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| Aug 28 • 17:00 | Jeffrey John Wolf |  | - |  | Zhang Zhizhen | 2 | : | 3 |
| Aug 28 • 17:00 | Adrian Mannarino |  | - |  | Yosuke Watanuki | 3 | : | 1 |
| Aug 28 • 17:00 | Richard Gasquet | | - |  | Fábián Marozsán | 2 | : | 3 |
| Aug 28 • 17:00 | Sebastian Ofner |  | - |  | Nuno Borges | 3 | : | 1 |
| Aug 28 • 17:00 | Ilya Ivashka |  | - |  | Juan Manuel Cerúndolo | 2 | : | 3 |
| Aug 28 • 17:00 | Alexander Bublik |  | - | | Dominic Thiem | 0 | : | 3 |
| Aug 28 • 17:00 | Pedro Cachín | | - | | Ben Shelton | 1 | : | 3 |
| Aug 28 • 18:30 | Casper Ruud |  | - | | Emilio Nava | 3 | : | 1 |
| Aug 28 • 18:30 | Rinky Hijikata |  | - |  | Pavel Kotov | 3 | : | 1 |
| Aug 28 • 18:30 | Marcos Giron | | - |  | Alejandro Davidovich Fokina | 0 | : | 3 |
| Aug 28 • 18:30 | Roberto Carballés Baena | | - |  | Holger Rune | 3 | : | 1 |
| Aug 28 • 18:30 | Jakub Mensik |  | - | | Gregoire Barrere | 3 | : | 1 |
| Aug 28 • 19:15 | Learner Tien | | - | | Frances Tiafoe | 0 | : | 3 |
| Aug 28 • 20:00 | Lorenzo Musetti |  | - | | Titouan Droguet | 2 | : | 3 |
| Aug 28 • 20:00 | Steve Johnson | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Aug 28 • 20:00 | Zachary Svajda | | - | | Francisco Cerundolo | 1 | : | 3 |
| Aug 28 • 20:00 | Laslo Djere |  | - | | Brandon Nakashima | 3 | : | 0 |
| Aug 28 • 20:30 | Márton Fucsovics | | - | | Sebastian Korda | 3 | : | 2 |
| Aug 28 • 20:30 | Tommy Paul | | - | | Stefano Travaglia | 3 | : | 1 |
| Aug 28 • 20:30 | Roman Safiullin | | - | | Marco Cecchinato | 3 | : | 0 |
| Aug 28 • 20:30 | Aslan Karatsev | | - | | Jiří Lehečka | 3 | : | 0 |
| Aug 28 • 20:30 | Miomir Kecmanovic | | - |  | Juan Pablo Varillas | 1 | : | 3 |
| Aug 28 • 20:30 | Jiří Veselý | | - | | Enzo Couacaud | 3 | : | 2 |
| Aug 28 • 22:00 | Dominic Stricker |  | - | | Alexei Popyrin | 3 | : | 1 |
| Aug 28 • 22:00 | Quentin Halys | | - | | Benjamin Bonzi | 1 | : | 3 |
| Aug 28 • 22:00 | Felix Auger Aliassime |  | - | | Mackenzie McDonald | 1 | : | 3 |
| Aug 28 • 22:00 | Hugo Dellien |  | - |  | Borna Gojo | 0 | : | 3 |
| Aug 28 • 22:00 | Sho Shimabukuro | | - | | Hugo Gaston | 0 | : | 3 |
| Aug 28 • 22:00 | Bernabe Zapata Miralles | | - | | Ethan Quinn | 3 | : | 0 |
| Aug 28 • 23:00 | Kwon Soon-woo |  | - | | Christopher Eubanks | 1 | : | 3 |
| Aug 29 • 01:00 | Stefanos Tsitsipas |  | - | | Milos Raonic | 3 | : | 0 |
| Aug 29 • 02:15 | Alexandre Muller | | - | | Novak Djokovic | 0 | : | 3 |
