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| Oct 09 • 17:30 | San Tirso SD |  | - |  | Selaya FC | 1 | : | 1 |
| Oct 09 • 18:30 | CD Sonseca |  | - |  | CP Parla Escuela | 0 | : | 1 |
| Oct 09 • 19:00 | Astur CF |  | - |  | CD Promesas EDF | 2 | : | 0 |
| Oct 09 • 19:00 | CD Baztán |  | - |  | Ontiñena CF | 1 | : | 1 |
| Oct 09 • 19:00 | UD San Pedro |  | - |  | CD Ceuta 6 de Junio | 4 | : | 2 |
| Oct 09 • 19:30 | CD Villamuriel |  | - |  | CD Aurrerá de Vitoria | 1 | : | 0 |
| Oct 09 • 20:00 | EF Dolorense |  | - |  | Manises CF | 1 | : | 3 |
| Oct 09 • 20:30 | UE Vic |  | - |  | CF Sporting de Mahón | 4 | : | 0 |
| Oct 09 • 20:30 | CD Gévora |  | - |  | UD Playas de Sotavento | 1 | : | 1 |
| Oct 09 • 21:00 | Chiclana CF |  | - |  | Melilla CD | 3 | : | 0 |
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| Oct 29 • 19:00 | CD Villamuriel | | - |  | Rayo Vallecano | 0 | : | 5 |
| Oct 29 • 19:00 | SD Compostela |  | - |  | Deportivo Alavés | 0 | : | 1 |
| Oct 29 • 20:00 | CD Guijuelo |  | - |  | Ourense CF | 1 | : | 2 |
| Oct 29 • 21:00 | Astur CF | | - |  | Real Valladolid | 1 | : | 4 |
| Oct 29 • 21:00 | UD Poblense |  | - |  | Villarreal CF | 1 | : | 6 |
| Oct 29 • 21:00 | Real Jaén |  | - |  | Cádiz CF | 0 | : | 3 |
| Oct 29 • 21:00 | CE L'Hospitalet |  | - |  | Real Zaragoza | 1 | : | 5 |
| Oct 29 • 21:00 | UD Lanzarote |  | - |  | Racing Santander | 3 | : | 4 |
| Oct 30 • 18:30 | CE Europa |  | - |  | Albacete Balompié | 2 | : | 1 |
| Oct 30 • 19:00 | Las Rozas CF |  | - |  | Sevilla FC | 0 | : | 3 |
| Oct 30 • 19:00 | CD Ciudad de Lucena |  | - |  | CD Leganés | 1 | : | 2 |
| Oct 30 • 19:00 | UE Olot |  | - |  | Córdoba CF | 1 | : | 1 |
| Oct 30 • 19:00 | CD Ibiza Islas Pitiusas |  | - |  | Gimnàstic de Tarragona | 1 | : | 2 |
| Oct 30 • 19:30 | SD Beasain |  | - |  | FC Cartagena | 0 | : | 1 |
| Oct 30 • 19:30 | CD Móstoles URJC |  | - |  | Burgos CF | 2 | : | 5 |
| Oct 30 • 19:30 | Bergantiños FC |  | - |  | Marbella FC | 1 | : | 2 |
| Oct 30 • 19:30 | UP Langreo |  | - |  | Orihuela CF | 1 | : | 2 |
| Oct 30 • 20:00 | CD Cortes |  | - |  | Granada CF | 0 | : | 2 |
| Oct 30 • 20:00 | UE Sant Andreu |  | - |  | CD Mirandés | 2 | : | 1 |
| Oct 30 • 20:00 | CF Badalona |  | - |  | SD Huesca | 0 | : | 2 |
| Oct 30 • 20:00 | UD Logroñés |  | - |  | SD Eibar | 1 | : | 0 |
| Oct 30 • 20:00 | CD Numancia |  | - |  | Sporting de Gijon | 0 | : | 1 |
| Oct 30 • 20:00 | Utebo FC |  | - |  | Unionistas de Salamanca | 0 | : | 4 |
| Oct 30 • 20:00 | CD Laredo |  | - |  | Yeclano Deportivo | 0 | : | 6 |
| Oct 30 • 20:00 | Juventud de Torremolinos CF |  | - |  | Zamora CF | 1 | : | 2 |
| Oct 30 • 20:00 | UM Escobedo |  | - |  | SD Ponferradina | 0 | : | 0 |
| Oct 30 • 20:00 | Lleida CF |  | - |  | Barakaldo CF | 1 | : | 3 |
| Oct 30 • 20:00 | Salamanca CF UDS |  | - |  | AD Alcorcón | 1 | : | 0 |
| Oct 30 • 20:30 | CD Coria |  | - |  | Elche CF | 0 | : | 3 |
| Oct 30 • 20:30 | CP Cacereño |  | - |  | Gimnástica Segoviana | 2 | : | 1 |
| Oct 30 • 20:30 | UB Conquense |  | - |  | UD Ibiza | 1 | : | 0 |
| Oct 30 • 21:00 | UD San Pedro | | - |  | Celta de Vigo | 1 | : | 5 |
