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| Oct 02 • 06:30 | Pablo Carreño Busta |  | - |  | Botic van de Zandschulp | 0 | : | 2 |
| Oct 02 • 06:30 | Luca Nardi |  | - |  | Alexandre Muller | 1 | : | 2 |
| Oct 02 • 06:30 | Yibing Wu |  | - |  | Sumit Nagal | 2 | : | 0 |
| Oct 02 • 06:30 | Reilly Opelka |  | - | | Arthur Rinderknech | 0 | : | 2 |
| Oct 02 • 07:50 | Roberto Bautista-Agut | | - | | Roberto Carballés Baena | 1 | : | 2 |
| Oct 02 • 07:50 | Gaël Monfils | | - |  | Damir Džumhur | 2 | : | 0 |
| Oct 02 • 07:50 | Marin Čilić |  | - | | Arthur Cazaux | 0 | : | 2 |
| Oct 02 • 07:50 | Fabio Fognini | | - | | Luciano Darderi | 2 | : | 1 |
| Oct 02 • 09:10 | Lorenzo Sonego | | - |  | Denis Shapovalov | 0 | : | 2 |
| Oct 02 • 09:10 | Adrian Mannarino | | - | | Zachary Svajda | 1 | : | 2 |
| Oct 02 • 09:10 | Aleksandar Vukic |  | - | | Corentin Moutet | 2 | : | 1 |
| Oct 02 • 10:30 | Egor Gerasimov |  | - |  | Taro Daniel | 1 | : | 2 |
| Oct 02 • 10:30 | Thiago Seyboth Wild |  | - |  | Daniel Evans | 2 | : | 1 |
| Oct 02 • 10:30 | Alejandro Davidovich Fokina | | - | | Gabriel Diallo | 2 | : | 0 |
| Oct 02 • 12:30 | Shang Juncheng | | - |  | Coleman Wong | 2 | : | 0 |
| Oct 02 • 13:50 | Kei Nishikori | | - |  | Mariano Navone | 2 | : | 1 |
| Oct 03 • 06:30 | Miomir Kecmanovic |  | - | | Rinky Hijikata | 2 | : | 0 |
| Oct 03 • 06:30 | Yoshihito Nishioka | | - | | Zhou Yi | 0 | : | 0 |
| Oct 03 • 06:30 | Jaume Munar | | - | | Hugo Gaston | 2 | : | 0 |
| Oct 03 • 06:30 | David Goffin |  | - | | James Duckworth | 2 | : | 0 |
| Oct 03 • 07:50 | Jakub Mensik |  | - | | Pedro Martínez | 2 | : | 1 |
| Oct 03 • 07:50 | Christopher O'Connell | | - | | Matteo Berrettini | 0 | : | 2 |
| Oct 03 • 07:50 | Li Tu | | - | | Marcos Giron | 0 | : | 2 |
| Oct 03 • 07:50 | Tallon Griekspoor | | - | | Facundo Díaz Acosta | 2 | : | 1 |
| Oct 03 • 09:05 | Ramkumar Ramanathan | | - |  | Alexander Shevchenko | 0 | : | 2 |
| Oct 03 • 09:10 | Beibit Zhukayev |  | - | | Roman Safiullin | 0 | : | 2 |
| Oct 03 • 09:10 | Pavel Kotov | | - | | Yosuke Watanuki | 1 | : | 2 |
| Oct 03 • 11:00 | Aleksandar Kovacevic | | - | | Terence Atmane | 0 | : | 2 |
| Oct 03 • 11:15 | Mattia Bellucci | | - | | Billy Harris | 2 | : | 0 |
| Oct 03 • 12:30 | Zhang Zhizhen | | - | | Zizou Bergs | 0 | : | 2 |
| Oct 03 • 13:50 | Stanislas Wawrinka |  | - | | Giovanni Mpetshi Perricard | 2 | : | 0 |
| Oct 04 • 08:00 | Alex Michelsen | | - | | Bu Yunchaokete | 2 | : | 0 |
