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| Jun 25 • 12:30 | Petra Martic |  | - |  | Sabine Lisicki | 0 | : | 2 |
| Jun 25 • 12:30 | Agnieszka Radwanska |  | - |  | Magdaléna Rybáriková | 2 | : | 0 |
| Jun 25 • 12:30 | Tamarine Tanasugarn |  | - |  | Anna Tatishvili | 0 | : | 2 |
| Jun 25 • 12:30 | Camila Giorgi |  | - | | Flavia Pennetta | 2 | : | 0 |
| Jun 25 • 12:30 | Li Na |  | - |  | Ksenia Pervak | 2 | : | 0 |
| Jun 25 • 12:30 | Sorana Cirstea |  | - |  | Pauline Parmentier | 2 | : | 0 |
| Jun 25 • 12:30 | Jarmila Gajdosova |  | - |  | Ayumi Morita | 0 | : | 2 |
| Jun 25 • 12:30 | Carla Suarez Navarro |  | - | | Samantha Stosur | 0 | : | 2 |
| Jun 25 • 14:20 | Su-Wei Hsieh |  | - | | Virginie Razzano | 2 | : | 0 |
| Jun 25 • 14:25 | Bojana Jovanovski |  | - |  | Eleni Daniilidou | 1 | : | 1 |
| Jun 25 • 14:35 | Venus Williams | | - | | Elena Vesnina | 0 | : | 2 |
| Jun 25 • 14:45 | Arantxa Rus |  | - | | Misaki Doi | 2 | : | 0 |
| Jun 25 • 15:00 | Kai-Chen Chang | | - |  | Andrea Hlavackova | 0 | : | 2 |
| Jun 25 • 15:05 | Stéphanie Foretz | | - | | Monica Niculescu | 2 | : | 1 |
| Jun 25 • 15:30 | Vesna Dolonc | | - |  | Tsvetana Pironkova | 1 | : | 2 |
| Jun 25 • 16:05 | Maria Sharapova | | - | | Anastasia Rodionova | 2 | : | 0 |
| Jun 25 • 16:10 | Tímea Babos |  | - | | Melanie Oudin | 2 | : | 1 |
| Jun 25 • 16:15 | Shuai Peng | | - | | Sandra Zaniewska | 2 | : | 1 |
| Jun 25 • 17:10 | Lucie Hradecka | | - | | Angelique Kerber | 0 | : | 2 |
| Jun 25 • 17:15 | Sloane Stephens | | - | | Karolina Pliskova | 2 | : | 0 |
| Jun 25 • 17:30 | Petra Cetkovska | | - | | Vania King | 2 | : | 0 |
| Jun 25 • 18:00 | Edina Gallovits-Hall | | - | | Silvia Soler-Espinosa | 1 | : | 2 |
| Jun 25 • 18:00 | Ekaterina Makarova | | - | | Alberta Brianti | 2 | : | 1 |
| Jun 25 • 18:30 | Nadia Petrova | | - | | Maria Elena Camerin | 2 | : | 0 |
| Jun 25 • 18:35 | Kim Clijsters |  | - | | Jelena Jankovic | 2 | : | 0 |
| Jun 25 • 18:50 | Naomi Broady |  | - | | Lourdes Dominguez Lino | 0 | : | 2 |
| Jun 25 • 19:15 | Christina McHale | | - | | Johanna Konta | 2 | : | 1 |
| Jun 25 • 20:10 | Alexandra Cadanțu-Ignatik | | - | | Maria Kirilenko | 0 | : | 2 |
| Jun 25 • 20:15 | Vera Zvonareva | | - | | Mona Barthel | 2 | : | 1 |
| Jun 25 • 20:15 | Jamie Hampton | | - | | Daniela Hantuchova | 2 | : | 0 |
| Jun 25 • 20:25 | Iveta Benesova | | - | | Heather Watson | 0 | : | 2 |
| Jun 25 • 20:30 | Lesia Tsurenko |  | - | | Mathilde Johansson | 1 | : | 2 |
