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| Aug 26 • 17:00 | Jan-Lennard Struff |  | - |  | Guillaume Rufin | 2 | : | 3 |
| Aug 26 • 17:00 | Aljaž Bedene |  | - |  | Dmitry Tursunov | 1 | : | 3 |
| Aug 26 • 17:00 | Feliciano López |  | - | | Florent Serra | 3 | : | 1 |
| Aug 26 • 17:00 | Albert Ramos-Viñolas | | - |  | Bernard Tomic | 2 | : | 3 |
| Aug 26 • 17:00 | Daniel Evans |  | - |  | Kei Nishikori | 3 | : | 0 |
| Aug 26 • 18:30 | Richard Gasquet | | - |  | Michael Russell | 3 | : | 0 |
| Aug 26 • 18:30 | Stéphane Robert | | - | | Albano Olivetti | 3 | : | 0 |
| Aug 26 • 18:30 | Kenny de Schepper | | - | | Bradley Klahn | 1 | : | 3 |
| Aug 26 • 18:30 | Mikhail Kukushkin |  | - |  | Andrej Martin | 3 | : | 0 |
| Aug 26 • 18:30 | Rhyne Williams | | - | | Nikolay Davydenko | 2 | : | 3 |
| Aug 26 • 19:35 | Ernests Gulbis |  | - |  | Andreas Haider-Maurer | 2 | : | 3 |
| Aug 26 • 20:25 | Pablo Cuevas |  | - |  | Janko Tipsarević | 1 | : | 2 |
| Aug 26 • 21:00 | Ryan Harrison | | - | | Rafael Nadal | 0 | : | 3 |
| Aug 26 • 21:25 | Fernando Verdasco | | - |  | Ivan Dodig | 2 | : | 3 |
| Aug 26 • 22:00 | Robin Haase |  | - |  | Frank Dancevic | 1 | : | 3 |
| Aug 26 • 22:30 | Roberto Bautista-Agut | | - |  | Thomaz Bellucci | 3 | : | 0 |
| Aug 26 • 22:45 | Andrey Kuznetsov | | - |  | Dudi Sela | 2 | : | 3 |
| Aug 26 • 23:00 | Santiago Giraldo |  | - |  | Carlos Berlocq | 2 | : | 3 |
| Aug 26 • 23:10 | Rogério Dutra da Silva | | - | | Vasek Pospisil | 3 | : | 2 |
| Aug 26 • 23:30 | Nick Kyrgios | | - | | David Ferrer | 0 | : | 3 |
| Aug 26 • 23:30 | Tommy Robredo | | - | | Marinko Matosevic | 3 | : | 1 |
| Aug 27 • 17:00 | Julien Benneteau | | - |  | Michał Przysiężny | 3 | : | 1 |
| Aug 27 • 17:00 | Pablo Andújar | | - | | Thiemo de Bakker | 3 | : | 0 |
| Aug 27 • 17:00 | Thomas Fabbiano |  | - | | Milos Raonic | 0 | : | 3 |
| Aug 27 • 17:00 | Collin Altamirano | | - | | Philipp Kohlschreiber | 0 | : | 3 |
| Aug 27 • 18:30 | Łukasz Kubot | | - |  | Jarkko Nieminen | 0 | : | 3 |
| Aug 27 • 18:30 | João Sousa |  | - |  | Grigor Dimitrov | 3 | : | 2 |
| Aug 27 • 18:30 | Sergiy Stakhovsky |  | - | | Jérémy Chardy | 2 | : | 3 |
| Aug 27 • 18:30 | Jerzy Janowicz | | - | | Máximo González | 0 | : | 3 |
| Aug 27 • 18:30 | Horacio Zeballos | | - | | Adrian Mannarino | 1 | : | 3 |
| Aug 27 • 18:30 | Albert Montañés | | - | | Édouard Roger-Vasselin | 0 | : | 3 |
| Aug 27 • 19:30 | Guido Pella | | - | | Sam Querrey | 1 | : | 3 |
| Aug 27 • 20:15 | John Isner | | - | | Filippo Volandri | 3 | : | 0 |
| Aug 27 • 20:30 | Adrian Ungur |  | - | | Gaël Monfils | 0 | : | 3 |
| Aug 27 • 20:50 | Lu Yen-Hsun |  | - | | Daniel Gimeno-Traver | 3 | : | 0 |
| Aug 27 • 21:20 | Jack Sock | | - | | Philipp Petzschner | 1 | : | 1 |
| Aug 27 • 21:25 | Denis Istomin |  | - | | Nicolás Almagro | 3 | : | 1 |
| Aug 27 • 21:30 | Roger Federer |  | - | | Grega Žemlja | 3 | : | 0 |
| Aug 27 • 21:55 | Tommy Haas | | - | | Paul-Henri Mathieu | 3 | : | 0 |
| Aug 27 • 21:55 | Paolo Lorenzi | | - |  | Tomáš Berdych | 0 | : | 3 |
| Aug 27 • 22:00 | Jiří Veselý | | - | | Denis Kudla | 1 | : | 3 |
| Aug 27 • 22:25 | Donald Young | | - | | Martin Kližan | 3 | : | 0 |
| Aug 27 • 23:10 | Florian Mayer | | - | | Juan Mónaco | 2 | : | 0 |
