martín del Potro | | - | | Andy Roddick | 3 | : | 1 |
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| Sep 05 • 23:00 | Andy Murray | | - | | Marin Čilić | 3 | : | 1 |
| Sep 06 • 03:00 | Roger Federer | | - | | Tomáš Berdych | 1 | : | 3 |
| Sep 06 • 20:15 | Janko Tipsarević | | - | | David Ferrer | 2 | : | 3 |
| Sep 07 • 03:00 | Juan Martín del Potro | | - | | Novak Djokovic | 0 | : | 3 |
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| Sep 08 • 18:25 | Tomáš Berdych | | - | | Andy Murray | 1 | : | 3 |
| Sep 08 • 21:00 | David Ferrer | | - | | Novak Djokovic | 1 | : | 3 |
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| Sep 10 • 22:10 | Andy Murray | | - | | Novak Djokovic | 3 | : | 2 |
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