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| Oct 11 • 09:00 | Alexandr Dolgopolov |  | - |  | Borna Ćorić | 1 | : | 2 |
| Oct 11 • 12:30 | Fernando Verdasco |  | - |  | Bernard Tomic | 0 | : | 2 |
| Oct 12 • 07:30 | Martin Kližan |  | - |  | Ze Zhang | 2 | : | 0 |
| Oct 12 • 07:30 | Steve Johnson |  | - |  | Andreas Seppi | 2 | : | 1 |
| Oct 12 • 07:30 | Ivo Karlović | | - |  | Jérémy Chardy | 2 | : | 0 |
| Oct 12 • 07:30 | Roberto Bautista-Agut | | - | | Guillermo García López | 2 | : | 0 |
| Oct 12 • 07:30 | Nick Kyrgios | | - |  | Andreas Haider-Maurer | 2 | : | 0 |
| Oct 12 • 09:00 | Lu Yen-Hsun |  | - | | Dominic Thiem | 0 | : | 2 |
| Oct 12 • 09:00 | Adrian Mannarino | | - | | John Isner | 0 | : | 2 |
| Oct 12 • 09:00 | Víctor Estrella Burgos |  | - | | Donald Young | 2 | : | 1 |
| Oct 12 • 09:00 | Sam Querrey | | - | | Albert Ramos-Viñolas | 1 | : | 2 |
| Oct 12 • 10:30 | Andrey Kuznetsov |  | - | | Feliciano López | 0 | : | 2 |
| Oct 12 • 12:00 | Leonardo Mayer |  | - | | Bai Yan | 2 | : | 0 |
| Oct 12 • 12:00 | Jo-Wilfried Tsonga | | - | | Tommy Robredo | 2 | : | 1 |
| Oct 12 • 14:00 | Marin Čilić | | - | | Wu Di | 2 | : | 1 |
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| Oct 13 • 07:30 | Simone Bolelli | | - |  | Vasek Pospisil | 0 | : | 2 |
| Oct 13 • 07:30 | David Goffin |  | - |  | Go Soeda | 2 | : | 0 |
| Oct 13 • 07:30 | Łukasz Kubot |  | - | | Jack Sock | 0 | : | 2 |
| Oct 13 • 07:30 | Thomaz Bellucci |  | - | | Milos Raonic | 0 | : | 2 |
| Oct 13 • 09:00 | Richard Gasquet | | - |  | Gilles Müller | 2 | : | 0 |
| Oct 13 • 09:00 | Pablo Cuevas |  | - |  | Viktor Troicki | 1 | : | 2 |
| Oct 13 • 09:00 | Tommy Haas |  | - |  | Kevin Anderson | 0 | : | 2 |
| Oct 13 • 10:30 | Fabio Fognini | | - |  | João Sousa | 2 | : | 0 |
| Oct 13 • 12:00 | Gilles Simon | | - |  | Nikoloz Basilashvili | 2 | : | 1 |
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| Oct 13 • 12:00 | Marin Čilić | | - | | Borna Ćorić | 2 | : | 0 |
| Oct 13 • 12:00 | Albert Ramos-Viñolas | | - |  | Roger Federer | 2 | : | 1 |
| Oct 13 • 14:00 | Jo-Wilfried Tsonga | | - | | Víctor Estrella Burgos | 2 | : | 0 |
| Oct 14 • 07:30 | Bernard Tomic | | - | | David Ferrer | 2 | : | 0 |
| Oct 14 • 07:30 | David Goffin | | - | | John Isner | 0 | : | 2 |
| Oct 14 • 07:30 | Kei Nishikori | | - | | Nick Kyrgios | 2 | : | 1 |
| Oct 14 • 09:00 | Andy Murray |  | - | | Steve Johnson | 2 | : | 0 |
| Oct 14 • 09:00 | Gilles Simon | | - | | Leonardo Mayer | 2 | : | 1 |
| Oct 14 • 09:00 | Jack Sock | | - |  | Tomáš Berdych | 1 | : | 2 |
| Oct 14 • 09:00 | Fabio Fognini | | - | | Kevin Anderson | 0 | : | 2 |
| Oct 14 • 10:30 | Richard Gasquet | | - | | Vasek Pospisil | 2 | : | 1 |
| Oct 14 • 10:30 | Viktor Troicki | | - | | Stanislas Wawrinka | 0 | : | 2 |
| Oct 14 • 12:00 | Novak Djokovic | | - | | Martin Kližan | 2 | : | 0 |
| Oct 14 • 12:00 | Dominic Thiem | | - | | Feliciano López | 1 | : | 2 |
| Oct 14 • 12:00 | Roberto Bautista-Agut | | - | | Milos Raonic | 1 | : | 2 |
| Oct 14 • 14:00 | Rafael Nadal | | - | | Ivo Karlović | 2 | : | 1 |
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| Oct 15 • 07:30 | Andy Murray | | - | | John Isner | 2 | : | 1 |
| Oct 15 • 07:30 | Jo-Wilfried Tsonga | | - | | Albert Ramos-Viñolas | 2 | : | 1 |
| Oct 15 • 09:00 | Novak Djokovic | | - | | Feliciano López | 2 | : | 0 |
| Oct 15 • 09:00 | Kei Nishikori | | - | | Kevin Anderson | 0 | : | 2 |
| Oct 15 • 10:30 | Marin Čilić | | - | | Stanislas Wawrinka | 1 | : | 2 |
| Oct 15 • 12:00 | Richard Gasquet | | - | | Bernard Tomic | 1 | : | 2 |
| Oct 15 • 12:00 | Rafael Nadal | | - | | Milos Raonic | 2 | : | 0 |
| Oct 15 • 14:00 | Gilles Simon | | - | | Tomáš Berdych | 0 | : | 2 |
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| Oct 16 • 07:30 | Kevin Anderson | | - | | Jo-Wilfried Tsonga | 1 | : | 2 |
| Oct 16 • 09:00 | Rafael Nadal | | - | | Stanislas Wawrinka | 2 | : | 0 |
| Oct 16 • 12:00 | Novak Djokovic | | - | | Bernard Tomic | 2 | : | 0 |
| Oct 16 • 14:00 | Andy Murray | | - | | Tomáš Berdych | 2 | : | 0 |
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| Oct 17 • 10:30 | Rafael Nadal | | - | | Jo-Wilfried Tsonga | 1 | : | 2 |
| Oct 17 • 14:00 | Novak Djokovic | | - | | Andy Murray | 2 | : | 0 |
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| Oct 18 • 10:30 | Novak Djokovic | | - | | Jo-Wilfried Tsonga | 2 | : | 0 |
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