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| Apr 26 • 11:00 | Emilio Nava |  | - |  | Gregoire Barrere | 1 | : | 2 |
| Apr 26 • 11:00 | Jérémy Chardy | | - | | Hugo Gaston | 0 | : | 2 |
| Apr 26 • 11:00 | Albert Ramos-Viñolas |  | - |  | Ilya Ivashka | 2 | : | 1 |
| Apr 26 • 12:30 | Alexei Popyrin |  | - | | Quentin Halys | 1 | : | 2 |
| Apr 26 • 12:30 | Yibing Wu |  | - |  | Alex Molcan | 0 | : | 2 |
| Apr 26 • 14:10 | Alexander Bublik |  | - |  | Daniel Elahi Galán | 2 | : | 1 |
| Apr 26 • 14:20 | Roberto Carballés Baena | | - |  | David Goffin | 2 | : | 0 |
| Apr 26 • 15:15 | Juan Pablo Varillas |  | - |  | Yannick Hanfmann | 1 | : | 2 |
| Apr 26 • 15:40 | Maxime Cressy | | - |  | Stanislas Wawrinka | 1 | : | 2 |
| Apr 26 • 16:20 | Diego Schwartzman |  | - | | Hugo Grenier | 0 | : | 2 |
| Apr 26 • 17:20 | Pavel Kotov |  | - | | Oscar Otte | 1 | : | 2 |
| Apr 26 • 17:50 | Benoît Paire | | - |  | Matteo Arnaldi | 1 | : | 2 |
| Apr 26 • 18:40 | Emil Ruusuvuori |  | - | | Ugo Humbert | 2 | : | 0 |
| Apr 26 • 18:45 | Thanasi Kokkinakis | | - | | Jaume Munar | 0 | : | 2 |
| Apr 26 • 18:50 | Thiago Moura Monteiro |  | - |  | Borna Gojo | 2 | : | 1 |
| Apr 26 • 20:00 | Martin Landaluce | | - | | Richard Gasquet | 0 | : | 2 |
| Apr 27 • 11:00 | Tomás Martín Etcheverry | | - | | Adrian Mannarino | 2 | : | 0 |
| Apr 27 • 11:00 | Roman Safiullin | | - |  | Nicolás Jarry | 2 | : | 1 |
| Apr 27 • 11:00 | Kyle Edmund |  | - |  | Dominic Thiem | 0 | : | 2 |
| Apr 27 • 11:00 | Jeffrey John Wolf | | - | | Alexander Shevchenko | 0 | : | 2 |
| Apr 27 • 12:30 | Cristian Garín | | - | | Marc-Andrea Hüsler | 2 | : | 0 |
| Apr 27 • 12:30 | Jurij Rodionov | | - | | Zhang Zhizhen | 0 | : | 2 |
| Apr 27 • 12:30 | Corentin Moutet | | - |  | Yosuke Watanuki | 0 | : | 2 |
| Apr 27 • 14:15 | Abedallah Shelbayh |  | - | | Pedro Cachín | 0 | : | 2 |
| Apr 27 • 14:45 | Lorenzo Sonego | | - | | Jan-Lennard Struff | 0 | : | 2 |
| Apr 27 • 14:45 | Nuno Borges |  | - | | Marcos Giron | 0 | : | 2 |
| Apr 27 • 16:35 | Márton Fucsovics |  | - | | Marco Cecchinato | 0 | : | 2 |
| Apr 27 • 16:55 | Christopher O'Connell | | - |  | Filip Krajinović | 2 | : | 1 |
| Apr 27 • 17:00 | Andrea Vavassori | | - | | Andy Murray | 2 | : | 0 |
| Apr 27 • 18:25 | Aslan Karatsev | | - | | Laslo Djere | 2 | : | 0 |
| Apr 27 • 18:30 | Jason Kubler | | - | | Dušan Lajović | 0 | : | 2 |
| Apr 27 • 18:30 | Mackenzie McDonald | | - | | Bernabe Zapata Miralles | 1 | : | 2 |
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| Apr 28 • 11:00 | Yoshihito Nishioka | | - | | Alex Molcan | 2 | : | 1 |