| Jun 26 • 12:30 | Vera Dushevina | | - |  | Aleksandra Wozniak | 0 | : | 2 |
| Jun 26 • 12:30 | Stephanie Dubois | | - | | Jie Zheng | 1 | : | 2 |
| Jun 26 • 12:30 | Lucie Šafářová | | - | | Kiki Bertens | 0 | : | 2 |
| Jun 26 • 12:30 | Chanelle Scheepers |  | - |  | Yaroslava Shvedova | 0 | : | 2 |
| Jun 26 • 12:30 | Laura Robson | | - | | Francesca Schiavone | 1 | : | 2 |
| Jun 26 • 14:10 | Akgul Amanmuradova |  | - | | Petra Kvitova | 0 | : | 2 |
| Jun 26 • 14:15 | Anastasia Pavlyuchenkova | | - |  | Sofia Arvidsson | 2 | : | 0 |
| Jun 26 • 14:35 | Mirjana Lučić-Baroni | | - | | Alexandra Panova | 2 | : | 1 |
| Jun 26 • 14:45 | Polona Hercog |  | - | | Kristyna Pliskova | 0 | : | 2 |
| Jun 26 • 16:20 | Serena Williams | | - | | Barbora Strýcová | 2 | : | 0 |
| Jun 26 • 16:20 | Casey Dellacqua | | - | | Marion Bartoli | 0 | : | 2 |
| Jun 26 • 16:30 | Irina-Camelia Begu | | - |  | Romina Oprandi | 0 | : | 2 |
| Jun 26 • 17:00 | Patricia Mayr-Achleiter |  | - | | Varvara Lepchenko | 0 | : | 2 |
| Jun 26 • 17:00 | Elena Baltacha | | - | | Karin Knapp | 2 | : | 1 |
| Jun 26 • 17:30 | A Medina Garrigues | | - | | Simona Halep | 2 | : | 1 |
| Jun 26 • 18:00 | Jana Čepelová | | - | | Kristina Mladenovic | 2 | : | 1 |
| Jun 26 • 18:00 | Irina Falconi | | - |  | Victoria Azarenka | 0 | : | 2 |
| Jun 26 • 18:40 | Johanna Larsson | | - | | Melinda Czink | 0 | : | 2 |
| Jun 26 • 19:05 | Greta Arn | | - | | Galina Voskoboeva | 0 | : | 2 |
| Jun 26 • 19:35 | Urszula Radwanska | | - |  | Marina Erakovic | 0 | : | 2 |
| Jun 26 • 19:45 | Laura Pous-Tio | | - | | Anne Keothavong | 0 | : | 2 |
| Jun 26 • 19:50 | Coco Vandeweghe | | - | | Sara Errani | 0 | : | 2 |
| Jun 26 • 19:50 | Roberta Vinci | | - | | Ashleigh Barty | 2 | : | 0 |
| Jun 26 • 20:00 | Dominika Cibulkova | | - | | Klara Koukalová | 0 | : | 2 |
| Jun 26 • 20:00 | Alize Cornet | | - | | Nina Bratchikova | 2 | : | 0 |
| Jun 26 • 20:00 | Ana Ivanovic | | - | | María José Martínez Sánchez | 2 | : | 1 |
| Jun 26 • 20:00 | Kimiko Date-Krumm | | - | | Kateryna Bondarenko | 1 | : | 2 |
| Jun 26 • 20:10 | Yanina Wickmayer | | - | | Svetlana Kuznetsova | 2 | : | 0 |
| Jun 26 • 20:40 | Shahar Pe'er |  | - | | Julia Görges | 0 | : | 2 |
| Jun 26 • 20:45 | Olga Govortsova | | - | | Annika Beck | 2 | : | 1 |
| Jun 26 • 20:45 | Anastasiya Yakimova | | - |  | Mandy Minella | 2 | : | 1 |
| Jun 26 • 20:55 | Caroline Wozniacki |  | - | | Tamira Paszek | 1 | : | 2 |
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| Jun 27 • 12:40 | Bojana Jovanovski | | - | | Sabine Lisicki | 1 | : | 2 |
