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| Sep 05 • 17:30 | CD Mensajero |  | - |  | SD Compostela | 0 | : | 3 |
| Sep 05 • 19:00 | UD Poblense |  | - |  | Ontinyent CF | 1 | : | 4 |
| Sep 05 • 20:00 | Rápido de Bouzas |  | - |  | Unionistas de Salamanca | 0 | : | 4 |
| Sep 05 • 20:00 | Inter de Madrid |  | - |  | CF Fuenlabrada | 2 | : | 2 |
| Sep 05 • 20:00 | CDA Navalcarnero |  | - |  | Cultural Leonesa | 0 | : | 2 |
| Sep 05 • 20:00 | UP Langreo |  | - |  | UD Logroñés | 1 | : | 2 |
| Sep 05 • 20:00 | Gernika Club |  | - |  | SCD Durango | 1 | : | 0 |
| Sep 05 • 20:00 | CD Castellón |  | - |  | UB Conquense | 1 | : | 0 |
| Sep 05 • 20:00 | Lleida CF |  | - |  | CD Teruel | 2 | : | 0 |
| Sep 05 • 20:00 | UCAM Murcia |  | - |  | AD Ceuta FC | 2 | : | 0 |
| Sep 05 • 20:15 | Barakaldo CF |  | - |  | UD Mutilvera | 1 | : | 1 |
| Sep 05 • 20:30 | CD Mirandés |  | - |  | Racing Santander | 0 | : | 1 |
| Sep 05 • 20:30 | UE Cornellà |  | - |  | UE Sant Andreu | 1 | : | 1 |
| Sep 05 • 20:30 | Yeclano Deportivo |  | - |  | UD Melilla | 1 | : | 2 |
| Sep 05 • 20:30 | Marbella FC |  | - |  | CD Ebro | 0 | : | 1 |
| Sep 05 • 20:30 | CD Calahorra |  | - |  | Gimnástica de Torrelavega | 1 | : | 1 |
| Sep 05 • 20:45 | CD Don Benito |  | - |  | FC Cartagena | 0 | : | 1 |
| Sep 05 • 20:45 | CF Talavera de la Reina |  | - |  | Real Jaén | 2 | : | 2 |
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| Sep 11 • 18:45 | Málaga CF |  | - |  | UD Almeria | 1 | : | 2 |
| Sep 11 • 18:45 | RCD Mallorca |  | - |  | Real Oviedo | 1 | : | 0 |
| Sep 12 • 18:00 | CD Ebro | | - |  | Real Murcia | 0 | : | 0 |
| Sep 12 • 19:30 | Ontinyent CF | | - | | Real Jaén | 1 | : | 1 |
| Sep 12 • 20:00 | Lleida CF | | - | | SD Compostela | 1 | : | 0 |
| Sep 12 • 20:00 | UCAM Murcia | | - | | Racing Santander | 0 | : | 2 |
| Sep 12 • 20:00 | CA Osasuna |  | - |  | CF Reus Deportiu | 1 | : | 2 |
| Sep 12 • 20:00 | AD Alcorcón |  | - |  | Extremadura UD | 1 | : | 0 |
| Sep 12 • 20:30 | Cultural Leonesa | | - | | CF Fuenlabrada | 1 | : | 1 |
| Sep 12 • 20:30 | UE Sant Andreu | | - | | Gernika Club | 1 | : | 0 |
| Sep 12 • 20:30 | CD Calahorra | | - | | CD Castellón | 2 | : | 0 |
| Sep 12 • 20:45 | CF Villanovense |  | - |  | CF Badalona | 2 | : | 1 |
| Sep 12 • 20:45 | UD Melilla | | - |  | CD Tudelano | 3 | : | 0 |
| Sep 12 • 20:45 | Lorca FC |  | - | | Unionistas de Salamanca | 2 | : | 1 |
| Sep 12 • 21:00 | FC Cartagena | | - | | UD Logroñés | 1 | : | 1 |
| Sep 12 • 21:00 | Real Zaragoza |  | - |  | Deportivo La Coruña | 2 | : | 1 |
| Sep 12 • 22:00 | CD Tenerife |  | - |  | Cádiz CF | 1 | : | 2 |
| Sep 12 • 22:00 | Córdoba CF |  | - |  | Gimnàstic de Tarragona | 2 | : | 0 |
| Sep 13 • 20:00 | CD Numancia |  | - |  | Sporting de Gijon | 1 | : | 2 |
| Sep 13 • 20:00 | Albacete Balompié |  | - |  | CD Lugo | 2 | : | 3 |