| Apr 28 • 11:00 | Casper Ruud |  | - | | Matteo Arnaldi | 0 | : | 2 |
| Apr 28 • 11:00 | Jaume Munar | | - |  | Tallon Griekspoor | 1 | : | 0 |
| Apr 28 • 11:05 | Daniel Altmaier | | - | | Oscar Otte | 2 | : | 0 |
| Apr 28 • 12:40 | Yannick Hanfmann | | - | | Lorenzo Musetti | 2 | : | 0 |
| Apr 28 • 13:15 | Stanislas Wawrinka | | - | | Andrey Rublev | 0 | : | 2 |
| Apr 28 • 13:50 | Gregoire Barrere | | - |  | Grigor Dimitrov | 0 | : | 2 |
| Apr 28 • 14:15 | Karen Khachanov | | - | | Thiago Moura Monteiro | 2 | : | 1 |
| Apr 28 • 16:05 | Carlos Alcaraz | | - | | Emil Ruusuvuori | 2 | : | 1 |
| Apr 28 • 16:05 | Quentin Halys | | - | | Roberto Bautista-Agut | 1 | : | 2 |
| Apr 28 • 16:30 | Hugo Gaston | | - | | Borna Ćorić | 0 | : | 2 |
| Apr 28 • 18:00 | Hubert Hurkacz |  | - | | Richard Gasquet | 2 | : | 1 |
| Apr 28 • 18:45 | Sebastian Korda | | - | | Hugo Grenier | 0 | : | 2 |
| Apr 28 • 19:15 | Alejandro Davidovich Fokina | | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Apr 28 • 19:15 | Alexander Bublik | | - |  | Holger Rune | 1 | : | 2 |
| Apr 28 • 21:30 | Roberto Carballés Baena | | - | | Alexander Zverev | 1 | : | 2 |
| Apr 29 • 11:00 | Jan-Lennard Struff | | - | | Ben Shelton | 2 | : | 1 |
| Apr 29 • 11:00 | Jiří Lehečka |  | - | | Alexander Shevchenko | 0 | : | 2 |
| Apr 29 • 11:00 | Andrea Vavassori | | - | | Daniil Medvedev | 0 | : | 2 |
| Apr 29 • 12:10 | Tommy Paul | | - | | Roman Safiullin | 0 | : | 2 |
| Apr 29 • 12:30 | Felix Auger Aliassime |  | - | | Dušan Lajović | 1 | : | 2 |
| Apr 29 • 12:30 | Alex De Minaur | | - | | Marco Cecchinato | 2 | : | 0 |
| Apr 29 • 12:30 | Aslan Karatsev | | - | | Botic van de Zandschulp | 2 | : | 0 |
| Apr 29 • 14:00 | Bernabe Zapata Miralles | | - | | Daniel Evans | 2 | : | 0 |
| Apr 29 • 14:00 | Sebastián Báez | | - | | Marcos Giron | 2 | : | 1 |
| Apr 29 • 14:00 | Taylor Harry Fritz | | - | | Christopher O'Connell | 2 | : | 0 |
| Apr 29 • 14:00 | Cristian Garín | | - | | Miomir Kecmanovic | 2 | : | 1 |
| Apr 29 • 15:30 | Francisco Cerundolo | | - | | Pedro Cachín | 0 | : | 2 |
| Apr 29 • 15:30 | Tomás Martín Etcheverry | | - | | Frances Tiafoe | 0 | : | 2 |
| Apr 29 • 15:30 | Denis Shapovalov | | - | | Zhang Zhizhen | 1 | : | 2 |
| Apr 29 • 18:00 | Yosuke Watanuki | | - | | Cameron Norrie | 0 | : | 2 |
| Apr 29 • 20:00 | Dominic Thiem | | - |  | Stefanos Tsitsipas | 1 | : | 2 |
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| Apr 30 • 11:00 | Karen Khachanov | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| Apr 30 • 11:00 | Matteo Arnaldi | | - | | Jaume Munar | 1 | : | 2 |