| Aug 29 • 17:00 | Tallon Griekspoor |  | - | | Arthur Fils | 2 | : | 3 |
| Aug 29 • 17:00 | Jason Kubler | | - | | Matteo Arnaldi | 0 | : | 1 |
| Aug 29 • 17:00 | Alexander Zverev |  | - | | Aleksandar Vukic | 3 | : | 0 |
| Aug 29 • 17:00 | Max Purcell | | - | | Christopher O'Connell | 1 | : | 3 |
| Aug 29 • 17:00 | James Duckworth | | - |  | Felipe Meligeni Alves | 0 | : | 3 |
| Aug 29 • 17:00 | Nicolás Jarry |  | - | | Luca Van Assche | 3 | : | 1 |
| Aug 29 • 17:00 | Ugo Humbert | | - | | Matteo Berrettini | 0 | : | 3 |
| Aug 29 • 17:00 | Diego Schwartzman | | - | | Arthur Rinderknech | 0 | : | 3 |
| Aug 29 • 18:00 | Daniil Medvedev | | - | | Attila Balazs | 3 | : | 0 |
| Aug 29 • 18:15 | Karen Khachanov | | - | | Michael Mmoh | 0 | : | 3 |
| Aug 29 • 18:40 | Daniel Altmaier | | - | | Constant Lestienne | 3 | : | 1 |
| Aug 29 • 18:40 | Albert Ramos-Viñolas | | - | | Alex Michelsen | 0 | : | 3 |
| Aug 29 • 19:05 | Alexander Shevchenko | | - |  | Cameron Norrie | 0 | : | 3 |
| Aug 29 • 19:20 | Alex Molcan |  | - |  | Grigor Dimitrov | 2 | : | 3 |
| Aug 29 • 19:35 | Thanasi Kokkinakis | | - |  | Hsu Yu-hsiou | 1 | : | 3 |
| Aug 29 • 20:35 | Andy Murray | | - | | Corentin Moutet | 3 | : | 0 |
| Aug 29 • 21:00 | Sebastián Báez | | - | | Borna Ćorić | 3 | : | 0 |
| Aug 29 • 21:10 | Arthur Cazaux | | - | | Andrey Rublev | 0 | : | 3 |
| Aug 29 • 21:15 | Facundo Díaz Acosta | | - | | John Isner | 0 | : | 3 |
| Aug 29 • 21:30 | Radu Albot |  | - | | Jack Draper | 0 | : | 3 |
| Aug 29 • 22:00 | Nicolas Moreno de Alboran | | - | | Lorenzo Sonego | 0 | : | 3 |
| Aug 29 • 22:00 | Yibing Wu | | - | | Dušan Lajović | 3 | : | 2 |
| Aug 29 • 22:00 | Timofey Skatov | | - | | Alex De Minaur | 1 | : | 3 |
| Aug 29 • 22:00 | Taro Daniel | | - | | Gaël Monfils | 1 | : | 3 |
| Aug 29 • 22:10 | Tomás Martín Etcheverry | | - |  | Otto Virtanen | 3 | : | 2 |
| Aug 29 • 22:15 | Botic van de Zandschulp | | - | | Jordan Thompson | 1 | : | 0 |
| Aug 29 • 22:15 | Daniel Elahi Galán |  | - | | Daniel Evans | 0 | : | 3 |
| Aug 29 • 22:15 | Stanislas Wawrinka | | - | | Yoshihito Nishioka | 3 | : | 0 |
| Aug 29 • 22:45 | Marc-Andrea Hüsler | | - |  | Hubert Hurkacz | 2 | : | 3 |
| Aug 29 • 23:00 | Lloyd Harris |  | - | | Guido Pella | 3 | : | 0 |
| Aug 30 • 01:00 | Yannick Hanfmann | | - | | Jannik Sinner | 0 | : | 3 |
| Aug 30 • 02:30 | Carlos Alcaraz Garfia | | - | | Dominik Koepfer | 1 | : | 0 |
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| Aug 30 • 17:00 | Stefanos Tsitsipas | | - | | Dominic Stricker | 2 | : | 3 |
