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| May 27 • 11:00 | Samantha Stosur |  | - |  | Elena Baltacha | 2 | : | 0 |
| May 27 • 11:00 | Lucie Šafářová |  | - |  | Anastasiya Yakimova | 2 | : | 0 |
| May 27 • 11:00 | Svetlana Kuznetsova |  | - |  | Mirjana Lučić-Baroni | 2 | : | 0 |
| May 27 • 11:00 | María José Martínez Sánchez |  | - | | Eva Birnerová | 2 | : | 1 |
| May 27 • 11:00 | Irina Falconi |  | - | | Edina Gallovits-Hall | 2 | : | 1 |
| May 27 • 11:15 | Melanie Oudin | | - |  | Johanna Larsson | 2 | : | 0 |
| May 27 • 13:15 | Angelique Kerber |  | - |  | Shuai Zhang | 2 | : | 0 |
| May 27 • 13:55 | Sara Errani |  | - | | Casey Dellacqua | 2 | : | 1 |
| May 27 • 15:00 | Ana Ivanovic |  | - | | Lara Arruabarrena-Vecino | 2 | : | 0 |
| May 27 • 15:35 | Stephanie Dubois |  | - |  | Shahar Pe'er | 0 | : | 2 |
| May 27 • 17:00 | Mathilde Johansson |  | - | | Anastasia Rodionova | 2 | : | 1 |
| May 27 • 17:40 | Heidi El Tabakh | | - | | Aleksandra Wozniak | 0 | : | 2 |
| May 27 • 18:20 | Kai-Chen Chang |  | - | | Irena Pavlovic | 0 | : | 2 |
| May 27 • 18:45 | Venus Williams | | - |  | Paula Ormaechea | 2 | : | 1 |
| May 27 • 19:15 | Caroline Garcia | | - | | Dinah Pfizenmaier | 1 | : | 2 |
| May 27 • 19:30 | Anna Tatishvili | | - | | Alexa Glatch | 1 | : | 2 |
| May 28 • 11:00 | Victoria Azarenka | | - | | Alberta Brianti | 2 | : | 1 |
| May 28 • 11:00 | Dominika Cibulkova |  | - | | Kristina Mladenovic | 2 | : | 0 |
| May 28 • 11:00 | Jelena Jankovic | | - |  | Patricia Mayr-Achleiter | 2 | : | 1 |
| May 28 • 11:15 | Nadia Petrova | | - | | Iveta Benesova | 2 | : | 0 |
| May 28 • 11:15 | A Medina Garrigues | | - | | Laura Robson | 2 | : | 0 |
| May 28 • 11:15 | Mona Barthel | | - | | Lauren Davis | 0 | : | 2 |
| May 28 • 11:20 | Vania King | | - |  | Galina Voskoboeva | 2 | : | 0 |
| May 28 • 11:20 | Yung-Jan Chan | | - |  | Kateryna Bondarenko | 2 | : | 0 |
| May 28 • 12:15 | Romina Oprandi |  | - | | Olga Govortsova | 0 | : | 2 |
| May 28 • 12:25 | Jie Zheng | | - | | Alize Cornet | 2 | : | 0 |
| May 28 • 12:30 | Christina McHale | | - |  | Kiki Bertens | 2 | : | 1 |
| May 28 • 12:50 | Petra Martic | | - | | Michaella Krajicek | 2 | : | 0 |
| May 28 • 13:00 | Sesil Karatantcheva |  | - |  | Tímea Babos | 2 | : | 0 |
| May 28 • 13:10 | Laura Pous-Tio | | - |  | Chanelle Scheepers | 1 | : | 2 |
| May 28 • 13:45 | Li Na | | - |  | Sorana Cirstea | 2 | : | 0 |
| May 28 • 14:45 | Flavia Pennetta | | - | | Su-Wei Hsieh | 2 | : | 1 |
| May 28 • 14:55 | Petra Cetkovska | | - | | Simona Halep | 2 | : | 0 |
| May 28 • 15:05 | Ekaterina Makarova | | - | | Sloane Stephens | 0 | : | 2 |
| May 28 • 15:15 | Varvara Lepchenko | | - | | Ksenia Pervak | 2 | : | 1 |
| May 28 • 15:30 | Sabine Lisicki | | - | | Bethanie Mattek-Sands | 0 | : | 2 |
| May 28 • 15:40 | Tamarine Tanasugarn |  | - | | Carla Suarez Navarro | 0 | : | 2 |
| May 28 • 16:35 | Monica Niculescu | | - | | Nina Bratchikova | 1 | : | 2 |
| May 28 • 16:45 | Roberta Vinci | | - | | Sofia Arvidsson | 1 | : | 2 |
| May 28 • 18:10 | Marion Bartoli | | - | | Karolina Pliskova | 2 | : | 0 |
| May 28 • 18:35 | Yaroslava Shvedova | | - |  | Mandy Minella | 2 | : | 0 |
| May 28 • 18:35 | Vera Dushevina | | - | | Claire Feuerstein | 0 | : | 2 |
| May 28 • 19:00 | Agnieszka Radwanska |  | - | | Bojana Jovanovski | 2 | : | 0 |