| Jun 27 • 12:40 | Petra Cetkovska | | - | | Sloane Stephens | 1 | : | 2 |
| Jun 27 • 12:40 | Heather Watson | | - | | Jamie Hampton | 2 | : | 0 |
| Jun 27 • 14:00 | Arantxa Rus | | - | | Samantha Stosur | 2 | : | 1 |
| Jun 27 • 14:30 | Agnieszka Radwanska | | - | | Elena Vesnina | 2 | : | 0 |
| Jun 27 • 14:30 | Shuai Peng | | - | | Ayumi Morita | 2 | : | 0 |
| Jun 27 • 14:30 | Vera Zvonareva | | - | | Silvia Soler-Espinosa | 2 | : | 1 |
| Jun 27 • 15:10 | Su-Wei Hsieh | | - | | Stéphanie Foretz | 2 | : | 0 |
| Jun 27 • 18:30 | Lourdes Dominguez Lino | | - | | Maria Kirilenko | 0 | : | 2 |
| Jun 27 • 19:00 | Anna Tatishvili | | - | | Camila Giorgi | 0 | : | 2 |
| Jun 27 • 19:30 | Andrea Hlavackova | | - | | Kim Clijsters | 0 | : | 2 |
| Jun 27 • 19:40 | Li Na | | - | | Sorana Cirstea | 0 | : | 2 |
| Jun 27 • 20:40 | Maria Sharapova | | - | | Tsvetana Pironkova | 2 | : | 1 |
| Jun 27 • 20:40 | Nadia Petrova | | - | | Tímea Babos | 2 | : | 1 |
| Jun 28 • 12:30 | Ekaterina Makarova | | - | | Angelique Kerber | 0 | : | 2 |
| Jun 28 • 12:45 | Christina McHale | | - | | Mathilde Johansson | 2 | : | 0 |
| Jun 28 • 12:45 | Aleksandra Wozniak | | - | | Jie Zheng | 0 | : | 2 |
| Jun 28 • 12:45 | Anne Keothavong | | - | | Sara Errani | 0 | : | 2 |
| Jun 28 • 12:45 | Roberta Vinci | | - | | Marina Erakovic | 2 | : | 0 |
| Jun 28 • 14:10 | Serena Williams | | - | | Melinda Czink | 2 | : | 0 |
| Jun 28 • 14:15 | Anastasiya Yakimova | | - | | Julia Görges | 0 | : | 2 |
| Jun 28 • 14:15 | Klara Koukalová | | - | | Olga Govortsova | 2 | : | 1 |
| Jun 28 • 14:30 | Galina Voskoboeva | | - | | Yanina Wickmayer | 1 | : | 2 |
| Jun 28 • 14:40 | Kiki Bertens | | - | | Yaroslava Shvedova | 0 | : | 2 |
| Jun 28 • 15:25 | Ana Ivanovic | | - | | Kateryna Bondarenko | 2 | : | 0 |
| Jun 28 • 15:25 | Tamira Paszek | | - | | Alize Cornet | 2 | : | 0 |
| Jun 28 • 16:00 | Mirjana Lučić-Baroni | | - | | Marion Bartoli | 2 | : | 0 |
| Jun 28 • 16:05 | Kristyna Pliskova | | - | | Francesca Schiavone | 0 | : | 2 |
| Jun 28 • 17:45 | Anastasia Pavlyuchenkova | | - | | Varvara Lepchenko | 0 | : | 2 |
| Jun 28 • 18:30 | Elena Baltacha | | - | | Petra Kvitova | 0 | : | 2 |
| Jun 28 • 18:30 | Romina Oprandi | | - | | Victoria Azarenka | 0 | : | 2 |
| Jun 28 • 18:30 | A Medina Garrigues | | - | | Jana Čepelová | 1 | : | 2 |
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| Jun 29 • 14:15 | Sloane Stephens | | - | | Sabine Lisicki | 1 | : | 2 |