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| Oct 04 • 06:30 | Denis Shapovalov | | - | | Ben Shelton | 0 | : | 2 |
| Oct 04 • 06:30 | Alexandre Muller | | - | | Felix Auger Aliassime | 2 | : | 0 |
| Oct 04 • 06:30 | Tommy Paul | | - | | Fabio Fognini | 2 | : | 0 |
| Oct 04 • 06:30 | Arthur Rinderknech | | - |  | Alejandro Tabilo | 0 | : | 2 |
| Oct 04 • 08:00 | Stefanos Tsitsipas |  | - | | Kei Nishikori | 2 | : | 0 |
| Oct 04 • 08:00 | Matteo Arnaldi | | - | | Zachary Svajda | 2 | : | 1 |
| Oct 04 • 08:00 | Sebastián Báez | | - | | Gaël Monfils | 1 | : | 2 |
| Oct 04 • 09:30 | Botic van de Zandschulp | | - | | Tomás Martín Etcheverry | 1 | : | 2 |
| Oct 04 • 09:30 | Arthur Fils | | - | | Roberto Carballés Baena | 0 | : | 2 |
| Oct 04 • 09:30 | Arthur Cazaux | | - | | Ugo Humbert | 0 | : | 2 |
| Oct 04 • 11:00 | Yibing Wu | | - | | Nicolás Jarry | 2 | : | 0 |
| Oct 04 • 11:00 | Tomáš Macháč | | - | | Alejandro Davidovich Fokina | 2 | : | 1 |
| Oct 04 • 12:30 | Thiago Seyboth Wild | | - | | Daniil Medvedev | 0 | : | 2 |
| Oct 04 • 14:00 | Aleksandar Vukic | | - |  | Casper Ruud | 2 | : | 0 |
| Oct 05 • 06:30 | Carlos Alcaraz | | - | | Shang Juncheng | 2 | : | 0 |
| Oct 05 • 06:30 | Andrey Rublev | | - | | Jakub Mensik | 1 | : | 2 |
| Oct 05 • 06:30 | Alexander Shevchenko | | - | | Francisco Cerundolo | 2 | : | 0 |
| Oct 05 • 06:30 | Yosuke Watanuki | | - | | Brandon Nakashima | 2 | : | 0 |
| Oct 05 • 07:50 | Jannik Sinner | | - | | Taro Daniel | 2 | : | 0 |
| Oct 05 • 07:50 | Alexei Popyrin | | - | | Miomir Kecmanovic | 2 | : | 0 |
| Oct 05 • 07:50 | Zizou Bergs | | - |  | Grigor Dimitrov | 1 | : | 2 |
| Oct 05 • 07:50 | Taylor Harry Fritz | | - | | Terence Atmane | 2 | : | 0 |
| Oct 05 • 07:50 | Jiří Lehečka | | - | | Jaume Munar | 2 | : | 0 |
| Oct 05 • 09:10 | Roman Safiullin | | - | | Alexander Bublik | 2 | : | 0 |
| Oct 05 • 12:30 | Alex Michelsen | | - | | Novak Djokovic | 0 | : | 2 |
| Oct 05 • 13:50 | Mattia Bellucci | | - |  | Alexander Zverev | 0 | : | 2 |
| Oct 07 • 07:30 | Lorenzo Musetti | | - | | David Goffin | 1 | : | 2 |
| Oct 07 • 07:30 | Marcos Giron | | - | | Karen Khachanov | 2 | : | 0 |
| Oct 07 • 07:30 | Jordan Thompson | | - | | Tallon Griekspoor | 0 | : | 2 |
| Oct 07 • 08:30 | Frances Tiafoe | | - | | Zhou Yi | 2 | : | 0 |
| Oct 07 • 12:30 | Matteo Berrettini | | - |  | Holger Rune | 1 | : | 2 |
| Oct 07 • 14:00 | Flavio Cobolli | | - | | Stanislas Wawrinka | 2 | : | 1 |
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| Oct 06 • 06:30 | Matteo Arnaldi | | - | | Daniil Medvedev | 1 | : | 2 |