| Oct 30 • 21:00 | CD Extremadura 1924 |  | - |  | Girona FC | 0 | : | 4 |
| Oct 30 • 21:00 | UD San Sebastián de los Reyes |  | - |  | UD Almeria | 1 | : | 2 |
| Oct 30 • 21:00 | Águilas FC |  | - |  | CD Castellón | 0 | : | 1 |
| Oct 30 • 21:30 | CD Atlético Paso |  | - |  | CD Eldense | 0 | : | 1 |
| Oct 31 • 19:00 | UE Vic | | - |  | Atlético Madrid | 0 | : | 2 |
| Oct 31 • 19:00 | San Tirso SD | | - |  | RCD Espanyol | 0 | : | 4 |
| Oct 31 • 19:00 | UD Barbastro |  | - |  | SD Amorebieta | 4 | : | 0 |
| Oct 31 • 20:00 | Real Ávila |  | - |  | Real Oviedo | 0 | : | 0 |
| Oct 31 • 20:00 | CD Tudelano |  | - |  | CD Minera | 0 | : | 5 |
| Oct 31 • 20:30 | CD Don Benito |  | - |  | FC Andorra | 1 | : | 2 |
| Oct 31 • 21:00 | CD Gévora | | - |  | Real Betis | 1 | : | 6 |
| Oct 31 • 21:00 | Ontiñena CF | | - |  | UD Las Palmas | 0 | : | 7 |
| Oct 31 • 21:00 | CD Cuarte |  | - |  | Racing de Ferrol | 1 | : | 3 |
| Oct 31 • 21:00 | CD Estepona FS |  | - |  | Málaga CF | 3 | : | 2 |
| Oct 31 • 21:00 | CD Alfaro |  | - |  | CD Tenerife | 0 | : | 2 |
| Oct 31 • 21:00 | UD Llanera |  | - |  | Cultural Leonesa | 0 | : | 2 |
| Nov 05 • 19:00 | Chiclana CF | | - |  | CA Osasuna | 0 | : | 5 |
| Nov 06 • 19:00 | Xerez CD |  | - |  | AD Ceuta FC | 0 | : | 1 |
| Nov 14 • 18:00 | SD Ejea |  | - |  | Hércules CF | 1 | : | 0 |
| Nov 19 • 20:00 | Pontevedra CF |  | - |  | Levante UD | 4 | : | 1 |
| Nov 21 • 21:00 | Jove Español San Vicente |  | - |  | Real Sociedad | 0 | : | 5 |
| Nov 26 • 19:00 | CP Parla Escuela | | - |  | Valencia CF | 0 | : | 1 |
| Nov 26 • 19:00 | Manises CF | | - |  | Getafe CF | 0 | : | 3 |
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| Dec 03 • 19:00 | Real Ávila | | - | | Real Valladolid | 2 | : | 4 |
| Dec 03 • 20:00 | Yeclano Deportivo | | - | | Elche CF | 0 | : | 1 |
| Dec 03 • 21:00 | Salamanca CF UDS | | - | | Celta de Vigo | 0 | : | 7 |
| Dec 03 • 21:00 | UD Barbastro | | - | | RCD Espanyol | 2 | : | 0 |
| Dec 03 • 21:00 | Real Zaragoza | | - | | Granada CF | 2 | : | 2 |
| Dec 03 • 21:15 | CE Europa | | - | | UD Las Palmas | 1 | : | 2 |
| Dec 04 • 19:00 | UE Sant Andreu | | - | | Real Betis | 1 | : | 3 |
| Dec 04 • 19:00 | Unionistas de Salamanca | | - | | Rayo Vallecano | 2 | : | 3 |
| Dec 04 • 19:00 | Gimnàstic de Tarragona | | - | | SD Huesca | 0 | : | 1 |
| Dec 04 • 20:00 | Ourense CF | | - |  | Deportivo La Coruña | 1 | : | 0 |
| Dec 04 • 20:00 | Cultural Leonesa | | - | | UD Almeria | 1 | : | 2 |
| Dec 04 • 20:00 | Cádiz CF | | - | | CD Eldense | 0 | : | 1 |
| Dec 04 • 20:30 | Racing Santander | | - | | Sporting de Gijon | 1 | : | 0 |
| Dec 04 • 21:00 | UD Logroñés | | - | | Girona FC | 0 | : | 0 |
| Dec 04 • 21:00 | SD Ejea | | - | | Valencia CF | 1 | : | 3 |
| Dec 04 • 21:00 | Pontevedra CF | | - | | Villarreal CF | 1 | : | 0 |
| Dec 04 • 21:00 | CD Estepona FS | | - | | CD Leganés | 2 | : | 2 |
| Dec 04 • 21:00 | Zamora CF | | - | | CD Tenerife | 0 | : | 0 |
| Dec 05 • 19:00 | CP Cacereño | | - | | Atlético Madrid | 1 | : | 3 |
| Dec 05 • 19:00 | Orihuela CF | | - | | Getafe CF | 0 | : | 0 |