| May 28 • 19:00 | Barbora Strýcová | | - | | Stéphanie Foretz | 0 | : | 2 |
| May 29 • 11:10 | Petra Kvitova | | - | | Ashleigh Barty | 2 | : | 0 |
| May 29 • 11:10 | Francesca Schiavone | | - |  | Kimiko Date-Krumm | 2 | : | 0 |
| May 29 • 11:10 | Polona Hercog |  | - | | Ayumi Morita | 1 | : | 2 |
| May 29 • 11:10 | Julia Görges | | - | | Lucie Hradecka | 2 | : | 0 |
| May 29 • 11:10 | Klara Koukalová | | - | | Lesia Tsurenko | 2 | : | 0 |
| May 29 • 11:15 | Elena Vesnina | | - | | Heather Watson | 0 | : | 2 |
| May 29 • 12:25 | Maria Sharapova | | - | | Alexandra Cadanțu-Ignatik | 2 | : | 0 |
| May 29 • 13:15 | Anastasia Pavlyuchenkova | | - | | Greta Arn | 2 | : | 0 |
| May 29 • 13:15 | Tsvetana Pironkova | | - |  | Yanina Wickmayer | 2 | : | 1 |
| May 29 • 13:30 | Arantxa Rus | | - | | Jamie Hampton | 1 | : | 0 |
| May 29 • 13:35 | Marina Erakovic |  | - | | Lourdes Dominguez Lino | 0 | : | 2 |
| May 29 • 14:05 | Pauline Parmentier | | - | | Urszula Radwanska | 0 | : | 2 |
| May 29 • 15:00 | Anne Keothavong | | - | | Melinda Czink | 0 | : | 2 |
| May 29 • 16:15 | Kaia Kanepi |  | - | | Alexandra Panova | 2 | : | 0 |
| May 29 • 17:15 | Irina-Camelia Begu | | - | | Aravane Rezai | 2 | : | 1 |
| May 29 • 17:40 | Maria Kirilenko | | - | | Victoria Larriere | 2 | : | 0 |
| May 29 • 17:50 | Serena Williams | | - | | Virginie Razzano | 1 | : | 2 |
| May 29 • 18:45 | Jarmila Gajdosova | | - | | Magdaléna Rybáriková | 1 | : | 0 |
| May 29 • 19:20 | Caroline Wozniacki |  | - |  | Eleni Daniilidou | 2 | : | 0 |
| May 29 • 19:40 | Shuai Peng | | - | | Tamira Paszek | 2 | : | 0 |
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| May 30 • 11:00 | Samantha Stosur | | - | | Irina Falconi | 2 | : | 0 |
| May 30 • 11:00 | Sara Errani | | - | | Melanie Oudin | 2 | : | 0 |
| May 30 • 11:00 | Aleksandra Wozniak | | - | | Jie Zheng | 2 | : | 0 |
| May 30 • 11:00 | Victoria Azarenka | | - | | Dinah Pfizenmaier | 2 | : | 0 |
| May 30 • 11:00 | Vania King | | - | | Dominika Cibulkova | 0 | : | 2 |
| May 30 • 12:30 | A Medina Garrigues | | - | | Irena Pavlovic | 2 | : | 0 |
| May 30 • 12:35 | Nadia Petrova | | - | | Chanelle Scheepers | 2 | : | 0 |
| May 30 • 12:55 | Lucie Šafářová | | - | | María José Martínez Sánchez | 0 | : | 2 |
| May 30 • 13:45 | Mathilde Johansson | | - | | Petra Cetkovska | 2 | : | 0 |
| May 30 • 14:55 | Yung-Jan Chan | | - | | Svetlana Kuznetsova | 0 | : | 2 |
| May 30 • 15:10 | Shahar Pe'er | | - | | Ana Ivanovic | 0 | : | 2 |
| May 30 • 15:45 | Petra Martic | | - | | Marion Bartoli | 2 | : | 1 |
| May 30 • 16:00 | Bethanie Mattek-Sands | | - | | Sloane Stephens | 0 | : | 2 |
| May 30 • 18:30 | Agnieszka Radwanska | | - | | Venus Williams | 2 | : | 0 |
| May 30 • 18:30 | Alexa Glatch | | - | | Flavia Pennetta | 0 | : | 2 |
| May 30 • 19:45 | Angelique Kerber | | - | | Olga Govortsova | 2 | : | 0 |
| May 31 • 11:00 | Urszula Radwanska | | - | | Petra Kvitova | 0 | : | 2 |
| May 31 • 11:00 | Melinda Czink | | - | | Anastasia Pavlyuchenkova | 1 | : | 2 |
| May 31 • 11:15 | Maria Kirilenko | | - | | Klara Koukalová | 1 | : | 2 |
| May 31 • 13:25 | Nina Bratchikova | | - | | Claire Feuerstein | 2 | : | 1 |
| May 31 • 13:30 | Francesca Schiavone | | - | | Tsvetana Pironkova | 2 | : | 1 |
| May 31 • 14:00 | Jarmila Gajdosova | | - | | Caroline Wozniacki | 0 | : | 2 |
