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| Mar 06 • 20:00 | Tim Smyczek |  | - | | Jack Sock | 2 | : | 1 |
| Mar 06 • 20:00 | Sergiy Stakhovsky |  | - |  | Łukasz Kubot | 2 | : | 0 |
| Mar 06 • 20:00 | Benjamin Becker |  | - |  | Édouard Roger-Vasselin | 0 | : | 2 |
| Mar 06 • 20:00 | Alejandro Falla |  | - |  | Federico Delbonis | 2 | : | 0 |
| Mar 06 • 21:45 | Michael Russell | | - | | Donald Young | 2 | : | 1 |
| Mar 06 • 21:55 | Radek Štěpánek |  | - |  | Denis Istomin | 2 | : | 1 |
| Mar 06 • 22:10 | Jiří Veselý | | - |  | Igor Sijsling | 2 | : | 1 |
| Mar 06 • 23:30 | Dušan Lajović |  | - | | Lukáš Rosol | 1 | : | 2 |
| Mar 07 • 00:05 | Daniel Gimeno-Traver |  | - | | Santiago Giraldo | 1 | : | 2 |
| Mar 07 • 00:20 | Juan Mónaco | | - |  | Peter Polansky | 2 | : | 1 |
| Mar 07 • 01:15 | Lleyton Hewitt |  | - | | Matthew Ebden | 2 | : | 1 |
| Mar 07 • 02:00 | Andrey Golubev |  | - | | Ryan Harrison | 0 | : | 2 |
| Mar 07 • 02:00 | Ivo Karlović |  | - |  | Alex Bogomolov Jr | 2 | : | 0 |
| Mar 07 • 02:00 | Jérémy Chardy | | - | | Rhyne Williams | 2 | : | 0 |
| Mar 07 • 02:00 | Robby Ginepri | | - | | Paul-Henri Mathieu | 0 | : | 2 |
| Mar 07 • 05:30 | Alex Kuznetsov | | - | | Sam Querrey | 0 | : | 2 |
| Mar 07 • 20:00 | Tobias Kamke | | - |  | Lu Yen-Hsun | 0 | : | 2 |
| Mar 07 • 20:00 | Mikhail Kukushkin | | - | | Samuel Groth | 2 | : | 1 |
| Mar 07 • 20:10 | Aleksandr Nedovyesov | | - |  | João Sousa | 0 | : | 2 |
| Mar 07 • 20:15 | Nicolas Mahut | | - | | Teymuraz Gabashvili | 0 | : | 2 |
| Mar 07 • 20:15 | Julien Benneteau | | - | | Daniel Muñoz de la Nava | 2 | : | 1 |
| Mar 07 • 21:50 | Bradley Klahn | | - | | Marinko Matosevic | 0 | : | 2 |
| Mar 07 • 21:50 | Alejandro González | | - | | Adrian Mannarino | 2 | : | 1 |
| Mar 07 • 22:50 | Victor Hănescu |  | - | | Stéphane Robert | 2 | : | 1 |
| Mar 07 • 23:45 | Roberto Bautista-Agut | | - | | Steve Johnson | 2 | : | 0 |
| Mar 08 • 00:00 | Horacio Zeballos | | - | | Rajeev Ram | 2 | : | 0 |
| Mar 08 • 01:00 | Feliciano López | | - |  | Dudi Sela | 2 | : | 0 |
| Mar 08 • 01:00 | Pablo Carreño Busta | | - |  | Paolo Lorenzi | 1 | : | 2 |
| Mar 08 • 02:00 | Robin Haase | | - | | John-Patrick Smith | 2 | : | 0 |
| Mar 08 • 02:00 | Dominic Thiem |  | - | | Daniel Kosakowski | 2 | : | 0 |
| Mar 08 • 03:30 | Michał Przysiężny | | - | | Nikolay Davydenko | 1 | : | 1 |
| Mar 08 • 03:30 | Daniel Brands | | - |  | Jarkko Nieminen | 1 | : | 2 |
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| Mar 08 • 20:00 | Alejandro Falla | | - | | Jerzy Janowicz | 2 | : | 1 |
| Mar 08 • 20:00 | Tommy Haas | | - | | Jérémy Chardy | 2 | : | 0 |
| Mar 08 • 20:15 | Michael Russell | | - | | Mikhail Youzhny | 0 | : | 0 |
| Mar 08 • 21:30 | Lukáš Rosol | | - |  | Andy Murray | 1 | : | 2 |
| Mar 08 • 21:30 | Sam Querrey | | - | | Andreas Seppi | 1 | : | 2 |
| Mar 08 • 21:30 | Kevin Anderson |  | - | | Lleyton Hewitt | 2 | : | 0 |
| Mar 08 • 23:35 | Tim Smyczek | | - | | Alexandr Dolgopolov | 0 | : | 2 |
| Mar 08 • 23:35 | Dmitry Tursunov | | - | | Juan Mónaco | 2 | : | 0 |
| Mar 08 • 23:45 | Pablo Andújar | | - | | Jiří Veselý | 1 | : | 2 |
| Mar 09 • 00:00 | Milos Raonic | | - | | Édouard Roger-Vasselin | 2 | : | 1 |
| Mar 09 • 00:10 | Paul-Henri Mathieu | | - |  | Roger Federer | 0 | : | 2 |
| Mar 09 • 01:30 | Ryan Harrison | | - | | Fabio Fognini | 1 | : | 2 |
| Mar 09 • 01:30 | Stanislas Wawrinka | | - | | Ivo Karlović | 2 | : | 0 |
| Mar 09 • 02:00 | Gaël Monfils | | - | | Sergiy Stakhovsky | 2 | : | 0 |
| Mar 09 • 02:00 | Santiago Giraldo | | - |  | Kei Nishikori | 0 | : | 2 |
| Mar 09 • 04:00 | Rafael Nadal | | - | | Radek Štěpánek | 2 | : | 1 |
| Mar 09 • 19:00 | Roberto Bautista-Agut | | - | | Tomáš Berdych | 2 | : | 1 |