| Dec 05 • 19:00 | AD Ceuta FC | | - | | CA Osasuna | 2 | : | 3 |
| Dec 05 • 20:00 | SD Ponferradina | | - | | CD Castellón | 1 | : | 1 |
| Dec 05 • 20:00 | Barakaldo CF | | - | | Racing de Ferrol | 1 | : | 2 |
| Dec 05 • 20:00 | Marbella FC | | - | | Burgos CF | 1 | : | 0 |
| Dec 05 • 20:00 | FC Andorra | | - | | FC Cartagena | 0 | : | 1 |
| Dec 05 • 21:00 | UE Olot | | - | | Sevilla FC | 1 | : | 3 |
| Dec 05 • 21:00 | CD Minera | | - | | Deportivo Alavés | 2 | : | 2 |
| Dec 05 • 21:00 | UB Conquense | | - | | Real Sociedad | 0 | : | 1 |
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| Jan 03 • 19:00 | Granada CF | | - | | Getafe CF | 0 | : | 1 |
| Jan 03 • 19:00 | Pontevedra CF | | - |  | RCD Mallorca | 3 | : | 0 |
| Jan 03 • 19:00 | Racing de Ferrol | | - | | Rayo Vallecano | 1 | : | 3 |
| Jan 04 • 15:30 | SD Huesca | | - | | Real Betis | 0 | : | 1 |
| Jan 04 • 16:30 | CD Tenerife | | - | | CA Osasuna | 1 | : | 2 |
| Jan 04 • 17:30 | UD Almeria | | - | | Sevilla FC | 4 | : | 1 |
| Jan 04 • 19:00 | UD Barbastro | | - |  | FC Barcelona | 0 | : | 4 |
| Jan 04 • 21:30 | Marbella FC | | - | | Atlético Madrid | 0 | : | 1 |
| Jan 04 • 21:30 | UD Logroñés | | - |  | Athletic Bilbao | 0 | : | 0 |
| Jan 05 • 12:00 | Elche CF | | - | | UD Las Palmas | 4 | : | 0 |
| Jan 05 • 12:00 | Ourense CF | | - | | Real Valladolid | 3 | : | 2 |
| Jan 05 • 15:30 | FC Cartagena | | - | | CD Leganés | 1 | : | 2 |
| Jan 05 • 15:30 | SD Ponferradina | | - | | Real Sociedad | 0 | : | 2 |
| Jan 05 • 15:30 | Racing Santander | | - | | Celta de Vigo | 2 | : | 3 |
| Jan 06 • 19:00 | CD Minera | | - |  | Real Madrid | 0 | : | 5 |
| Jan 07 • 21:00 | CD Eldense | | - | | Valencia CF | 0 | : | 2 |
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| Jan 14 • 21:00 | Ourense CF | | - | | Valencia CF | 0 | : | 2 |
| Jan 15 • 19:30 | Pontevedra CF | | - | | Getafe CF | 0 | : | 1 |
| Jan 15 • 19:30 | UD Almeria | | - | | CD Leganés | 2 | : | 3 |
| Jan 15 • 21:00 | FC Barcelona | | - | | Real Betis | 5 | : | 1 |
| Jan 15 • 21:30 | Elche CF | | - | | Atlético Madrid | 0 | : | 4 |
| Jan 16 • 19:30 | Real Sociedad | | - | | Rayo Vallecano | 3 | : | 1 |
| Jan 16 • 19:30 | Athletic Bilbao | | - | | CA Osasuna | 2 | : | 3 |
| Jan 16 • 21:30 | Real Madrid | | - | | Celta de Vigo | 5 | : | 2 |
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| Feb 04 • 21:30 | Atlético Madrid | | - | | Getafe CF | 5 | : | 0 |
| Feb 05 • 21:00 | CD Leganés | | - | | Real Madrid | 2 | : | 3 |
| Feb 06 • 19:30 | Real Sociedad | | - | | CA Osasuna | 2 | : | 0 |
| Feb 06 • 21:30 | Valencia CF | | - | | FC Barcelona | 0 | : | 5 |
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| Feb 25 • 21:30 | FC Barcelona | | - | | Atlético Madrid | 4 | : | 4 |
| Feb 26 • 21:30 | Real Sociedad | | - | | Real Madrid | 0 | : | 1 |
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| Apr 01 • 21:30 | Real Madrid | | - | | Real Sociedad |
| Apr 02 • 21:30 | Atlético Madrid | | - | | FC Barcelona |
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| Apr 26 • 00:00 | [ tbd ] | | - | | [ tbd ] |
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