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| Sep 28 • 06:30 | Ugo Humbert |  | - |  | Lorenzo Sonego | 2 | : | 1 |
| Sep 28 • 08:00 | Matteo Arnaldi | | - |  | Jeffrey John Wolf | 2 | : | 0 |
| Sep 28 • 08:55 | Lloyd Harris |  | - |  | Tomás Martín Etcheverry | 1 | : | 2 |
| Sep 28 • 10:45 | Alejandro Davidovich Fokina |  | - |  | Zhou Yi | 2 | : | 0 |
| Sep 28 • 13:30 | Alex De Minaur |  | - |  | Andy Murray | 2 | : | 1 |
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| Sep 29 • 06:30 | Mackenzie McDonald | | - |  | Grigor Dimitrov | 1 | : | 2 |
| Sep 29 • 06:30 | Daniel Evans | | - | | Jannik Sinner | 1 | : | 2 |
| Sep 29 • 06:30 | Tommy Paul | | - |  | Daniil Medvedev | 0 | : | 2 |
| Sep 29 • 07:50 | Holger Rune |  | - |  | Felix Auger Aliassime | 2 | : | 0 |
| Sep 29 • 07:50 | Nicolás Jarry |  | - |  | Stefanos Tsitsipas | 2 | : | 0 |
| Sep 29 • 07:50 | Andrey Rublev | | - | | Cameron Norrie | 2 | : | 1 |
| Sep 29 • 09:30 | Alexander Zverev |  | - | | Diego Schwartzman | 2 | : | 1 |
| Sep 29 • 11:00 | Karen Khachanov | | - | | Lorenzo Musetti | 1 | : | 2 |
| Sep 29 • 11:15 | Shang Juncheng | | - |  | Yoshihito Nishioka | 1 | : | 2 |
| Sep 29 • 13:00 | Jan-Lennard Struff | | - |  | Casper Ruud | 0 | : | 2 |
| Sep 29 • 13:30 | Carlos Alcaraz | | - | | Yannick Hanfmann | 2 | : | 0 |
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| Sep 30 • 06:30 | Matteo Arnaldi | | - | | Nicolás Jarry | 1 | : | 2 |
| Sep 30 • 07:50 | Alex De Minaur | | - | | Daniil Medvedev | 0 | : | 2 |
| Sep 30 • 08:45 | Andrey Rublev | | - | | Ugo Humbert | 1 | : | 2 |
| Sep 30 • 16:30 | Alexander Zverev | | - | | Alejandro Davidovich Fokina | 2 | : | 1 |
| Oct 01 • 06:15 | Tomás Martín Etcheverry | | - | | Casper Ruud | 1 | : | 2 |
| Oct 01 • 07:35 | Yoshihito Nishioka | | - | | Jannik Sinner | 0 | : | 2 |
| Oct 01 • 10:00 | Carlos Alcaraz | | - | | Lorenzo Musetti | 2 | : | 0 |
| Oct 01 • 13:30 | Holger Rune | | - | | Grigor Dimitrov | 0 | : | 2 |
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| Oct 02 • 06:30 | Ugo Humbert | | - | | Daniil Medvedev | 1 | : | 2 |
| Oct 02 • 08:00 | Alexander Zverev | | - | | Nicolás Jarry | 2 | : | 1 |
| Oct 02 • 13:00 | Carlos Alcaraz | | - | | Casper Ruud | 2 | : | 0 |
| Oct 02 • 15:00 | Grigor Dimitrov | | - | | Jannik Sinner | 1 | : | 2 |
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| Oct 03 • 10:30 | Alexander Zverev | | - | | Daniil Medvedev | 0 | : | 2 |
| Oct 03 • 14:30 | Carlos Alcaraz | | - | | Jannik Sinner | 0 | : | 2 |
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| Oct 04 • 13:30 | Jannik Sinner | | - | | Daniil Medvedev | 2 | : | 0 |
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