| Mar 09 • 19:00 | Paolo Lorenzi | | - | | Marin Čilić | 0 | : | 2 |
| Mar 09 • 20:00 | Ivan Dodig | | - | | Alejandro González | 1 | : | 2 |
| Mar 09 • 20:00 | Mikhail Kukushkin | | - | | Vasek Pospisil | 2 | : | 0 |
| Mar 09 • 20:45 | Philipp Kohlschreiber | | - | | Lu Yen-Hsun | 0 | : | 2 |
| Mar 09 • 21:15 | Nikolay Davydenko | | - | | John Isner | 0 | : | 2 |
| Mar 09 • 22:00 | Juan Martín del Potro | | - | | Feliciano López | 0 | : | 0 |
| Mar 09 • 22:45 | Gilles Simon | | - | | Dominic Thiem | 0 | : | 2 |
| Mar 09 • 22:45 | Tommy Robredo | | - | | Marinko Matosevic | 2 | : | 1 |
| Mar 09 • 23:45 | Richard Gasquet | | - | | Teymuraz Gabashvili | 1 | : | 0 |
| Mar 09 • 23:45 | João Sousa | | - |  | Ernests Gulbis | 0 | : | 2 |
| Mar 10 • 01:15 | Fernando Verdasco | | - | | Horacio Zeballos | 2 | : | 0 |
| Mar 10 • 02:15 | Julien Benneteau | | - | | Jo-Wilfried Tsonga | 2 | : | 0 |
| Mar 10 • 02:45 | Grigor Dimitrov |  | - | | Robin Haase | 2 | : | 0 |
| Mar 10 • 02:45 | Florian Mayer | | - | | Jarkko Nieminen | 0 | : | 1 |
| Mar 10 • 03:45 | Victor Hănescu | | - | | Novak Djokovic | 0 | : | 2 |
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| Mar 10 • 19:00 | Jiří Veselý | | - | | Andy Murray | 1 | : | 2 |
| Mar 10 • 20:30 | Gaël Monfils | | - | | Fabio Fognini | 1 | : | 2 |
| Mar 10 • 20:30 | Dmitry Tursunov | | - | | Roger Federer | 0 | : | 2 |
| Mar 10 • 23:45 | Milos Raonic | | - | | Alejandro Falla | 2 | : | 0 |
| Mar 11 • 00:15 | Stanislas Wawrinka | | - | | Andreas Seppi | 2 | : | 0 |
| Mar 11 • 00:30 | Rafael Nadal | | - | | Alexandr Dolgopolov | 1 | : | 2 |
| Mar 11 • 01:00 | Kevin Anderson | | - | | Evgeny Donskoy | 2 | : | 1 |
| Mar 11 • 04:30 | Tommy Haas | | - | | Kei Nishikori | 2 | : | 0 |
| Mar 11 • 19:00 | Jarkko Nieminen | | - | | Roberto Bautista-Agut | 1 | : | 2 |
| Mar 11 • 19:00 | Tommy Robredo | | - | | Marin Čilić | 0 | : | 2 |
| Mar 11 • 21:00 | Feliciano López | | - | | Mikhail Kukushkin | 2 | : | 1 |
| Mar 11 • 21:00 | Richard Gasquet | | - | | Fernando Verdasco | 0 | : | 2 |
| Mar 11 • 22:15 | Alejandro González | | - | | Novak Djokovic | 1 | : | 2 |
| Mar 11 • 23:00 | Grigor Dimitrov | | - | | Ernests Gulbis | 1 | : | 2 |
| Mar 12 • 00:00 | Dominic Thiem | | - | | Julien Benneteau | 0 | : | 2 |
| Mar 12 • 03:00 | Lu Yen-Hsun | | - | | John Isner | 0 | : | 2 |
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| Mar 12 • 19:00 | Alexandr Dolgopolov | | - | | Fabio Fognini | 2 | : | 0 |
| Mar 12 • 19:00 | Milos Raonic | | - | | Andy Murray | 2 | : | 1 |
| Mar 12 • 20:30 | Ernests Gulbis | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| Mar 12 • 22:00 | Fernando Verdasco | | - | | John Isner | 1 | : | 2 |
| Mar 12 • 22:30 | Stanislas Wawrinka | | - | | Kevin Anderson | 1 | : | 2 |
| Mar 12 • 23:30 | Feliciano López | | - | | Julien Benneteau | 0 | : | 2 |
| Mar 13 • 00:00 | Tommy Haas | | - | | Roger Federer | 0 | : | 2 |
| Mar 13 • 04:30 | Marin Čilić | | - | | Novak Djokovic | 1 | : | 2 |
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| Mar 13 • 21:00 | Alexandr Dolgopolov | | - | | Milos Raonic | 2 | : | 0 |
| Mar 14 • 03:00 | Kevin Anderson | | - | | Roger Federer | 0 | : | 2 |
| Mar 14 • 21:30 | Julien Benneteau | | - | | Novak Djokovic | 0 | : | 2 |
| Mar 14 • 23:30 | John Isner | | - | | Ernests Gulbis | 2 | : | 0 |
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| Mar 15 • 20:00 | Alexandr Dolgopolov | | - | | Roger Federer | 0 | : | 2 |
| Mar 15 • 21:30 | John Isner | | - | | Novak Djokovic | 1 | : | 2 |
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| Mar 16 • 22:00 | Roger Federer | | - | | Novak Djokovic | 1 | : | 2 |
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