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| Oct 06 • 08:00 | Julien Benneteau |  | - |  | Lukáš Rosol | 1 | : | 2 |
| Oct 06 • 09:30 | Dmitry Tursunov |  | - |  | Carlos Berlocq | 1 | : | 2 |
| Oct 06 • 12:00 | Di Wu |  | - |  | Florian Mayer | 0 | : | 2 |
| Oct 06 • 14:00 | Mikhail Youzhny | | - |  | Pablo Andújar | 0 | : | 0 |
| Oct 07 • 08:00 | Marcel Granollers | | - |  | Janko Tipsarević | 2 | : | 0 |
| Oct 07 • 09:30 | John Isner |  | - |  | Santiago Giraldo | 2 | : | 1 |
| Oct 07 • 12:30 | Tatsuma Ito |  | - | | Gaël Monfils | 0 | : | 2 |
| Oct 07 • 14:00 | Sam Querrey | | - | | Tommy Haas | 0 | : | 2 |
| Oct 08 • 06:00 | Philipp Kohlschreiber | | - | | Mao-Xin Gong | 2 | : | 0 |
| Oct 08 • 06:00 | Feliciano López | | - |  | Jarkko Nieminen | 2 | : | 1 |
| Oct 08 • 06:00 | Victor Hănescu |  | - |  | Kevin Anderson | 1 | : | 2 |
| Oct 08 • 08:00 | Lleyton Hewitt |  | - |  | Andreas Seppi | 0 | : | 2 |
| Oct 08 • 08:00 | Benoît Paire | | - | | Gilles Simon | 2 | : | 0 |
| Oct 08 • 08:40 | Paolo Lorenzi | | - | | Fabio Fognini | 1 | : | 2 |
| Oct 08 • 09:55 | Richard Gasquet | | - |  | Vasek Pospisil | 0 | : | 2 |
| Oct 08 • 10:25 | Albert Montañés | | - | | Tommy Robredo | 0 | : | 2 |
| Oct 08 • 10:30 | Jürgen Melzer |  | - |  | Ivan Dodig | 2 | : | 1 |
| Oct 08 • 10:30 | Alexandr Dolgopolov |  | - | | Michael Russell | 2 | : | 0 |
| Oct 08 • 11:00 | Alejandro Falla | | - | | Daniel Brands | 0 | : | 2 |
| Oct 08 • 11:00 | Jérémy Chardy | | - | | Bernard Tomic | 2 | : | 0 |
| Oct 08 • 11:30 | Nicolás Almagro | | - | | Go Soeda | 2 | : | 0 |
| Oct 08 • 12:00 | Kei Nishikori | | - |  | Grigor Dimitrov | 2 | : | 0 |
| Oct 08 • 12:30 | Ze Zhang | | - | | Fernando Verdasco | 0 | : | 2 |
| Oct 08 • 14:00 | Michał Przysiężny |  | - | | Milos Raonic | 0 | : | 2 |
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| Oct 09 • 07:00 | Fabio Fognini | | - | | Tommy Robredo | 1 | : | 0 |
| Oct 09 • 08:00 | Pablo Andújar | | - | | Jo-Wilfried Tsonga | 0 | : | 2 |
| Oct 09 • 08:00 | Juan Martín del Potro | | - | | Philipp Kohlschreiber | 2 | : | 1 |
| Oct 09 • 08:00 | John Isner | | - | | Carlos Berlocq | 0 | : | 2 |
| Oct 09 • 08:30 | Vasek Pospisil | | - | | Gaël Monfils | 0 | : | 2 |
| Oct 09 • 09:30 | Feliciano López | | - | | Tomáš Berdych | 0 | : | 2 |
| Oct 09 • 10:15 | Florian Mayer | | - | | Benoît Paire | 2 | : | 0 |
| Oct 09 • 10:30 | Novak Djokovic | | - | | Marcel Granollers | 2 | : | 0 |
| Oct 09 • 10:30 | Daniel Brands | | - | | Tommy Haas | 0 | : | 2 |
| Oct 09 • 10:40 | Kei Nishikori | | - | | Jürgen Melzer | 2 | : | 1 |
| Oct 09 • 11:00 | Stanislas Wawrinka |  | - | | Kevin Anderson | 2 | : | 1 |
| Oct 09 • 11:30 | Nicolás Almagro | | - | | Jérémy Chardy | 2 | : | 0 |
| Oct 09 • 12:00 | Andreas Seppi | | - | | Roger Federer | 0 | : | 2 |
| Oct 09 • 13:45 | David Ferrer | | - | | Lukáš Rosol | 2 | : | 0 |
| Oct 09 • 13:55 | Fernando Verdasco | | - | | Milos Raonic | 1 | : | 2 |
| Oct 09 • 14:00 | Alexandr Dolgopolov | | - | | Rafael Nadal | 0 | : | 2 |
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| Oct 10 • 08:00 | Kei Nishikori | | - | | Jo-Wilfried Tsonga | 0 | : | 2 |
| Oct 10 • 08:00 | Juan Martín del Potro | | - | | Tommy Haas | 0 | : | 0 |
| Oct 10 • 09:30 | David Ferrer | | - | | Florian Mayer | 0 | : | 2 |
| Oct 10 • 10:25 | Gaël Monfils | | - | | Roger Federer | 2 | : | 1 |
| Oct 10 • 11:30 | Nicolás Almagro | | - | | Tomáš Berdych | 2 | : | 1 |
| Oct 10 • 12:00 | Novak Djokovic | | - | | Fabio Fognini | 2 | : | 0 |
| Oct 10 • 13:40 | Stanislas Wawrinka | | - | | Milos Raonic | 2 | : | 0 |
| Oct 10 • 14:10 | Carlos Berlocq | | - | | Rafael Nadal | 0 | : | 2 |
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| Oct 11 • 08:00 | Florian Mayer | | - | | Jo-Wilfried Tsonga | 0 | : | 2 |
| Oct 11 • 09:30 | Juan Martín del Potro | | - | | Nicolás Almagro | 2 | : | 0 |
| Oct 11 • 12:00 | Novak Djokovic | | - | | Gaël Monfils | 2 | : | 1 |
| Oct 11 • 14:00 | Stanislas Wawrinka | | - | | Rafael Nadal | 0 | : | 2 |
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| Oct 12 • 10:30 | Novak Djokovic | | - | | Jo-Wilfried Tsonga | 2 | : | 0 |
| Oct 12 • 14:00 | Juan Martín del Potro | | - | | Rafael Nadal | 2 | : | 0 |
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| Oct 13 • 10:30 | Novak Djokovic | | - | | Juan Martín del Potro | 2 | : | 1 |
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