| Apr 30 • 12:30 | Yoshihito Nishioka | | - | | Andrey Rublev | 0 | : | 2 |
| Apr 30 • 14:00 | Hugo Grenier | | - | | Alexander Zverev | 0 | : | 2 |
| Apr 30 • 15:30 | Hubert Hurkacz | | - | | Borna Ćorić | 0 | : | 2 |
| Apr 30 • 20:00 | Carlos Alcaraz | | - | | Grigor Dimitrov | 2 | : | 0 |
| Apr 30 • 20:25 | Daniel Altmaier | | - | | Yannick Hanfmann | 2 | : | 0 |
| Apr 30 • 21:30 | Alejandro Davidovich Fokina | | - | | Holger Rune | 2 | : | 1 |
| May 01 • 11:00 | Alexander Shevchenko | | - | | Daniil Medvedev | 1 | : | 2 |
| May 01 • 12:15 | Pedro Cachín | | - | | Frances Tiafoe | 2 | : | 0 |
| May 01 • 12:15 | Alex De Minaur | | - | | Aslan Karatsev | 1 | : | 2 |
| May 01 • 12:20 | Dušan Lajović | | - | | Jan-Lennard Struff | 1 | : | 2 |
| May 01 • 13:35 | Roman Safiullin | | - | | Bernabe Zapata Miralles | 1 | : | 2 |
| May 01 • 14:55 | Taylor Harry Fritz | | - | | Cristian Garín | 2 | : | 0 |
| May 01 • 16:05 | Zhang Zhizhen | | - | | Cameron Norrie | 2 | : | 1 |
| May 01 • 20:00 | Sebastián Báez | | - | | Stefanos Tsitsipas | 1 | : | 2 |
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| May 02 • 11:00 | Karen Khachanov | | - | | Andrey Rublev | 2 | : | 0 |
| May 02 • 11:00 | Jaume Munar | | - | | Daniel Altmaier | 0 | : | 2 |
| May 02 • 12:20 | Aslan Karatsev | | - | | Daniil Medvedev | 2 | : | 0 |
| May 02 • 13:40 | Borna Ćorić | | - | | Alejandro Davidovich Fokina | 2 | : | 1 |
| May 02 • 16:00 | Carlos Alcaraz | | - | | Alexander Zverev | 2 | : | 0 |
| May 02 • 18:15 | Taylor Harry Fritz | | - | | Zhang Zhizhen | 1 | : | 2 |
| May 02 • 19:45 | Jan-Lennard Struff | | - | | Pedro Cachín | 2 | : | 1 |
| May 02 • 21:15 | Bernabe Zapata Miralles | | - | | Stefanos Tsitsipas | 0 | : | 2 |
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| May 03 • 16:00 | Carlos Alcaraz | | - | | Karen Khachanov | 2 | : | 0 |
| May 03 • 21:30 | Daniel Altmaier | | - | | Borna Ćorić | 0 | : | 2 |
| May 04 • 13:00 | Zhang Zhizhen | | - | | Aslan Karatsev | 0 | : | 2 |
| May 04 • 20:00 | Jan-Lennard Struff | | - | | Stefanos Tsitsipas | 2 | : | 1 |
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| May 05 • 16:00 | Carlos Alcaraz | | - | | Borna Ćorić | 2 | : | 0 |
| May 05 • 20:00 | Jan-Lennard Struff | | - | | Aslan Karatsev | 2 | : | 1 |
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| May 07 • 18:30 | Carlos Alcaraz | | - | | Jan-Lennard Struff | 2 | : | 1 |
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