| Oct 06 • 07:50 | Jannik Sinner | | - | | Tomás Martín Etcheverry | 2 | : | 1 |
| Oct 06 • 12:30 | Carlos Alcaraz | | - | | Yibing Wu | 2 | : | 0 |
| Oct 06 • 13:50 | Tommy Paul | | - | | Alejandro Tabilo | 2 | : | 1 |
| Oct 08 • 06:30 | Stefanos Tsitsipas | | - | | Alexandre Muller | 2 | : | 0 |
| Oct 08 • 06:30 | Gaël Monfils | | - | | Ugo Humbert | 2 | : | 1 |
| Oct 08 • 06:30 | Tomáš Macháč | | - | | Aleksandar Vukic | 2 | : | 0 |
| Oct 08 • 06:30 | Jakub Mensik | | - | | Alexander Shevchenko | 2 | : | 1 |
| Oct 08 • 07:50 | Roberto Carballés Baena | | - | | Ben Shelton | 0 | : | 2 |
| Oct 08 • 07:50 | Alexei Popyrin | | - | | Grigor Dimitrov | 0 | : | 2 |
| Oct 08 • 07:50 | Taylor Harry Fritz | | - | | Yosuke Watanuki | 2 | : | 0 |
| Oct 08 • 09:10 | Frances Tiafoe | | - | | Roman Safiullin | 1 | : | 2 |
| Oct 08 • 09:10 | Jiří Lehečka | | - | | Holger Rune | 0 | : | 2 |
| Oct 08 • 10:30 | David Goffin | | - | | Marcos Giron | 2 | : | 1 |
| Oct 08 • 12:30 | Flavio Cobolli | | - | | Novak Djokovic | 0 | : | 2 |
| Oct 08 • 13:50 | Tallon Griekspoor | | - | | Alexander Zverev | 1 | : | 2 |
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| Oct 09 • 06:30 | Jannik Sinner | | - | | Ben Shelton | 2 | : | 0 |
| Oct 09 • 07:00 | Stefanos Tsitsipas | | - | | Daniil Medvedev | 0 | : | 2 |
| Oct 09 • 07:50 | Carlos Alcaraz | | - | | Gaël Monfils | 2 | : | 0 |
| Oct 09 • 08:20 | Tommy Paul | | - | | Tomáš Macháč | 1 | : | 2 |
| Oct 09 • 10:40 | Jakub Mensik | | - | | Grigor Dimitrov | 2 | : | 1 |
| Oct 09 • 12:30 | Roman Safiullin | | - | | Novak Djokovic | 0 | : | 2 |
| Oct 09 • 12:30 | Taylor Harry Fritz | | - | | Holger Rune | 2 | : | 0 |
| Oct 09 • 13:50 | David Goffin | | - | | Alexander Zverev | 2 | : | 0 |
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| Oct 10 • 09:00 | Jannik Sinner | | - | | Daniil Medvedev | 2 | : | 0 |
| Oct 10 • 12:30 | Carlos Alcaraz | | - | | Tomáš Macháč | 0 | : | 2 |
| Oct 11 • 09:00 | Taylor Harry Fritz | | - | | David Goffin | 2 | : | 0 |
| Oct 11 • 12:30 | Jakub Mensik | | - | | Novak Djokovic | 1 | : | 2 |
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| Oct 12 • 10:30 | Jannik Sinner | | - | | Tomáš Macháč | 2 | : | 0 |
| Oct 12 • 13:00 | Novak Djokovic | | - | | Taylor Harry Fritz | 2 | : | 0 |
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| Oct 13 • 10:30 | Jannik Sinner | | - | | Novak Djokovic | 2 | : | 0 |
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