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| Apr 15 • 11:00 | Facundo Díaz Acosta |  | - |  | Daniel Rincón | 2 | : | 0 |
| Apr 15 • 11:00 | Daniel Evans |  | - |  | Brandon Nakashima | 0 | : | 2 |
| Apr 15 • 12:30 | Roman Safiullin |  | - | | Roberto Bautista-Agut | 0 | : | 2 |
| Apr 15 • 13:30 | Matteo Arnaldi |  | - |  | Arthur Cazaux | 0 | : | 0 |
| Apr 15 • 13:45 | Duje Ajduković |  | - | | Marco Trungelliti | 0 | : | 2 |
| Apr 15 • 14:15 | Nick Hardt |  | - | | Martin Landaluce | 2 | : | 1 |
| Apr 15 • 14:45 | Harold Mayot | | - | | Pedro Cachín | 2 | : | 1 |
| Apr 15 • 16:05 | Pavel Kotov | | - |  | Sebastian Ofner | 1 | : | 2 |
| Apr 15 • 16:15 | Alexandre Muller | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Apr 16 • 11:00 | Luca Van Assche | | - |  | Zhang Zhizhen | 2 | : | 0 |
| Apr 16 • 11:00 | Hugo Grenier | | - | | Roberto Carballés Baena | 0 | : | 2 |
| Apr 16 • 11:00 | Diego Schwartzman | | - |  | Dušan Lajović | 0 | : | 2 |
| Apr 16 • 12:30 | Jaume Munar | | - |  | Yoshihito Nishioka | 2 | : | 0 |
| Apr 16 • 14:15 | Tomáš Macháč |  | - | | Shang Juncheng | 2 | : | 0 |
| Apr 16 • 15:30 | Daniel Altmaier |  | - |  | Alexei Popyrin | 2 | : | 0 |
| Apr 16 • 16:00 | Flavio Cobolli | | - | | Rafael Nadal | 0 | : | 2 |
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| Apr 16 • 12:25 | Facundo Díaz Acosta | | - | | Borna Ćorić | 2 | : | 0 |
| Apr 16 • 14:00 | Brandon Nakashima | | - | | Andrey Rublev | 2 | : | 0 |
| Apr 16 • 15:30 | Sebastián Báez | | - | | Matteo Arnaldi | 1 | : | 2 |
| Apr 16 • 17:00 | Harold Mayot | | - | | Cameron Norrie | 1 | : | 1 |
| Apr 16 • 17:00 | Tomás Martín Etcheverry | | - | | Nick Hardt | 2 | : | 0 |
| Apr 17 • 11:00 | Alejandro Davidovich Fokina | | - | | Tomáš Macháč | 0 | : | 0 |
| Apr 17 • 11:00 | Andrea Vavassori | | - | | Roberto Bautista-Agut | 1 | : | 2 |
| Apr 17 • 12:30 | Marco Trungelliti | | - |  | Nicolás Jarry | 2 | : | 0 |
| Apr 17 • 12:30 | Jordan Thompson | | - | | Jaume Munar | 2 | : | 1 |
| Apr 17 • 12:30 | Alexandre Muller | | - |  | Casper Ruud | 0 | : | 2 |
| Apr 17 • 14:00 | Lorenzo Musetti | | - | | Roberto Carballés Baena | 0 | : | 2 |
| Apr 17 • 14:00 | Dušan Lajović | | - | | Ugo Humbert | 2 | : | 0 |
| Apr 17 • 15:30 | Fábián Marozsán |  | - | | Luca Van Assche | 1 | : | 0 |
| Apr 17 • 15:30 | Daniel Altmaier | | - | | Arthur Fils | 1 | : | 2 |
| Apr 17 • 16:00 | Alex De Minaur | | - | | Rafael Nadal | 2 | : | 0 |
| Apr 17 • 17:30 | Sebastian Ofner | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
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| Apr 18 • 11:00 | Roberto Bautista-Agut | | - | | Cameron Norrie | 0 | : | 2 |
| Apr 18 • 11:00 | Tomás Martín Etcheverry | | - | | Brandon Nakashima | 2 | : | 1 |
| Apr 18 • 12:30 | Alejandro Davidovich Fokina | | - | | Dušan Lajović | 1 | : | 2 |
| Apr 18 • 12:30 | Matteo Arnaldi | | - | | Marco Trungelliti | 2 | : | 0 |
| Apr 18 • 14:00 | Fábián Marozsán | | - | | Facundo Díaz Acosta | 1 | : | 2 |
| Apr 18 • 16:00 | Alex De Minaur | | - | | Arthur Fils | 0 | : | 2 |
| Apr 18 • 16:00 | Jordan Thompson | | - | | Casper Ruud | 0 | : | 2 |
| Apr 18 • 17:30 | Roberto Carballés Baena | | - | | Stefanos Tsitsipas | 0 | : | 2 |
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| Apr 19 • 12:30 | Cameron Norrie | | - | | Tomás Martín Etcheverry | 0 | : | 2 |
| Apr 19 • 14:00 | Matteo Arnaldi | | - | | Casper Ruud | 0 | : | 2 |
| Apr 19 • 16:00 | Facundo Díaz Acosta | | - | | Stefanos Tsitsipas | 1 | : | 2 |
| Apr 19 • 17:30 | Arthur Fils | | - | | Dušan Lajović | 1 | : | 2 |
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| Apr 20 • 13:30 | Casper Ruud | | - | | Tomás Martín Etcheverry | 2 | : | 0 |
| Apr 20 • 16:00 | Stefanos Tsitsipas | | - | | Dušan Lajović | 2 | : | 1 |
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| Apr 21 • 16:00 | Stefanos Tsitsipas | | - | | Casper Ruud | 0 | : | 2 |
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