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| May 14 • 12:00 | Fernando Verdasco |  | - |  | Donald Young | 2 | : | 0 |
| May 14 • 13:30 | Fabio Fognini |  | - | | Matteo Berrettini | 2 | : | 0 |
| May 14 • 15:00 | John Isner | | - | | Albert Ramos-Viñolas | 2 | : | 1 |
| May 14 • 15:00 | Jiří Veselý |  | - |  | Daniel Evans | 2 | : | 0 |
| May 15 • 11:00 | Jan-Lennard Struff |  | - |  | Bernard Tomic | 2 | : | 1 |
| May 15 • 11:00 | Sam Querrey | | - |  | Lucas Pouille | 2 | : | 0 |
| May 15 • 12:05 | Tomáš Berdych | | - | | Mischa Zverev | 2 | : | 0 |
| May 15 • 12:45 | David Goffin |  | - |  | Thomaz Bellucci | 2 | : | 1 |
| May 15 • 12:45 | Gianluca Mager | | - |  | Aljaž Bedene | 1 | : | 1 |
| May 15 • 14:30 | Viktor Troicki |  | - | | Stefano Napolitano | 2 | : | 0 |
| May 15 • 15:00 | Robin Haase |  | - |  | Carlos Berlocq | 0 | : | 2 |
| May 15 • 16:10 | Nicolás Almagro | | - | | Andreas Seppi | 2 | : | 0 |
| May 15 • 17:00 | Florian Mayer | | - | | Thiago Moura Monteiro | 2 | : | 0 |
| May 15 • 17:00 | João Sousa |  | - | | Kyle Edmund | 0 | : | 2 |
| May 15 • 19:00 | Ryan Harrison | | - | | Jared Donaldson | 2 | : | 1 |
| May 15 • 19:30 | Juan Martín del Potro | | - |  | Grigor Dimitrov | 2 | : | 1 |
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| May 16 • 11:00 | Adrian Mannarino | | - |  | Pablo Cuevas | 0 | : | 2 |
| May 16 • 11:00 | Jack Sock | | - | | Diego Schwartzman | 2 | : | 1 |
| May 16 • 12:30 | Kevin Anderson |  | - | | Alexander Zverev | 1 | : | 2 |
| May 16 • 12:30 | Nicolas Mahut | | - | | Benoît Paire | 0 | : | 2 |
| May 16 • 14:00 | Ernesto Escobedo | | - | | Tommy Haas | 1 | : | 2 |
| May 16 • 14:00 | David Ferrer | | - | | Feliciano López | 2 | : | 1 |
| May 16 • 14:00 | Pablo Carreño Busta | | - | | Gilles Simon | 2 | : | 0 |
| May 16 • 15:30 | Alexandr Dolgopolov |  | - | | Roberto Bautista-Agut | 0 | : | 2 |
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| May 16 • 13:30 | David Goffin | | - | | Fernando Verdasco | 2 | : | 1 |
| May 16 • 15:00 | Aljaž Bedene | | - | | Novak Djokovic | 0 | : | 2 |
| May 16 • 15:30 | Tomáš Berdych | | - | | Carlos Berlocq | 2 | : | 0 |
| May 16 • 15:30 | Florian Mayer | | - | | John Isner | 0 | : | 2 |
| May 16 • 20:15 | Ryan Harrison | | - |  | Marin Čilić | 0 | : | 2 |
| May 16 • 21:00 | Andy Murray | | - | | Fabio Fognini | 0 | : | 2 |
| May 17 • 12:00 | Kei Nishikori |  | - | | David Ferrer | 2 | : | 0 |
| May 17 • 12:30 | Kyle Edmund | | - | | Juan Martín del Potro | 0 | : | 2 |
| May 17 • 13:50 | Nicolás Almagro | | - | | Rafael Nadal | 0 | : | 0 |
| May 17 • 14:15 | Jack Sock | | - | | Jiří Veselý | 2 | : | 1 |
| May 17 • 14:30 | Viktor Troicki | | - | | Alexander Zverev | 0 | : | 2 |
| May 17 • 15:45 | Pablo Carreño Busta | | - | | Roberto Bautista-Agut | 1 | : | 2 |
| May 17 • 16:00 | Tommy Haas | | - |  | Milos Raonic | 0 | : | 2 |
| May 17 • 16:30 | Dominic Thiem |  | - | | Pablo Cuevas | 2 | : | 0 |
| May 17 • 19:30 | Stanislas Wawrinka |  | - | | Benoît Paire | 2 | : | 1 |
| May 17 • 19:30 | Jan-Lennard Struff | | - | | Sam Querrey | 0 | : | 2 |
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| May 18 • 12:00 | Fabio Fognini | | - | | Alexander Zverev | 0 | : | 2 |
| May 18 • 12:30 | David Goffin | | - | | Marin Čilić | 0 | : | 2 |
| May 18 • 14:00 | Tomáš Berdych | | - | | Milos Raonic | 0 | : | 2 |
| May 18 • 15:15 | Stanislas Wawrinka | | - | | John Isner | 0 | : | 2 |
| May 18 • 15:15 | Roberto Bautista-Agut | | - | | Novak Djokovic | 0 | : | 2 |
| May 18 • 17:30 | Kei Nishikori | | - | | Juan Martín del Potro | 0 | : | 2 |
| May 18 • 19:00 | Dominic Thiem | | - | | Sam Querrey | 2 | : | 1 |
| May 18 • 19:30 | Jack Sock | | - | | Rafael Nadal | 0 | : | 2 |
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| May 19 • 12:00 | John Isner | | - | | Marin Čilić | 2 | : | 1 |
| May 19 • 14:00 | Alexander Zverev | | - | | Milos Raonic | 2 | : | 0 |
| May 19 • 16:00 | Dominic Thiem | | - | | Rafael Nadal | 2 | : | 0 |
| May 19 • 21:00 | Juan Martín del Potro | | - | | Novak Djokovic | 0 | : | 2 |
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| May 20 • 14:30 | Alexander Zverev | | - | | John Isner | 2 | : | 1 |
| May 20 • 20:00 | Dominic Thiem | | - | | Novak Djokovic | 0 | : | 2 |
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| May 21 • 16:00 | Alexander Zverev | | - | | Novak Djokovic | 2 | : | 0 |
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