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| Oct 02 • 06:30 | Ze Zhang |  | - |  | Roberto Bautista-Agut | 0 | : | 2 |
| Oct 02 • 08:00 | Marcel Granollers | | - |  | Aljaž Bedene | 0 | : | 2 |
| Oct 02 • 08:30 | Robin Haase |  | - |  | Fabio Fognini | 0 | : | 2 |
| Oct 02 • 12:30 | Jan-Lennard Struff |  | - | | Mischa Zverev | 1 | : | 2 |
| Oct 02 • 12:30 | Fernando Verdasco | | - |  | Dušan Lajović | 1 | : | 2 |
| Oct 02 • 13:30 | Steve Darcis |  | - | | Pablo Carreño Busta | 2 | : | 0 |
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| Oct 03 • 06:30 | Grigor Dimitrov |  | - |  | Damir Džumhur | 2 | : | 1 |
| Oct 03 • 06:30 | Nick Kyrgios |  | - |  | Nikoloz Basilashvili | 2 | : | 0 |
| Oct 03 • 08:00 | Leonardo Mayer |  | - | | Paolo Lorenzi | 2 | : | 1 |
| Oct 03 • 08:30 | Pablo Cuevas |  | - | | Juan Martín del Potro | 0 | : | 2 |
| Oct 03 • 09:30 | Malek Jaziri |  | - |  | John Isner | 0 | : | 2 |
| Oct 03 • 10:00 | Rafael Nadal | | - |  | Lucas Pouille | 2 | : | 1 |
| Oct 03 • 11:25 | Jack Sock | | - |  | Andrey Rublev | 1 | : | 2 |
| Oct 03 • 12:35 | Tomáš Berdych |  | - | | Jared Donaldson | 2 | : | 1 |
| Oct 03 • 14:10 | Di Wu | | - | | Karen Khachanov | 0 | : | 2 |
| Oct 03 • 15:30 | Kyle Edmund |  | - | | Alexander Zverev | 0 | : | 2 |
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| Oct 04 • 06:30 | Nick Kyrgios | | - | | Mischa Zverev | 2 | : | 1 |
| Oct 04 • 08:30 | Dušan Lajović | | - | | Steve Darcis | 0 | : | 2 |
| Oct 04 • 10:15 | Aljaž Bedene | | - | | Roberto Bautista-Agut | 0 | : | 1 |
| Oct 04 • 13:30 | Grigor Dimitrov | | - | | Juan Martín del Potro | 2 | : | 0 |
| Oct 05 • 08:30 | Leonardo Mayer | | - | | John Isner | 0 | : | 2 |
| Oct 05 • 10:30 | Rafael Nadal | | - | | Karen Khachanov | 2 | : | 0 |
| Oct 05 • 12:30 | Tomáš Berdych | | - | | Andrey Rublev | 1 | : | 2 |
| Oct 05 • 15:00 | Fabio Fognini | | - | | Alexander Zverev | 0 | : | 2 |
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| Oct 06 • 06:30 | Grigor Dimitrov | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| Oct 06 • 08:30 | Rafael Nadal | | - | | John Isner | 2 | : | 0 |
| Oct 06 • 10:30 | Nick Kyrgios | | - | | Steve Darcis | 1 | : | 0 |
| Oct 06 • 13:30 | Andrey Rublev | | - | | Alexander Zverev | 0 | : | 2 |
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| Oct 07 • 10:30 | Rafael Nadal | | - | | Grigor Dimitrov | 2 | : | 1 |
| Oct 07 • 15:15 | Nick Kyrgios | | - | | Alexander Zverev | 2 | : | 0 |
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| Oct 08 • 13:30 | Rafael Nadal | | - | | Nick Kyrgios | 2 | : | 0 |
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