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| Oct 05 • 08:00 | Tommy Robredo |  | - |  | Mikhail Kukushkin | 1 | : | 2 |
| Oct 05 • 10:15 | Lukáš Rosol |  | - |  | Dominic Thiem | 0 | : | 2 |
| Oct 05 • 12:30 | Alexandr Dolgopolov |  | - | | Roberto Bautista-Agut | 0 | : | 2 |
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| Oct 06 • 07:00 | Donald Young |  | - |  | Malek Jaziri | 0 | : | 2 |
| Oct 06 • 07:00 | João Sousa |  | - |  | Juan Mónaco | 0 | : | 2 |
| Oct 06 • 07:00 | John Isner | | - | | Pablo Andújar | 2 | : | 1 |
| Oct 06 • 08:30 | Marcel Granollers | | - |  | Lu Yen-Hsun | 1 | : | 2 |
| Oct 06 • 08:30 | Ivo Karlović |  | - | | Marin Čilić | 2 | : | 1 |
| Oct 06 • 10:40 | James Ward |  | - |  | Kevin Anderson | 1 | : | 2 |
| Oct 06 • 12:30 | Jack Sock | | - |  | Bernard Tomic | 2 | : | 1 |
| Oct 06 • 12:30 | Jérémy Chardy |  | - | | Richard Gasquet | 0 | : | 2 |
| Oct 06 • 14:00 | Grigor Dimitrov |  | - |  | Denis Istomin | 2 | : | 0 |
| Oct 07 • 07:00 | Julien Benneteau | | - |  | Ze Zhang | 2 | : | 1 |
| Oct 07 • 07:00 | Gilles Simon | | - | | Guillermo García López | 2 | : | 1 |
| Oct 07 • 07:00 | Mikhail Youzhny |  | - |  | Ernests Gulbis | 2 | : | 0 |
| Oct 07 • 07:00 | Steve Johnson | | - | | Andrey Golubev | 2 | : | 1 |
| Oct 07 • 07:00 | Thanasi Kokkinakis | | - | | Feliciano López | 1 | : | 2 |
| Oct 07 • 08:30 | Samuel Groth | | - |  | Martin Kližan | 0 | : | 2 |
| Oct 07 • 08:30 | Vasek Pospisil |  | - |  | Santiago Giraldo | 2 | : | 1 |
| Oct 07 • 09:20 | Fabio Fognini |  | - | | Wang Chuhan | 0 | : | 2 |
| Oct 07 • 09:45 | Pablo Cuevas |  | - | | Ivan Dodig | 0 | : | 2 |
| Oct 07 • 10:00 | Édouard Roger-Vasselin | | - |  | Jerzy Janowicz | 1 | : | 2 |
| Oct 07 • 12:40 | Andy Murray | | - | | Teymuraz Gabashvili | 2 | : | 0 |
| Oct 07 • 14:00 | Leonardo Mayer | | - | | Wu Di | 2 | : | 0 |
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| Oct 07 • 09:45 | Lu Yen-Hsun | | - | | Ivo Karlović | 0 | : | 2 |
| Oct 07 • 12:45 | Mikhail Kukushkin | | - | | Kevin Anderson | 2 | : | 0 |
| Oct 08 • 07:00 | Martin Kližan | | - | | David Ferrer | 1 | : | 2 |
| Oct 08 • 07:00 | Wang Chuhan | | - | | Malek Jaziri | 0 | : | 2 |
| Oct 08 • 07:00 | Gilles Simon | | - |  | Stanislas Wawrinka | 2 | : | 1 |
| Oct 08 • 08:30 | Vasek Pospisil | | - | | Roberto Bautista-Agut | 1 | : | 2 |
| Oct 08 • 08:30 | Jack Sock | | - |  | Kei Nishikori | 2 | : | 0 |
| Oct 08 • 08:30 | Ivan Dodig | | - | | Mikhail Youzhny | 1 | : | 2 |
| Oct 08 • 09:00 | Andy Murray | | - | | Jerzy Janowicz | 2 | : | 0 |
| Oct 08 • 09:10 | Grigor Dimitrov | | - | | Julien Benneteau | 0 | : | 2 |
| Oct 08 • 11:30 | Novak Djokovic |  | - | | Dominic Thiem | 2 | : | 0 |
| Oct 08 • 11:45 | Tomáš Berdych | | - | | Richard Gasquet | 2 | : | 0 |
| Oct 08 • 12:30 | John Isner | | - | | Steve Johnson | 2 | : | 0 |
| Oct 08 • 13:20 | Milos Raonic | | - | | Juan Mónaco | 0 | : | 0 |
| Oct 08 • 13:30 | Feliciano López | | - | | Rafael Nadal | 2 | : | 0 |
| Oct 08 • 15:00 | Roger Federer | | - | | Leonardo Mayer | 2 | : | 1 |
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| Oct 09 • 07:00 | Tomáš Berdych | | - | | Ivo Karlović | 2 | : | 0 |
| Oct 09 • 07:00 | Malek Jaziri | | - | | Gilles Simon | 0 | : | 2 |
| Oct 09 • 08:30 | Andy Murray | | - | | David Ferrer | 1 | : | 2 |
| Oct 09 • 09:00 | Julien Benneteau | | - | | Jack Sock | 2 | : | 0 |
| Oct 09 • 10:30 | Juan Mónaco | | - | | Mikhail Youzhny | 1 | : | 2 |
| Oct 09 • 12:30 | Novak Djokovic | | - | | Mikhail Kukushkin | 2 | : | 1 |
| Oct 09 • 12:30 | John Isner | | - | | Feliciano López | 0 | : | 2 |
| Oct 09 • 14:00 | Roger Federer | | - | | Roberto Bautista-Agut | 2 | : | 0 |
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| Oct 10 • 07:00 | Tomáš Berdych | | - | | Gilles Simon | 1 | : | 2 |
| Oct 10 • 09:00 | Mikhail Youzhny | | - | | Feliciano López | 1 | : | 2 |
| Oct 10 • 12:30 | Novak Djokovic | | - | | David Ferrer | 2 | : | 0 |
| Oct 10 • 14:00 | Roger Federer | | - | | Julien Benneteau | 2 | : | 0 |
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| Oct 11 • 10:30 | Gilles Simon | | - | | Feliciano López | 2 | : | 0 |
| Oct 11 • 14:00 | Novak Djokovic | | - | | Roger Federer | 0 | : | 2 |
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| Oct 12 • 10:30 | Roger Federer | | - | | Gilles Simon | 2 | : | 0 |
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