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| Jul 15 • 12:00 | Flavio Cobolli |  | - |  | Daniel Altmaier | 2 | : | 1 |
| Jul 15 • 13:00 | Ugo Blanchet |  | - |  | Alexei Popyrin | 2 | : | 1 |
| Jul 15 • 13:20 | Kwon Soon-woo |  | - | | Maximilian Marterer | 1 | : | 2 |
| Jul 15 • 14:20 | Laslo Djere |  | - |  | Zizou Bergs | 2 | : | 0 |
| Jul 15 • 16:30 | Rudolf Molleker | | - |  | Alexander Shevchenko | 1 | : | 2 |
| Jul 15 • 16:40 | Francisco Cerundolo |  | - | | Francisco Comesana | 2 | : | 0 |
| Jul 15 • 18:30 | Pedro Martínez |  | - | | Matteo Arnaldi | 2 | : | 0 |
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| Jul 16 • 11:00 | Luciano Darderi | | - |  | Nick Hardt | 2 | : | 1 |
| Jul 16 • 12:00 | Arthur Fils | | - | | Jaume Munar | 2 | : | 1 |
| Jul 16 • 12:20 | Felipe Meligeni Alves |  | - | | Dušan Lajović | 1 | : | 2 |
| Jul 16 • 13:20 | Thiago Seyboth Wild | | - |  | Zhang Zhizhen | 0 | : | 2 |
| Jul 16 • 13:40 | Marco Trungelliti | | - |  | Sebastian Ofner | 1 | : | 0 |
| Jul 16 • 14:40 | Dominik Koepfer | | - | | Sebastián Báez | 0 | : | 2 |
| Jul 16 • 15:00 | Facundo Díaz Acosta | | - | | Hugo Gaston | 1 | : | 2 |
| Jul 16 • 18:30 | Fábián Marozsán |  | - |  | Holger Rune | 0 | : | 2 |
| Jul 17 • 14:00 | Alexander Zverev | | - |  | Jesper de Jong | 2 | : | 0 |
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| Jul 17 • 12:00 | Luciano Darderi | | - | | Alexander Shevchenko | 2 | : | 1 |
| Jul 17 • 13:20 | Ugo Blanchet | | - | | Pedro Martínez | 1 | : | 2 |
| Jul 17 • 15:20 | Francisco Cerundolo | | - | | Maximilian Marterer | 2 | : | 0 |
| Jul 17 • 18:30 | Dušan Lajović | | - | | Sebastián Báez | 1 | : | 2 |
| Jul 18 • 12:00 | Arthur Fils | | - | | Laslo Djere | 2 | : | 0 |
| Jul 18 • 13:20 | Flavio Cobolli | | - | | Zhang Zhizhen | 0 | : | 2 |
| Jul 18 • 14:40 | Marco Trungelliti | | - | | Holger Rune | 0 | : | 2 |
| Jul 18 • 18:30 | Alexander Zverev | | - | | Hugo Gaston | 2 | : | 1 |
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| Jul 19 • 12:00 | Luciano Darderi | | - | | Sebastián Báez | 1 | : | 2 |
| Jul 19 • 13:30 | Arthur Fils | | - | | Holger Rune | 1 | : | 0 |
| Jul 19 • 15:00 | Francisco Cerundolo | | - | | Pedro Martínez | 1 | : | 2 |
| Jul 19 • 18:30 | Alexander Zverev | | - | | Zhang Zhizhen | 2 | : | 0 |
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| Jul 20 • 15:30 | Sebastián Báez | | - | | Arthur Fils | 0 | : | 2 |
| Jul 20 • 16:50 | Alexander Zverev | | - | | Pedro Martínez | 2 | : | 0 |
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| Jul 21 • 15:00 | Alexander Zverev | | - | | Arthur Fils | 1 | : | 2 |
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