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| Mar 20 • 16:00 | Pavel Kotov |  | - |  | Luca Van Assche | 0 | : | 2 |
| Mar 20 • 16:00 | Rinky Hijikata |  | - |  | Botic van de Zandschulp | 0 | : | 2 |
| Mar 20 • 16:00 | Luciano Darderi |  | - |  | Denis Shapovalov | 1 | : | 2 |
| Mar 20 • 17:15 | Jack Draper |  | - |  | Taro Daniel | 2 | : | 0 |
| Mar 20 • 17:30 | Yoshihito Nishioka | | - | | Flavio Cobolli | 1 | : | 2 |
| Mar 20 • 17:30 | Christopher O'Connell | | - |  | Vít Kopřiva | 2 | : | 0 |
| Mar 20 • 18:30 | Tomáš Macháč | | - |  | Darwin Blanch | 2 | : | 0 |
| Mar 20 • 19:00 | Thiago Seyboth Wild |  | - |  | Nuno Borges | 2 | : | 0 |
| Mar 20 • 19:00 | Max Purcell | | - |  | Márton Fucsovics | 0 | : | 2 |
| Mar 20 • 19:00 | Pedro Cachín |  | - | | Andrea Vavassori | 0 | : | 2 |
| Mar 20 • 20:00 | Andy Murray | | - | | Matteo Berrettini | 2 | : | 1 |
| Mar 20 • 20:30 | Miomir Kecmanovic |  | - |  | Shang Juncheng | 1 | : | 2 |
| Mar 20 • 21:30 | Martin Damm | | - | | Zhang Zhizhen | 2 | : | 0 |
| Mar 20 • 23:00 | Arthur Fils | | - | | Matteo Arnaldi | 0 | : | 2 |
| Mar 21 • 00:00 | Marcos Giron | | - |  | Dominik Koepfer | 1 | : | 2 |
| Mar 21 • 01:00 | Alex Michelsen | | - |  | Lukáš Klein | 2 | : | 0 |
| Mar 21 • 16:00 | Laslo Djere | | - |  | Coleman Wong | 2 | : | 0 |
| Mar 21 • 16:00 | Daniel Altmaier | | - | | Harold Mayot | 2 | : | 0 |
| Mar 21 • 17:00 | Felix Auger Aliassime | | - | | Adam Walton | 2 | : | 0 |
| Mar 21 • 17:30 | Alejandro Tabilo |  | - | | Brandon Nakashima | 2 | : | 1 |
| Mar 21 • 17:30 | Sebastian Ofner |  | - | | Kei Nishikori | 2 | : | 0 |
| Mar 21 • 19:00 | Lorenzo Sonego | | - | | Daniel Evans | 1 | : | 2 |
| Mar 21 • 19:00 | Aleksandar Kovacevic | | - | | Fábián Marozsán | 0 | : | 2 |
| Mar 21 • 20:30 | Emil Ruusuvuori |  | - | | Yannick Hanfmann | 1 | : | 2 |
| Mar 21 • 20:30 | Alexandre Muller | | - |  | Kwon Soon-woo | 0 | : | 2 |
| Mar 21 • 22:50 | Martin Landaluce |  | - | | Jaume Munar | 2 | : | 1 |
| Mar 21 • 23:00 | Aleksandar Vukic | | - | | Roberto Carballés Baena | 0 | : | 2 |
| Mar 21 • 23:00 | Emilio Nava | | - | | Roberto Bautista-Agut | 0 | : | 2 |
| Mar 21 • 23:15 | Daniel Elahi Galán |  | - | | Alexander Shevchenko | 1 | : | 2 |
| Mar 21 • 23:15 | Alexei Popyrin | | - | | Facundo Díaz Acosta | 2 | : | 0 |
| Mar 21 • 23:45 | Dušan Lajović | | - | | Gaël Monfils | 0 | : | 2 |
| Mar 22 • 00:15 | Roman Safiullin | | - | | Diego Schwartzman | 2 | : | 0 |
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| Mar 22 • 16:00 | Andrey Rublev | | - | | Tomáš Macháč | 0 | : | 2 |
| Mar 22 • 22:30 | Ugo Humbert | | - | | Botic van de Zandschulp | 2 | : | 0 |
| Mar 22 • 23:30 | Andy Murray | | - | | Tomás Martín Etcheverry | 2 | : | 0 |
| Mar 22 • 23:30 | Denis Shapovalov | | - |  | Stefanos Tsitsipas | 2 | : | 0 |
| Mar 22 • 23:30 | Andrea Vavassori | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 23 • 16:00 | Nicolás Jarry | | - | | Jack Draper | 2 | : | 1 |
| Mar 23 • 16:00 | Thiago Seyboth Wild | | - | | Taylor Harry Fritz | 2 | : | 0 |
| Mar 23 • 16:00 | Dominik Koepfer | | - | | Sebastián Báez | 2 | : | 0 |
| Mar 23 • 16:00 | Tommy Paul | | - | | Martin Damm | 0 | : | 0 |
| Mar 23 • 16:00 | Christopher O'Connell | | - | | Frances Tiafoe | 2 | : | 0 |
| Mar 23 • 16:00 | Tallon Griekspoor | | - | | Alex Michelsen | 2 | : | 1 |
| Mar 23 • 17:20 | Shang Juncheng | | - | | Alejandro Davidovich Fokina | 0 | : | 2 |
| Mar 23 • 17:20 | Alexander Bublik |  | - | | Matteo Arnaldi | 0 | : | 2 |
| Mar 23 • 18:35 | Márton Fucsovics | | - | | Daniil Medvedev | 0 | : | 2 |
| Mar 23 • 22:15 | Casper Ruud |  | - | | Luca Van Assche | 2 | : | 1 |
| Mar 23 • 22:15 | Cameron Norrie | | - | | Flavio Cobolli | 2 | : | 1 |
| Mar 23 • 22:30 | Sebastian Korda | | - | | Roberto Bautista-Agut | 2 | : | 1 |
