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| Oct 05 • 06:30 | Jo-Wilfried Tsonga |  | - |  | Andreas Haider-Maurer | 0 | : | 2 |
| Oct 05 • 08:00 | Fabio Fognini |  | - |  | Martin Kližan | 2 | : | 0 |
| Oct 05 • 08:30 | David Goffin |  | - | | Andreas Seppi | 2 | : | 0 |
| Oct 05 • 09:30 | Aljaž Bedene |  | - |  | Lukáš Rosol | 1 | : | 2 |
| Oct 05 • 10:00 | Denis Istomin |  | - |  | Ze Zhang | 1 | : | 2 |
| Oct 05 • 11:00 | Jack Sock |  | - |  | Teymuraz Gabashvili | 2 | : | 0 |
| Oct 05 • 13:30 | Viktor Troicki |  | - |  | Milos Raonic | 2 | : | 0 |
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| Oct 06 • 06:30 | Vasek Pospisil | | - |  | Víctor Estrella Burgos | 2 | : | 1 |
| Oct 06 • 06:30 | Lu Yen-Hsun |  | - | | Adrian Mannarino | 2 | : | 0 |
| Oct 06 • 08:30 | Wu Di | | - |  | Rafael Nadal | 0 | : | 2 |
| Oct 06 • 09:30 | John Millman |  | - | | Tommy Robredo | 2 | : | 1 |
| Oct 06 • 10:00 | Novak Djokovic | | - | | Simone Bolelli | 2 | : | 0 |
| Oct 06 • 12:30 | David Ferrer | | - |  | Thomaz Bellucci | 2 | : | 0 |
| Oct 06 • 15:00 | Dominic Thiem | | - | | John Isner | 0 | : | 2 |
| Oct 07 • 08:00 | Guillermo García López | | - |  | Ivo Karlović | 0 | : | 2 |
| Oct 07 • 08:30 | Pablo Cuevas |  | - | | Tomáš Berdych | 2 | : | 0 |
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| Oct 07 • 06:30 | Lu Yen-Hsun | | - | | Viktor Troicki | 2 | : | 0 |
| Oct 07 • 08:00 | Andreas Haider-Maurer | | - | | Jack Sock | 0 | : | 2 |
| Oct 07 • 10:00 | David Ferrer | | - | | Lukáš Rosol | 2 | : | 0 |
| Oct 07 • 15:00 | Vasek Pospisil | | - | | Rafael Nadal | 0 | : | 2 |
| Oct 08 • 06:30 | Ivo Karlović | | - | | Pablo Cuevas | 0 | : | 2 |
| Oct 08 • 08:30 | David Goffin | | - | | Fabio Fognini | 1 | : | 2 |
| Oct 08 • 10:00 | Novak Djokovic | | - | | Ze Zhang | 2 | : | 0 |
| Oct 08 • 12:30 | John Millman | | - | | John Isner | 1 | : | 2 |
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| Oct 09 • 06:30 | Jack Sock | | - | | Rafael Nadal | 1 | : | 2 |
| Oct 09 • 08:30 | Fabio Fognini | | - | | Pablo Cuevas | 2 | : | 1 |
| Oct 09 • 10:00 | David Ferrer | | - | | Lu Yen-Hsun | 2 | : | 0 |
| Oct 09 • 13:30 | Novak Djokovic | | - | | John Isner | 2 | : | 0 |
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| Oct 10 • 06:30 | Rafael Nadal | | - | | Fabio Fognini | 2 | : | 0 |
| Oct 10 • 13:30 | Novak Djokovic | | - | | David Ferrer | 2 | : | 0 |
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| Oct 11 • 13:30 | Novak Djokovic | | - | | Rafael Nadal | 2 | : | 0 |
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