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| Oct 21 • 14:00 | Ugo Humbert |  | - |  | Jérôme Kym | 2 | : | 1 |
| Oct 21 • 15:55 | David Goffin |  | - |  | Matteo Arnaldi | 2 | : | 1 |
| Oct 21 • 16:40 | Daniel Altmaier |  | - | | Arthur Fils | 0 | : | 2 |
| Oct 21 • 17:00 | James Duckworth |  | - | | Giovanni Mpetshi Perricard | 0 | : | 2 |
| Oct 21 • 20:00 | Andrey Rublev |  | - |  | Nuno Borges | 2 | : | 0 |
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| Oct 22 • 13:20 | Denis Shapovalov |  | - |  | Shang Juncheng | 2 | : | 0 |
| Oct 22 • 14:00 | Dominic Stricker | | - |  | Tallon Griekspoor | 2 | : | 0 |
| Oct 22 • 15:15 | Botic van de Zandschulp | | - |  | Alexander Bublik | 1 | : | 1 |
| Oct 22 • 15:20 | Tomás Martín Etcheverry |  | - |  | Ben Shelton | 0 | : | 2 |
| Oct 22 • 16:45 | Marin Čilić |  | - |  | Alejandro Tabilo | 0 | : | 2 |
| Oct 22 • 18:00 | Nicolás Jarry | | - |  | Holger Rune | 0 | : | 2 |
| Oct 22 • 19:20 | Stefanos Tsitsipas |  | - | | Francisco Cerundolo | 2 | : | 1 |
| Oct 23 • 14:00 | Felix Auger Aliassime | | - | | Sebastián Báez | 2 | : | 0 |
| Oct 23 • 15:00 | Pedro Martínez |  | - |  | Jiří Lehečka | 2 | : | 0 |
| Oct 23 • 15:30 | Roberto Bautista-Agut | | - |  | Casper Ruud | 2 | : | 1 |
| Oct 23 • 18:10 | Adrian Mannarino | | - | | Stanislas Wawrinka | 1 | : | 2 |
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| Oct 23 • 16:30 | Ugo Humbert | | - | | David Goffin | 1 | : | 2 |
| Oct 23 • 19:40 | Andrey Rublev | | - | | Alejandro Tabilo | 2 | : | 0 |
| Oct 24 • 14:00 | Stefanos Tsitsipas | | - | | Botic van de Zandschulp | 2 | : | 0 |
| Oct 24 • 14:40 | Pedro Martínez | | - | | Arthur Fils | 0 | : | 2 |
| Oct 24 • 16:00 | Stanislas Wawrinka | | - | | Ben Shelton | 0 | : | 2 |
| Oct 24 • 16:00 | Denis Shapovalov | | - | | Roberto Bautista-Agut | 2 | : | 0 |
| Oct 24 • 18:00 | Dominic Stricker | | - | | Holger Rune | 0 | : | 2 |
| Oct 24 • 19:20 | Felix Auger Aliassime | | - | | Giovanni Mpetshi Perricard | 0 | : | 2 |
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| Oct 25 • 14:00 | Stefanos Tsitsipas | | - | | Arthur Fils | 0 | : | 2 |
| Oct 25 • 15:30 | Andrey Rublev | | - | | Ben Shelton | 1 | : | 2 |
| Oct 25 • 18:00 | David Goffin | | - | | Holger Rune | 0 | : | 2 |
| Oct 25 • 19:00 | Giovanni Mpetshi Perricard | | - | | Denis Shapovalov | 2 | : | 1 |
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| Oct 26 • 15:00 | Ben Shelton | | - | | Arthur Fils | 2 | : | 0 |
| Oct 26 • 17:00 | Holger Rune | | - | | Giovanni Mpetshi Perricard | 0 | : | 2 |
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| Oct 27 • 15:30 | Ben Shelton | | - | | Giovanni Mpetshi Perricard | 0 | : | 2 |
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