| Jun 29 • 15:35 | Maria Sharapova | | - | | Su-Wei Hsieh | 2 | : | 0 |
| Jun 29 • 17:05 | Christina McHale | | - | | Angelique Kerber | 0 | : | 2 |
| Jun 29 • 17:15 | Shuai Peng | | - | | Arantxa Rus | 2 | : | 0 |
| Jun 29 • 17:15 | Vera Zvonareva | | - | | Kim Clijsters | 0 | : | 1 |
| Jun 29 • 17:30 | Agnieszka Radwanska | | - | | Heather Watson | 2 | : | 0 |
| Jun 29 • 19:30 | Sorana Cirstea | | - | | Maria Kirilenko | 0 | : | 2 |
| Jun 29 • 19:50 | Nadia Petrova | | - | | Camila Giorgi | 0 | : | 2 |
| Jun 30 • 12:30 | Ana Ivanovic | | - | | Julia Görges | 2 | : | 1 |
| Jun 30 • 12:30 | Klara Koukalová | | - | | Francesca Schiavone | 0 | : | 2 |
| Jun 30 • 12:30 | Tamira Paszek | | - | | Yanina Wickmayer | 2 | : | 1 |
| Jun 30 • 14:10 | Varvara Lepchenko | | - | | Petra Kvitova | 0 | : | 2 |
| Jun 30 • 14:15 | Serena Williams | | - | | Jie Zheng | 2 | : | 1 |
| Jun 30 • 14:50 | Jana Čepelová | | - | | Victoria Azarenka | 0 | : | 2 |
| Jun 30 • 15:10 | Roberta Vinci | | - | | Mirjana Lučić-Baroni | 2 | : | 0 |
| Jun 30 • 15:30 | Yaroslava Shvedova | | - | | Sara Errani | 2 | : | 0 |
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| Jul 02 • 13:00 | Serena Williams | | - | | Yaroslava Shvedova | 2 | : | 1 |
| Jul 02 • 13:00 | Francesca Schiavone | | - | | Petra Kvitova | 1 | : | 2 |
| Jul 02 • 13:00 | Tamira Paszek | | - | | Roberta Vinci | 2 | : | 0 |
| Jul 02 • 14:00 | Maria Sharapova | | - | | Sabine Lisicki | 0 | : | 2 |
| Jul 02 • 14:40 | Maria Kirilenko | | - | | Shuai Peng | 2 | : | 1 |
| Jul 02 • 15:00 | Agnieszka Radwanska | | - | | Camila Giorgi | 2 | : | 0 |
| Jul 02 • 16:00 | Kim Clijsters | | - | | Angelique Kerber | 0 | : | 2 |
| Jul 02 • 17:30 | Ana Ivanovic | | - | | Victoria Azarenka | 0 | : | 2 |
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| Jul 03 • 15:30 | Agnieszka Radwanska | | - | | Maria Kirilenko | 2 | : | 1 |
| Jul 03 • 16:00 | Serena Williams | | - | | Petra Kvitova | 2 | : | 0 |
| Jul 03 • 17:30 | Tamira Paszek | | - | | Victoria Azarenka | 0 | : | 2 |
| Jul 03 • 18:00 | Sabine Lisicki | | - | | Angelique Kerber | 1 | : | 2 |
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| Jul 05 • 14:00 | Angelique Kerber | | - | | Agnieszka Radwanska | 0 | : | 2 |
| Jul 05 • 15:35 | Serena Williams | | - | | Victoria Azarenka | 2 | : | 0 |
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| Jul 07 • 15:05 | Agnieszka Radwanska | | - | | Serena Williams | 1 | : | 2 |
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