| Sep 13 • 22:00 | UD Las Palmas |  | - |  | Rayo Majadahonda | 1 | : | 2 |
| Sep 13 • 22:00 | Elche CF |  | - |  | Granada CF | 2 | : | 1 |
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| Oct 16 • 20:00 | Elche CF | | - | | Córdoba CF | 1 | : | 4 |
| Oct 17 • 17:00 | CD Ebro | | - | | Lleida CF | 2 | : | 1 |
| Oct 17 • 20:00 | CD Lugo | | - | | AD Alcorcón | 1 | : | 0 |
| Oct 17 • 20:15 | UD Mutilvera | | - | | CF Villanovense | 1 | : | 3 |
| Oct 17 • 20:30 | UE Sant Andreu | | - | | CD Calahorra | 1 | : | 0 |
| Oct 17 • 20:30 | Racing Santander | | - | | UD Logroñés | 1 | : | 0 |
| Oct 17 • 20:45 | UD Melilla | | - | | Ontinyent CF | 2 | : | 0 |
| Oct 17 • 20:45 | Lorca FC | | - | | Cultural Leonesa | 0 | : | 3 |
| Oct 17 • 21:00 | Real Zaragoza | | - | | Cádiz CF | 0 | : | 1 |
| Oct 18 • 20:00 | Rayo Majadahonda | | - | | Sporting de Gijon | 1 | : | 1 |
| Oct 18 • 21:00 | UD Almeria | | - | | CF Reus Deportiu | 3 | : | 1 |
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| Oct 30 • 19:30 | CD Ebro | | - |  | Valencia CF | 1 | : | 2 |
| Oct 30 • 19:30 | CD Lugo | | - |  | Levante UD | 1 | : | 1 |
| Oct 30 • 20:30 | CD Leganés |  | - |  | Rayo Vallecano | 2 | : | 2 |
| Oct 30 • 21:30 | UE Sant Andreu | | - |  | Atlético Madrid | 0 | : | 1 |
| Oct 31 • 19:30 | UD Melilla | | - |  | Real Madrid | 0 | : | 4 |
| Oct 31 • 20:30 | Deportivo Alavés |  | - |  | Girona FC | 2 | : | 2 |
| Oct 31 • 20:30 | Córdoba CF | | - |  | Getafe CF | 1 | : | 2 |
| Oct 31 • 20:30 | RCD Mallorca | | - |  | Real Valladolid | 1 | : | 2 |
| Oct 31 • 21:30 | Cultural Leonesa | | - |  | FC Barcelona | 0 | : | 1 |
| Nov 01 • 12:00 | Sporting de Gijon | | - |  | SD Eibar | 2 | : | 0 |
| Nov 01 • 16:15 | Celta de Vigo |  | - |  | Real Sociedad | 1 | : | 1 |
| Nov 01 • 16:15 | CF Villanovense | | - |  | Sevilla FC | 0 | : | 0 |
| Nov 01 • 18:30 | UD Almeria | | - |  | Villarreal CF | 3 | : | 3 |
| Nov 01 • 18:30 | Cádiz CF | | - |  | RCD Espanyol | 2 | : | 1 |
| Nov 01 • 20:45 | Racing Santander | | - |  | Real Betis | 0 | : | 1 |
| Nov 28 • 20:45 | Athletic Bilbao |  | - |  | SD Huesca | 4 | : | 0 |
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| Dec 04 • 19:30 | Getafe CF | | - | | Córdoba CF | 5 | : | 1 |
| Dec 04 • 19:30 | Valencia CF | | - | | CD Ebro | 1 | : | 0 |
| Dec 04 • 20:30 | Rayo Vallecano | | - | | CD Leganés | 0 | : | 1 |
| Dec 04 • 21:30 | RCD Espanyol | | - | | Cádiz CF | 1 | : | 0 |
| Dec 05 • 19:30 | Atlético Madrid | | - | | UE Sant Andreu | 4 | : | 0 |
| Dec 05 • 19:30 | Girona FC | | - | | Deportivo Alavés | 2 | : | 1 |
| Dec 05 • 20:30 | Real Sociedad | | - | | Celta de Vigo | 2 | : | 0 |
| Dec 05 • 20:30 | Sevilla FC | | - | | CF Villanovense | 1 | : | 0 |
| Dec 05 • 20:30 | Villarreal CF | | - | | UD Almeria | 8 | : | 0 |
| Dec 05 • 21:30 | FC Barcelona | | - | | Cultural Leonesa | 4 | : | 1 |
