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| Feb 19 • 20:30 | Francisco Cerundolo |  | - | | Francisco Comesana | 2 | : | 1 |
| Feb 19 • 20:30 | Juan Pablo Varillas |  | - |  | Albert Ramos-Viñolas | 1 | : | 2 |
| Feb 19 • 20:30 | Gustavo Heide |  | - |  | Tomas Barrios Vera | 0 | : | 2 |
| Feb 19 • 23:00 | Hugo Dellien |  | - |  | Cameron Norrie | 0 | : | 2 |
| Feb 19 • 23:30 | Bernabe Zapata Miralles | | - |  | Laslo Djere | 0 | : | 2 |
| Feb 19 • 23:30 | Sebastian Ofner |  | - | | Jaume Munar | 0 | : | 2 |
| Feb 20 • 00:30 | Alejandro Tabilo | | - | | Thiago Seyboth Wild | 1 | : | 2 |
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| Feb 20 • 20:30 | Felipe Meligeni Alves | | - | | Pedro Cachín | 2 | : | 1 |
| Feb 20 • 20:30 | Facundo Díaz Acosta | | - |  | Stanislas Wawrinka | 2 | : | 0 |
| Feb 20 • 20:30 | Corentin Moutet |  | - | | Sebastián Báez | 0 | : | 2 |
| Feb 20 • 20:30 | Dušan Lajović | | - |  | Daniel Elahi Galán | 2 | : | 1 |
| Feb 20 • 21:50 | Roberto Carballés Baena | | - | | Cristian Garín | 1 | : | 2 |
| Feb 20 • 21:50 | Federico Coria | | - | | Mariano Navone | 1 | : | 2 |
| Feb 20 • 21:50 | Yannick Hanfmann |  | - | | Nicolás Jarry | 2 | : | 1 |
| Feb 20 • 23:00 | Carlos Alcaraz | | - | | Thiago Moura Monteiro | 0 | : | 0 |
| Feb 21 • 20:30 | Arthur Fils | | - | | Joao Fonseca | 0 | : | 2 |
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| Feb 21 • 20:30 | Francisco Cerundolo | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Feb 21 • 23:00 | Jaume Munar | | - | | Thiago Seyboth Wild | 1 | : | 2 |
| Feb 22 • 19:00 | Dušan Lajović | | - | | Laslo Djere | 2 | : | 0 |
| Feb 22 • 20:20 | Facundo Díaz Acosta | | - | | Sebastián Báez | 0 | : | 2 |
| Feb 22 • 20:30 | Tomas Barrios Vera | | - | | Cameron Norrie | 0 | : | 2 |
| Feb 22 • 21:40 | Mariano Navone | | - | | Yannick Hanfmann | 2 | : | 0 |
| Feb 22 • 23:00 | Thiago Moura Monteiro | | - | | Felipe Meligeni Alves | 2 | : | 0 |
| Feb 23 • 00:20 | Joao Fonseca | | - | | Cristian Garín | 2 | : | 0 |
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| Feb 23 • 20:00 | Francisco Cerundolo | | - | | Dušan Lajović | 2 | : | 1 |
| Feb 23 • 20:30 | Thiago Moura Monteiro | | - | | Sebastián Báez | 1 | : | 2 |
| Feb 23 • 22:00 | Thiago Seyboth Wild | | - | | Cameron Norrie | 1 | : | 2 |
| Feb 24 • 00:20 | Joao Fonseca | | - | | Mariano Navone | 1 | : | 2 |
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| Feb 24 • 21:00 | Sebastián Báez | | - | | Francisco Cerundolo | 2 | : | 0 |
| Feb 24 • 22:20 | Mariano Navone | | - | | Cameron Norrie | 2 | : | 0 |
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| Feb 25 • 21:30 | Sebastián Báez | | - | | Mariano Navone | 2 | : | 0 |
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