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| Oct 08 • 06:00 | Jared Donaldson |  | - |  | Pablo Cuevas | 2 | : | 1 |
| Oct 08 • 07:30 | Yibing Wu |  | - |  | Gilles Simon | 0 | : | 2 |
| Oct 08 • 12:00 | Fernando Verdasco |  | - |  | Fabio Fognini | 1 | : | 2 |
| Oct 08 • 14:00 | Daniil Medvedev |  | - | | Lucas Pouille | 0 | : | 2 |
| Oct 09 • 07:00 | Albert Ramos-Viñolas | | - |  | João Sousa | 2 | : | 1 |
| Oct 09 • 07:00 | Robin Haase |  | - | | Richard Gasquet | 1 | : | 2 |
| Oct 09 • 07:00 | Feliciano López | | - |  | Ivo Karlović | 2 | : | 0 |
| Oct 09 • 08:30 | Benoît Paire | | - | | Frances Tiafoe | 0 | : | 2 |
| Oct 09 • 08:30 | Stefanos Tsitsipas |  | - | | Karen Khachanov | 2 | : | 0 |
| Oct 09 • 08:30 | Chung Hyeon |  | - | | Roberto Bautista-Agut | 2 | : | 0 |
| Oct 09 • 10:00 | Kyle Edmund |  | - |  | Jiří Veselý | 2 | : | 0 |
| Oct 09 • 12:00 | Juan Martín del Potro |  | - |  | Nikoloz Basilashvili | 2 | : | 1 |
| Oct 09 • 12:50 | Andrey Rublev | | - |  | Damir Džumhur | 2 | : | 1 |
| Oct 09 • 14:00 | Jérémy Chardy | | - | | Di Wu | 0 | : | 2 |
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| Oct 10 • 07:00 | Ze Zhang | | - | | Ryan Harrison | 0 | : | 2 |
| Oct 10 • 07:00 | Dušan Lajović |  | - | | John Isner | 1 | : | 2 |
| Oct 10 • 07:00 | Aljaž Bedene |  | - | | Paolo Lorenzi | 2 | : | 0 |
| Oct 10 • 07:00 | Jack Sock | | - |  | Alexandr Dolgopolov | 1 | : | 1 |
| Oct 10 • 08:30 | Kevin Anderson |  | - | | Adrian Mannarino | 2 | : | 0 |
| Oct 10 • 08:30 | Mischa Zverev |  | - | | Jan-Lennard Struff | 0 | : | 0 |
| Oct 10 • 08:30 | Diego Schwartzman | | - |  | Jordan Thompson | 2 | : | 0 |
| Oct 10 • 10:10 | Steve Johnson | | - | | Nick Kyrgios | 1 | : | 0 |
| Oct 10 • 10:10 | Viktor Troicki | | - |  | Denis Shapovalov | 2 | : | 1 |
| Oct 10 • 10:30 | Sam Querrey | | - |  | Yuichi Sugita | 2 | : | 0 |
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| Oct 10 • 08:30 | Albert Ramos-Viñolas | | - | | Pablo Carreño Busta | 2 | : | 0 |
| Oct 10 • 11:30 | Fabio Fognini | | - | | Lucas Pouille | 2 | : | 0 |
| Oct 10 • 12:00 | Juan Martín del Potro | | - | | Andrey Rublev | 2 | : | 0 |
| Oct 10 • 12:00 | Richard Gasquet | | - | | Chung Hyeon | 2 | : | 1 |
| Oct 10 • 14:00 | Marin Čilić | | - | | Kyle Edmund | 2 | : | 0 |
| Oct 11 • 07:00 | Sam Querrey | | - | | Frances Tiafoe | 2 | : | 0 |
| Oct 11 • 07:00 | Ryan Harrison | | - |  | Grigor Dimitrov | 1 | : | 2 |
| Oct 11 • 07:00 | Alexandr Dolgopolov | | - | | Feliciano López | 2 | : | 1 |
| Oct 11 • 08:30 | Di Wu | | - | | Steve Johnson | 0 | : | 2 |
| Oct 11 • 08:30 | Kevin Anderson | | - | | Jan-Lennard Struff | 0 | : | 2 |
| Oct 11 • 08:30 | Aljaž Bedene | | - | | Alexander Zverev | 0 | : | 0 |
| Oct 11 • 08:30 | David Goffin |  | - | | Gilles Simon | 0 | : | 2 |
| Oct 11 • 10:00 | Stefanos Tsitsipas | | - | | John Isner | 0 | : | 2 |
| Oct 11 • 11:30 | Dominic Thiem |  | - | | Viktor Troicki | 1 | : | 2 |
| Oct 11 • 12:00 | Rafael Nadal | | - | | Jared Donaldson | 2 | : | 0 |
| Oct 11 • 14:00 | Diego Schwartzman | | - |  | Roger Federer | 0 | : | 2 |
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| Oct 12 • 06:00 | Sam Querrey | | - | | Grigor Dimitrov | 0 | : | 2 |
| Oct 12 • 07:30 | Juan Martín del Potro | | - | | Alexander Zverev | 2 | : | 1 |
| Oct 12 • 08:30 | Jan-Lennard Struff | | - | | Albert Ramos-Viñolas | 0 | : | 2 |
| Oct 12 • 09:10 | Marin Čilić | | - | | Steve Johnson | 2 | : | 0 |
| Oct 12 • 10:30 | Gilles Simon | | - | | Richard Gasquet | 1 | : | 2 |
| Oct 12 • 11:30 | Viktor Troicki | | - | | John Isner | 2 | : | 0 |
| Oct 12 • 12:00 | Rafael Nadal | | - | | Fabio Fognini | 2 | : | 0 |
| Oct 12 • 14:00 | Alexandr Dolgopolov | | - | | Roger Federer | 0 | : | 2 |
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| Oct 13 • 07:00 | Marin Čilić | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Oct 13 • 08:30 | Rafael Nadal | | - | | Grigor Dimitrov | 2 | : | 1 |
| Oct 13 • 12:00 | Viktor Troicki | | - | | Juan Martín del Potro | 1 | : | 2 |
| Oct 13 • 14:00 | Richard Gasquet | | - | | Roger Federer | 0 | : | 2 |
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| Oct 14 • 10:30 | Rafael Nadal | | - | | Marin Čilić | 2 | : | 0 |
| Oct 14 • 14:10 | Juan Martín del Potro | | - | | Roger Federer | 1 | : | 2 |
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| Oct 15 • 10:30 | Rafael Nadal | | - | | Roger Federer | 0 | : | 2 |
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