| May 31 • 14:45 | Jelena Jankovic | | - | | Varvara Lepchenko | 1 | : | 2 |
| May 31 • 15:50 | Carla Suarez Navarro | | - | | Sesil Karatantcheva | 2 | : | 1 |
| May 31 • 16:00 | Li Na | | - | | Stéphanie Foretz | 2 | : | 0 |
| May 31 • 16:20 | Kaia Kanepi | | - | | Irina-Camelia Begu | 2 | : | 0 |
| May 31 • 17:55 | Christina McHale | | - | | Lauren Davis | 2 | : | 0 |
| May 31 • 18:30 | Sofia Arvidsson | | - | | Yaroslava Shvedova | 0 | : | 2 |
| May 31 • 18:30 | Virginie Razzano | | - | | Arantxa Rus | 0 | : | 2 |
| May 31 • 19:15 | Shuai Peng | | - | | Lourdes Dominguez Lino | 2 | : | 0 |
| May 31 • 19:45 | Heather Watson | | - | | Julia Görges | 0 | : | 2 |
| Jun 01 • 12:30 | Ayumi Morita | | - | | Maria Sharapova | 0 | : | 2 |
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| Jun 01 • 11:00 | Sara Errani | | - | | Ana Ivanovic | 2 | : | 1 |
| Jun 01 • 11:00 | Sloane Stephens | | - | | Mathilde Johansson | 2 | : | 0 |
| Jun 01 • 13:00 | María José Martínez Sánchez | | - | | Dominika Cibulkova | 0 | : | 2 |
| Jun 01 • 13:00 | Agnieszka Radwanska | | - | | Svetlana Kuznetsova | 0 | : | 2 |
| Jun 01 • 13:30 | A Medina Garrigues | | - | | Petra Martic | 0 | : | 2 |
| Jun 01 • 15:35 | Nadia Petrova | | - | | Samantha Stosur | 0 | : | 2 |
| Jun 01 • 19:40 | Angelique Kerber | | - | | Flavia Pennetta | 2 | : | 1 |
| Jun 01 • 20:00 | Victoria Azarenka | | - | | Aleksandra Wozniak | 2 | : | 0 |
| Jun 02 • 11:10 | Nina Bratchikova | | - | | Petra Kvitova | 1 | : | 2 |
| Jun 02 • 11:10 | Yaroslava Shvedova | | - | | Carla Suarez Navarro | 2 | : | 0 |
| Jun 02 • 11:15 | Francesca Schiavone | | - | | Varvara Lepchenko | 1 | : | 2 |
| Jun 02 • 13:15 | Li Na | | - | | Christina McHale | 2 | : | 1 |
| Jun 02 • 14:15 | Klara Koukalová | | - | | Anastasia Pavlyuchenkova | 2 | : | 0 |
| Jun 02 • 16:10 | Shuai Peng | | - | | Maria Sharapova | 0 | : | 2 |
| Jun 02 • 18:15 | Kaia Kanepi | | - | | Caroline Wozniacki | 2 | : | 1 |
| Jun 02 • 19:10 | Arantxa Rus | | - | | Julia Görges | 2 | : | 1 |
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| Jun 03 • 11:00 | Svetlana Kuznetsova | | - | | Sara Errani | 0 | : | 2 |
| Jun 03 • 11:00 | Angelique Kerber | | - | | Petra Martic | 2 | : | 0 |
| Jun 03 • 13:10 | Victoria Azarenka | | - | | Dominika Cibulkova | 0 | : | 2 |
| Jun 03 • 19:30 | Sloane Stephens | | - | | Samantha Stosur | 0 | : | 2 |
| Jun 04 • 14:00 | Klara Koukalová | | - | | Maria Sharapova | 1 | : | 2 |
| Jun 04 • 14:50 | Li Na | | - | | Yaroslava Shvedova | 1 | : | 2 |
| Jun 04 • 19:13 | Petra Kvitova | | - | | Varvara Lepchenko | 2 | : | 0 |
| Jun 04 • 19:23 | Arantxa Rus | | - | | Kaia Kanepi | 1 | : | 2 |
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| Jun 05 • 14:00 | Sara Errani | | - | | Angelique Kerber | 2 | : | 0 |
| Jun 05 • 14:00 | Dominika Cibulkova | | - | | Samantha Stosur | 0 | : | 2 |
| Jun 06 • 14:10 | Yaroslava Shvedova | | - | | Petra Kvitova | 1 | : | 2 |
| Jun 06 • 14:10 | Kaia Kanepi | | - | | Maria Sharapova | 0 | : | 2 |
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| Jun 07 • 14:00 | Samantha Stosur | | - | | Sara Errani | 1 | : | 2 |
| Jun 07 • 17:30 | Petra Kvitova | | - | | Maria Sharapova | 0 | : | 2 |
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| Jun 09 • 15:00 | Sara Errani | | - | | Maria Sharapova | 0 | : | 2 |
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