| Aug 30 • 17:00 | Mackenzie McDonald | | - | | Borna Gojo | 0 | : | 3 |
| Aug 30 • 18:45 | Aslan Karatsev | | - | | Roberto Carballés Baena | 3 | : | 1 |
| Aug 30 • 18:45 | Benjamin Bonzi | | - | | Christopher Eubanks | 3 | : | 1 |
| Aug 30 • 18:45 | Jiří Veselý | | - | | Francisco Cerundolo | 3 | : | 2 |
| Aug 30 • 18:45 | Laslo Djere | | - | | Hugo Gaston | 3 | : | 0 |
| Aug 30 • 19:45 | Bernabe Zapata Miralles | | - | | Novak Djokovic | 0 | : | 3 |
| Aug 30 • 20:20 | Rinky Hijikata | | - | | Márton Fucsovics | 3 | : | 0 |
| Aug 30 • 20:45 | Adrian Mannarino | | - | | Fábián Marozsán | 3 | : | 1 |
| Aug 30 • 20:45 | Dominic Thiem | | - | | Ben Shelton | 0 | : | 1 |
| Aug 30 • 20:50 | Titouan Droguet | | - | | Jakub Mensik | 1 | : | 3 |
| Aug 30 • 21:15 | Tommy Paul | | - | | Roman Safiullin | 3 | : | 2 |
| Aug 30 • 21:15 | Juan Manuel Cerúndolo | | - | | Alejandro Davidovich Fokina | 0 | : | 3 |
| Aug 30 • 23:00 | Casper Ruud | | - | | Zhang Zhizhen | 2 | : | 3 |
| Aug 31 • 01:00 | Sebastian Ofner | | - | | Frances Tiafoe | 0 | : | 3 |
| Aug 31 • 02:15 | Juan Pablo Varillas | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Aug 31 • 17:00 | Alexander Zverev | | - | | Daniel Altmaier | 3 | : | 1 |
| Aug 31 • 17:00 | Lorenzo Sonego | | - | | Jannik Sinner | 0 | : | 3 |
| Aug 31 • 17:00 | Michael Mmoh | | - | | John Isner | 3 | : | 2 |
| Aug 31 • 17:00 | Jack Draper | | - | | Hubert Hurkacz | 3 | : | 0 |
| Aug 31 • 18:00 | Andy Murray | | - | | Grigor Dimitrov | 0 | : | 3 |
| Aug 31 • 18:30 | Matteo Berrettini | | - | | Arthur Rinderknech | 0 | : | 1 |
| Aug 31 • 19:00 | Tomás Martín Etcheverry | | - | | Stanislas Wawrinka | 1 | : | 3 |
| Aug 31 • 20:00 | Arthur Fils | | - | | Matteo Arnaldi | 2 | : | 3 |
| Aug 31 • 20:00 | Yibing Wu | | - | | Alex De Minaur | 0 | : | 3 |
| Aug 31 • 20:30 | Hsu Yu-hsiou | | - | | Cameron Norrie | 0 | : | 3 |
| Aug 31 • 20:30 | Nicolás Jarry | | - | | Alex Michelsen | 3 | : | 1 |
| Aug 31 • 20:30 | Gaël Monfils | | - | | Andrey Rublev | 1 | : | 3 |
| Aug 31 • 22:00 | Felipe Meligeni Alves | | - | | Sebastián Báez | 1 | : | 2 |
| Aug 31 • 22:30 | Botic van de Zandschulp | | - | | Daniel Evans | 1 | : | 3 |
| Sep 01 • 01:00 | Carlos Alcaraz Garfia | | - | | Lloyd Harris | 3 | : | 0 |
| Sep 01 • 02:30 | Daniil Medvedev | | - | | Christopher O'Connell | 3 | : | 1 |
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| Sep 01 • 18:00 | Tommy Paul | | - | | Alejandro Davidovich Fokina | 3 | : | 1 |
