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| Oct 21 • 14:00 | Flavio Cobolli |  | - |  | Alejandro Davidovich Fokina | 2 | : | 0 |
| Oct 21 • 15:20 | Márton Fucsovics |  | - | | Matteo Berrettini | 0 | : | 2 |
| Oct 21 • 18:00 | Alexander Zverev |  | - |  | Joel Schwärzler | 2 | : | 0 |
| Oct 21 • 19:40 | Alexei Popyrin |  | - |  | Jakub Mensik | 0 | : | 2 |
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| Oct 22 • 12:00 | Miomir Kecmanovic |  | - |  | Mariano Navone | 2 | : | 0 |
| Oct 22 • 14:00 | Alex Michelsen |  | - | | Marcos Giron | 0 | : | 2 |
| Oct 22 • 14:00 | Jan-Lennard Struff | | - | | Alex De Minaur | 1 | : | 2 |
| Oct 22 • 15:20 | Quentin Halys |  | - | | Gaël Monfils | 0 | : | 2 |
| Oct 22 • 15:20 | Frances Tiafoe | | - |  | Cameron Norrie | 2 | : | 0 |
| Oct 22 • 17:40 | Lorenzo Sonego | | - | | Lorenzo Musetti | 0 | : | 2 |
| Oct 22 • 18:00 | Dominic Thiem | | - | | Luciano Darderi | 0 | : | 2 |
| Oct 22 • 19:30 | Kei Nishikori |  | - | | Jack Draper | 0 | : | 2 |
| Oct 23 • 14:00 | Grigor Dimitrov |  | - |  | Zhang Zhizhen | 2 | : | 0 |
| Oct 23 • 14:00 | Tomáš Macháč | | - | | Fábián Marozsán | 2 | : | 0 |
| Oct 23 • 15:30 | Karen Khachanov |  | - |  | Thiago Seyboth Wild | 2 | : | 0 |
| Oct 23 • 15:30 | Brandon Nakashima | | - | | Tommy Paul | 2 | : | 0 |
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| Oct 23 • 18:00 | Alexander Zverev | | - | | Marcos Giron | 2 | : | 0 |
| Oct 23 • 19:20 | Frances Tiafoe | | - | | Matteo Berrettini | 1 | : | 2 |
| Oct 24 • 12:00 | Gaël Monfils | | - | | Lorenzo Musetti | 0 | : | 0 |
| Oct 24 • 12:00 | Jakub Mensik | | - | | Miomir Kecmanovic | 2 | : | 0 |
| Oct 24 • 13:30 | Luciano Darderi | | - | | Jack Draper | 0 | : | 2 |
| Oct 24 • 14:50 | Grigor Dimitrov | | - | | Tomáš Macháč | 1 | : | 2 |
| Oct 24 • 18:00 | Flavio Cobolli | | - | | Alex De Minaur | 0 | : | 1 |
| Oct 24 • 19:20 | Karen Khachanov | | - | | Brandon Nakashima | 2 | : | 1 |
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| Oct 25 • 14:00 | Tomáš Macháč | | - | | Jack Draper | 1 | : | 2 |
| Oct 25 • 15:30 | Alexander Zverev | | - | | Lorenzo Musetti | 1 | : | 2 |
| Oct 25 • 18:00 | Matteo Berrettini | | - | | Karen Khachanov | 0 | : | 2 |
| Oct 25 • 19:30 | Jakub Mensik | | - | | Alex De Minaur | 1 | : | 2 |
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| Oct 26 • 15:00 | Lorenzo Musetti | | - | | Jack Draper | 0 | : | 2 |
| Oct 26 • 16:20 | Karen Khachanov | | - | | Alex De Minaur | 2 | : | 0 |
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| Oct 27 • 14:00 | Jack Draper | | - | | Karen Khachanov | 2 | : | 0 |
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