| Aug 28 • 00:10 | Tobias Kamke | | - | | Steve Johnson | 3 | : | 1 |
| Aug 28 • 00:25 | Benjamin Becker | | - | | Lukáš Rosol | 3 | : | 1 |
| Aug 28 • 01:00 | Novak Djokovic | | - |  | Ričardas Berankis | 3 | : | 0 |
| Aug 28 • 17:00 | David Goffin |  | - | | Alexandr Dolgopolov | 0 | : | 3 |
| Aug 28 • 17:00 | Nicolas Mahut | | - | | Mikhail Youzhny | 0 | : | 3 |
| Aug 28 • 17:00 | Lukáš Lacko | | - |  | Somdev Devvarman | 2 | : | 3 |
| Aug 28 • 17:00 | Marcos Baghdatis |  | - | | Go Soeda | 3 | : | 0 |
| Aug 28 • 17:00 | Daniel Brands | | - |  | Kevin Anderson | 1 | : | 3 |
| Aug 28 • 18:30 | Andreas Seppi | | - | | Xavier Malisse | 3 | : | 1 |
| Aug 28 • 18:40 | Tim Smyczek | | - | | James Duckworth | 3 | : | 1 |
| Aug 28 • 19:05 | Guillermo García López | | - | | Juan Martín del Potro | 1 | : | 3 |
| Aug 29 • 00:30 | Lleyton Hewitt | | - | | Brian Baker | 3 | : | 1 |
| Aug 29 • 00:30 | Victor Hănescu | | - | | Leonardo Mayer | 1 | : | 3 |
| Aug 29 • 01:00 | Igor Sijsling | | - | | Peter Gojowczyk | 1 | : | 3 |
| Aug 29 • 01:20 | Jurgen Zopp |  | - | | Marcel Granollers | 2 | : | 3 |
| Aug 29 • 01:20 | Jürgen Melzer | | - | | Evgeny Donskoy | 0 | : | 3 |
| Aug 29 • 01:30 | Benoît Paire | | - | | Alex Bogomolov Jr | 2 | : | 3 |
| Aug 29 • 01:30 | Rajeev Ram | | - | | Fabio Fognini | 3 | : | 0 |
| Aug 29 • 01:30 | Stanislas Wawrinka | | - | | Radek Štěpánek | 3 | : | 0 |
| Aug 29 • 01:30 | James Blake | | - | | Ivo Karlović | 2 | : | 3 |
| Aug 29 • 02:15 | Andy Murray | | - | | Michaël Llodra | 3 | : | 0 |
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| Aug 29 • 18:30 | Guillaume Rufin | | - | | Dmitry Tursunov | 0 | : | 1 |
| Aug 29 • 18:30 | Richard Gasquet | | - | | Stéphane Robert | 3 | : | 0 |
| Aug 29 • 18:30 | Dudi Sela | | - | | Janko Tipsarević | 0 | : | 3 |
| Aug 29 • 19:40 | Roberto Bautista-Agut | | - | | David Ferrer | 1 | : | 3 |
| Aug 29 • 20:15 | Máximo González | | - | | Jack Sock | 1 | : | 3 |
| Aug 29 • 20:30 | Bernard Tomic | | - | | Daniel Evans | 1 | : | 3 |
| Aug 29 • 20:30 | Andreas Haider-Maurer | | - | | Mikhail Kukushkin | 0 | : | 3 |
| Aug 29 • 20:50 | Roger Federer | | - | | Carlos Berlocq | 3 | : | 0 |
| Aug 29 • 21:45 | Adrian Mannarino | | - | | Sam Querrey | 3 | : | 1 |
| Aug 29 • 22:55 | Ivan Dodig | | - | | Nikolay Davydenko | 3 | : | 0 |
| Aug 29 • 23:00 | Édouard Roger-Vasselin | | - | | Philipp Kohlschreiber | 1 | : | 3 |
| Aug 29 • 23:05 | Tommy Robredo | | - | | Frank Dancevic | 3 | : | 0 |
| Aug 29 • 23:15 | Feliciano López | | - | | Bradley Klahn | 3 | : | 1 |
| Aug 30 • 01:15 | Pablo Andújar | | - | | Milos Raonic | 0 | : | 3 |
| Aug 30 • 02:00 | John Isner | | - | | Gaël Monfils | 3 | : | 1 |
| Aug 30 • 02:30 | Rogério Dutra da Silva | | - | | Rafael Nadal | 0 | : | 3 |
| Aug 30 • 17:00 | Tommy Haas | | - | | Lu Yen-Hsun | 3 | : | 0 |
| Aug 30 • 17:00 | Alexandr Dolgopolov | | - | | Mikhail Youzhny | 0 | : | 3 |
| Aug 30 • 17:00 | Marcel Granollers | | - | | Rajeev Ram | 3 | : | 2 |
| Aug 30 • 18:30 | Julien Benneteau | | - | | Jérémy Chardy | 3 | : | 0 |
| Aug 30 • 18:50 | Alex Bogomolov Jr | | - | | Tim Smyczek | 2 | : | 3 |
| Aug 30 • 19:10 | Novak Djokovic | | - | | Benjamin Becker | 3 | : | 0 |
| Aug 30 • 19:30 | Denis Kudla | | - | | Tomáš Berdych | 0 | : | 3 |
