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| Sep 26 • 05:00 | Adrian Mannarino |  | - |  | Lorenzo Sonego | 2 | : | 1 |
| Sep 26 • 06:30 | Zhou Yi |  | - |  | Pavel Kotov | 1 | : | 2 |
| Sep 26 • 08:00 | Jannik Sinner | | - |  | Nicolás Jarry | 2 | : | 1 |
| Sep 26 • 09:30 | Tallon Griekspoor |  | - |  | Miomir Kecmanovic | 2 | : | 1 |
| Sep 26 • 13:00 | Jiří Lehečka |  | - |  | Pedro Martínez | 2 | : | 0 |
| Sep 26 • 14:30 | Alexander Bublik |  | - | | Flavio Cobolli | 1 | : | 2 |
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| Sep 27 • 05:00 | Roman Safiullin | | - |  | Stanislas Wawrinka | 2 | : | 0 |
| Sep 27 • 05:00 | Shang Juncheng | | - | | Bu Yunchaokete | 1 | : | 2 |
| Sep 27 • 05:00 | Francisco Cerundolo |  | - | | Jakub Mensik | 2 | : | 0 |
| Sep 27 • 06:15 | Gaël Monfils | | - | | Daniil Medvedev | 0 | : | 2 |
| Sep 27 • 06:20 | Roberto Bautista-Agut | | - | | Arthur Rinderknech | 2 | : | 0 |
| Sep 27 • 06:20 | Zizou Bergs |  | - | | Lorenzo Musetti | 1 | : | 2 |
| Sep 27 • 07:40 | Karen Khachanov | | - | | Roberto Carballés Baena | 2 | : | 0 |
| Sep 27 • 09:00 | Giovanni Mpetshi Perricard | | - | | Carlos Alcaraz | 0 | : | 2 |
| Sep 27 • 12:15 | Andrey Rublev | | - | | Pablo Carreño Busta | 2 | : | 1 |
| Sep 27 • 13:00 | Alejandro Davidovich Fokina | | - | | Zhang Zhizhen | 2 | : | 1 |
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| Sep 28 • 05:00 | Flavio Cobolli | | - | | Pavel Kotov | 2 | : | 0 |
| Sep 28 • 06:20 | Jiří Lehečka | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| Sep 28 • 07:30 | Jannik Sinner | | - | | Roman Safiullin | 2 | : | 1 |
| Sep 28 • 14:30 | Adrian Mannarino | | - | | Daniil Medvedev | 0 | : | 2 |
| Sep 29 • 05:00 | Bu Yunchaokete | | - | | Lorenzo Musetti | 2 | : | 0 |
| Sep 29 • 06:15 | Karen Khachanov | | - | | Francisco Cerundolo | 2 | : | 0 |
| Sep 29 • 07:30 | Andrey Rublev | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Sep 29 • 13:00 | Tallon Griekspoor | | - | | Carlos Alcaraz | 0 | : | 2 |
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| Sep 30 • 10:00 | Flavio Cobolli | | - | | Daniil Medvedev | 0 | : | 2 |
| Sep 30 • 10:00 | Karen Khachanov | | - | | Carlos Alcaraz | 0 | : | 2 |
| Sep 30 • 13:20 | Jannik Sinner | | - | | Jiří Lehečka | 2 | : | 0 |
| Sep 30 • 14:15 | Andrey Rublev | | - | | Bu Yunchaokete | 0 | : | 2 |
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| Oct 01 • 10:00 | Daniil Medvedev | | - | | Carlos Alcaraz | 0 | : | 2 |
| Oct 01 • 13:00 | Jannik Sinner | | - | | Bu Yunchaokete | 2 | : | 0 |
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| Oct 02 • 11:00 | Jannik Sinner | | - | | Carlos Alcaraz | 1 | : | 2 |
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