| Dec 05 • 21:30 | Real Valladolid | | - | | RCD Mallorca | 2 | : | 1 |
| Dec 06 • 12:00 | Levante UD | | - | | CD Lugo | 2 | : | 0 |
| Dec 06 • 16:15 | Real Madrid | | - | | UD Melilla | 6 | : | 1 |
| Dec 06 • 18:30 | SD Eibar | | - | | Sporting de Gijon | 2 | : | 2 |
| Dec 06 • 18:30 | SD Huesca | | - | | Athletic Bilbao | 0 | : | 4 |
| Dec 06 • 20:45 | Real Betis | | - | | Racing Santander | 4 | : | 0 |
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| Jan 08 • 21:30 | Sporting de Gijon | | - | | Valencia CF | 2 | : | 1 |
| Jan 09 • 19:30 | Girona FC | | - | | Atlético Madrid | 1 | : | 1 |
| Jan 09 • 20:30 | Getafe CF | | - | | Real Valladolid | 1 | : | 0 |
| Jan 09 • 20:30 | Villarreal CF | | - | | RCD Espanyol | 2 | : | 2 |
| Jan 09 • 21:30 | Real Madrid | | - | | CD Leganés | 3 | : | 0 |
| Jan 10 • 19:30 | Athletic Bilbao | | - | | Sevilla FC | 1 | : | 3 |
| Jan 10 • 20:30 | Real Betis | | - | | Real Sociedad | 0 | : | 0 |
| Jan 10 • 21:30 | Levante UD | | - | | FC Barcelona | 2 | : | 1 |
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| Jan 15 • 19:30 | Real Valladolid | | - | | Getafe CF | 1 | : | 1 |
| Jan 15 • 21:30 | Valencia CF | | - | | Sporting de Gijon | 3 | : | 0 |
| Jan 16 • 19:30 | Atlético Madrid | | - | | Girona FC | 3 | : | 3 |
| Jan 16 • 20:30 | Sevilla FC | | - | | Athletic Bilbao | 0 | : | 1 |
| Jan 16 • 21:30 | CD Leganés | | - | | Real Madrid | 1 | : | 0 |
| Jan 17 • 19:30 | Real Sociedad | | - | | Real Betis | 2 | : | 2 |
| Jan 17 • 20:30 | RCD Espanyol | | - | | Villarreal CF | 3 | : | 1 |
| Jan 17 • 21:30 | FC Barcelona | | - | | Levante UD | 3 | : | 0 |
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| Jan 22 • 21:30 | Getafe CF | | - | | Valencia CF | 1 | : | 0 |
| Jan 23 • 21:30 | Sevilla FC | | - | | FC Barcelona | 2 | : | 0 |
| Jan 24 • 19:30 | RCD Espanyol | | - | | Real Betis | 1 | : | 1 |
| Jan 24 • 21:30 | Real Madrid | | - | | Girona FC | 4 | : | 2 |
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| Jan 29 • 21:30 | Valencia CF | | - | | Getafe CF | 3 | : | 1 |
| Jan 30 • 19:30 | Real Betis | | - | | RCD Espanyol | 3 | : | 1 |
| Jan 30 • 21:30 | FC Barcelona | | - | | Sevilla FC | 6 | : | 1 |
| Jan 31 • 21:30 | Girona FC | | - | | Real Madrid | 1 | : | 3 |
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| Feb 06 • 21:00 | FC Barcelona | | - | | Real Madrid | 1 | : | 1 |
| Feb 07 • 21:00 | Real Betis | | - | | Valencia CF | 2 | : | 2 |
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| Feb 27 • 21:00 | Real Madrid | | - | | FC Barcelona | 0 | : | 3 |
| Feb 28 • 21:00 | Valencia CF | | - | | Real Betis | 1 | : | 0 |
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| May 25 • 21:00 | FC Barcelona | | - | | Valencia CF | 1 | : | 2 |
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