| Aug 30 • 19:50 | Jarkko Nieminen | | - | | João Sousa | 2 | : | 3 |
| Aug 30 • 20:35 | Tobias Kamke | | - | | Denis Istomin | 0 | : | 3 |
| Aug 30 • 20:45 | Andreas Seppi | | - | | Somdev Devvarman | 3 | : | 0 |
| Aug 30 • 21:40 | Donald Young | | - | | Florian Mayer | 0 | : | 3 |
| Aug 30 • 22:30 | Evgeny Donskoy | | - | | Peter Gojowczyk | 3 | : | 2 |
| Aug 30 • 22:35 | Andy Murray | | - | | Leonardo Mayer | 3 | : | 1 |
| Aug 31 • 00:30 | Marcos Baghdatis | | - | | Kevin Anderson | 3 | : | 0 |
| Aug 31 • 00:30 | Stanislas Wawrinka | | - | | Ivo Karlović | 3 | : | 0 |
| Aug 31 • 01:00 | Lleyton Hewitt | | - | | Juan Martín del Potro | 3 | : | 2 |
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| Aug 31 • 17:00 | Mikhail Kukushkin | | - | | David Ferrer | 1 | : | 3 |
| Aug 31 • 18:30 | Feliciano López | | - | | Milos Raonic | 1 | : | 3 |
| Aug 31 • 20:00 | Ivan Dodig | | - | | Rafael Nadal | 0 | : | 3 |
| Aug 31 • 20:20 | Jack Sock | | - | | Janko Tipsarević | 1 | : | 3 |
| Aug 31 • 21:20 | John Isner | | - | | Philipp Kohlschreiber | 1 | : | 3 |
| Aug 31 • 21:45 | Richard Gasquet | | - | | Dmitry Tursunov | 2 | : | 1 |
| Aug 31 • 23:55 | Tommy Robredo | | - | | Daniel Evans | 3 | : | 1 |
| Sep 01 • 02:30 | Roger Federer | | - | | Adrian Mannarino | 3 | : | 0 |
| Sep 01 • 17:00 | Stanislas Wawrinka | | - | | Marcos Baghdatis | 3 | : | 1 |
| Sep 01 • 18:25 | Julien Benneteau | | - | | Tomáš Berdych | 0 | : | 3 |
| Sep 01 • 18:30 | Andreas Seppi | | - | | Denis Istomin | 2 | : | 3 |
| Sep 01 • 19:30 | Evgeny Donskoy | | - | | Lleyton Hewitt | 1 | : | 3 |
| Sep 01 • 19:45 | Andy Murray | | - | | Florian Mayer | 3 | : | 0 |
| Sep 01 • 21:00 | Tim Smyczek | | - | | Marcel Granollers | 2 | : | 3 |
| Sep 01 • 22:30 | Tommy Haas | | - | | Mikhail Youzhny | 1 | : | 3 |
| Sep 02 • 01:00 | Novak Djokovic | | - | | João Sousa | 3 | : | 0 |
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| Sep 02 • 18:30 | Janko Tipsarević | | - | | David Ferrer | 1 | : | 3 |
| Sep 02 • 20:00 | Roger Federer | | - | | Tommy Robredo | 0 | : | 3 |
| Sep 02 • 20:30 | Richard Gasquet | | - | | Milos Raonic | 3 | : | 2 |
| Sep 03 • 01:00 | Philipp Kohlschreiber | | - | | Rafael Nadal | 1 | : | 3 |
| Sep 03 • 18:30 | Mikhail Youzhny | | - | | Lleyton Hewitt | 3 | : | 2 |
| Sep 03 • 20:30 | Novak Djokovic | | - | | Marcel Granollers | 3 | : | 0 |
| Sep 03 • 23:00 | Stanislas Wawrinka | | - | | Tomáš Berdych | 3 | : | 1 |
| Sep 04 • 02:30 | Andy Murray | | - | | Denis Istomin | 3 | : | 1 |
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| Sep 04 • 19:30 | Richard Gasquet | | - | | David Ferrer | 3 | : | 2 |
| Sep 05 • 02:30 | Tommy Robredo | | - | | Rafael Nadal | 0 | : | 3 |
| Sep 05 • 19:30 | Andy Murray | | - | | Stanislas Wawrinka | 0 | : | 3 |
| Sep 06 • 02:00 | Novak Djokovic | | - | | Mikhail Youzhny | 3 | : | 1 |
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| Sep 07 • 18:00 | Novak Djokovic | | - | | Stanislas Wawrinka | 3 | : | 2 |
| Sep 07 • 21:15 | Richard Gasquet | | - | | Rafael Nadal | 0 | : | 3 |
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| Sep 09 • 23:00 | Novak Djokovic | | - | | Rafael Nadal | 1 | : | 3 |
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