| Mar 23 • 23:00 | Alexander Shevchenko | | - |  | Hubert Hurkacz | 1 | : | 2 |
| Mar 24 • 00:15 | Alexander Zverev | | - | | Felix Auger Aliassime | 2 | : | 0 |
| Mar 24 • 00:25 | Daniel Evans | | - | | Christopher Eubanks | 1 | : | 2 |
| Mar 24 • 00:40 | Gaël Monfils | | - | | Jordan Thompson | 2 | : | 1 |
| Mar 24 • 00:55 | Francisco Cerundolo | | - | | Sebastian Ofner | 2 | : | 1 |
| Mar 24 • 01:00 | Carlos Alcaraz | | - | | Roberto Carballés Baena | 2 | : | 0 |
| Mar 24 • 01:30 | Laslo Djere | | - | | Karen Khachanov | 0 | : | 2 |
| Mar 24 • 16:00 | Lorenzo Musetti | | - | | Roman Safiullin | 2 | : | 0 |
| Mar 24 • 16:00 | Martin Landaluce | | - | | Ben Shelton | 0 | : | 2 |
| Mar 24 • 16:00 | Yannick Hanfmann | | - | | Adrian Mannarino | 2 | : | 1 |
| Mar 24 • 16:00 | Daniel Altmaier | | - | | Jan-Lennard Struff | 0 | : | 2 |
| Mar 24 • 17:30 | Grigor Dimitrov |  | - | | Alejandro Tabilo | 2 | : | 1 |
| Mar 24 • 17:30 | Alex De Minaur | | - | | Kwon Soon-woo | 2 | : | 0 |
| Mar 24 • 17:30 | Jiří Lehečka | | - | | Alexei Popyrin | 0 | : | 2 |
| Mar 24 • 18:30 | Fábián Marozsán | | - |  | Holger Rune | 2 | : | 0 |
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| Mar 24 • 19:05 | Tallon Griekspoor | | - | | Jannik Sinner | 1 | : | 2 |
| Mar 24 • 19:55 | Tomáš Macháč | | - | | Andy Murray | 2 | : | 1 |
| Mar 24 • 20:15 | Matteo Arnaldi | | - | | Denis Shapovalov | 2 | : | 0 |
| Mar 24 • 23:20 | Martin Damm | | - | | Christopher O'Connell | 0 | : | 2 |
| Mar 24 • 23:30 | Nicolás Jarry | | - | | Thiago Seyboth Wild | 2 | : | 1 |
| Mar 25 • 00:00 | Casper Ruud | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Mar 25 • 00:40 | Ugo Humbert | | - | | Dominik Koepfer | 1 | : | 2 |
| Mar 25 • 01:30 | Cameron Norrie | | - | | Daniil Medvedev | 0 | : | 2 |
| Mar 25 • 16:00 | Francisco Cerundolo | | - | | Karen Khachanov | 1 | : | 2 |
| Mar 25 • 16:00 | Alexei Popyrin | | - | | Fábián Marozsán | 0 | : | 2 |
| Mar 25 • 17:00 | Alexander Zverev | | - | | Christopher Eubanks | 2 | : | 0 |
| Mar 25 • 17:15 | Alex De Minaur | | - | | Jan-Lennard Struff | 2 | : | 0 |
| Mar 25 • 20:50 | Sebastian Korda | | - | | Hubert Hurkacz | 1 | : | 2 |
| Mar 26 • 00:00 | Carlos Alcaraz | | - | | Gaël Monfils | 2 | : | 0 |
| Mar 26 • 00:10 | Lorenzo Musetti | | - | | Ben Shelton | 2 | : | 0 |
| Mar 26 • 00:15 | Grigor Dimitrov | | - | | Yannick Hanfmann | 2 | : | 0 |
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| Mar 26 • 16:00 | Tomáš Macháč | | - | | Matteo Arnaldi | 2 | : | 0 |
| Mar 26 • 17:00 | Dominik Koepfer | | - | | Daniil Medvedev | 0 | : | 2 |
| Mar 26 • 17:30 | Casper Ruud | | - | | Nicolás Jarry | 0 | : | 2 |
| Mar 26 • 20:00 | Christopher O'Connell | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 26 • 22:15 | Carlos Alcaraz | | - | | Lorenzo Musetti | 2 | : | 0 |
| Mar 26 • 22:30 | Grigor Dimitrov | | - | | Hubert Hurkacz | 2 | : | 1 |
| Mar 27 • 00:00 | Alex De Minaur | | - | | Fábián Marozsán | 1 | : | 2 |
| Mar 27 • 01:30 | Alexander Zverev | | - | | Karen Khachanov | 2 | : | 0 |
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| Mar 27 • 20:00 | Tomáš Macháč | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 28 • 01:30 | Nicolás Jarry | | - | | Daniil Medvedev | 0 | : | 2 |
| Mar 28 • 18:00 | Alexander Zverev | | - | | Fábián Marozsán | 2 | : | 0 |
| Mar 29 • 00:00 | Carlos Alcaraz | | - | | Grigor Dimitrov | 0 | : | 2 |
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| Mar 29 • 20:00 | Daniil Medvedev | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 30 • 00:00 | Grigor Dimitrov | | - | | Alexander Zverev | 2 | : | 1 |
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| Mar 31 • 21:00 | Grigor Dimitrov | | - | | Jannik Sinner | 0 | : | 2 |
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