| Sep 01 • 18:15 | Ben Shelton | | - | | Aslan Karatsev | 3 | : | 1 |
| Sep 01 • 19:30 | Adrian Mannarino | | - | | Frances Tiafoe | 1 | : | 3 |
| Sep 01 • 19:45 | Zhang Zhizhen | | - | | Rinky Hijikata | 1 | : | 3 |
| Sep 01 • 20:15 | Dominic Stricker | | - | | Benjamin Bonzi | 3 | : | 2 |
| Sep 02 • 00:00 | Borna Gojo | | - | | Jiří Veselý | 3 | : | 0 |
| Sep 02 • 01:00 | Jakub Mensik | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Sep 02 • 02:15 | Laslo Djere | | - | | Novak Djokovic | 2 | : | 3 |
| Sep 02 • 17:00 | Michael Mmoh | | - | | Jack Draper | 1 | : | 3 |
| Sep 02 • 18:00 | Carlos Alcaraz Garfia | | - | | Daniel Evans | 3 | : | 1 |
| Sep 02 • 18:30 | Matteo Arnaldi | | - | | Cameron Norrie | 3 | : | 0 |
| Sep 02 • 19:00 | Arthur Rinderknech | | - | | Andrey Rublev | 1 | : | 3 |
| Sep 02 • 20:00 | Stanislas Wawrinka | | - | | Jannik Sinner | 1 | : | 3 |
| Sep 02 • 23:00 | Nicolás Jarry | | - | | Alex De Minaur | 0 | : | 3 |
| Sep 03 • 01:00 | Alexander Zverev | | - | | Grigor Dimitrov | 3 | : | 1 |
| Sep 03 • 02:30 | Daniil Medvedev | | - | | Sebastián Báez | 3 | : | 0 |
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| Sep 03 • 18:00 | Tommy Paul | | - | | Ben Shelton | 1 | : | 3 |
| Sep 03 • 20:00 | Rinky Hijikata | | - | | Frances Tiafoe | 0 | : | 3 |
| Sep 03 • 22:45 | Dominic Stricker | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Sep 04 • 01:00 | Borna Gojo | | - | | Novak Djokovic | 0 | : | 3 |
| Sep 04 • 18:30 | Jack Draper | | - | | Andrey Rublev | 1 | : | 3 |
| Sep 04 • 19:30 | Carlos Alcaraz Garfia | | - | | Matteo Arnaldi | 3 | : | 0 |
| Sep 04 • 23:00 | Daniil Medvedev | | - | | Alex De Minaur | 3 | : | 1 |
| Sep 05 • 02:30 | Alexander Zverev | | - | | Jannik Sinner | 3 | : | 2 |
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| Sep 05 • 19:30 | Taylor Harry Fritz | | - | | Novak Djokovic | 0 | : | 3 |
| Sep 06 • 03:00 | Frances Tiafoe | | - | | Ben Shelton | 1 | : | 3 |
| Sep 06 • 19:30 | Daniil Medvedev | | - | | Andrey Rublev | 3 | : | 0 |
| Sep 07 • 02:15 | Carlos Alcaraz Garfia | | - | | Alexander Zverev | 3 | : | 0 |
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| Sep 08 • 21:00 | Ben Shelton | | - | | Novak Djokovic | 0 | : | 3 |
| Sep 09 • 01:00 | Carlos Alcaraz Garfia | | - | | Daniil Medvedev | 1 | : | 3 |
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| Sep 10 • 22:00 | Daniil Medvedev | | - | | Novak Djokovic | 0 | : | 3 |
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