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| Oct 28 • 11:00 | Nikoloz Basilashvili |  | - |  | Radu Albot | 0 | : | 2 |
| Oct 28 • 11:00 | Marin Čilić |  | - |  | Hubert Hurkacz | 2 | : | 0 |
| Oct 28 • 12:30 | Borna Ćorić | | - |  | Fernando Verdasco | 1 | : | 2 |
| Oct 28 • 12:30 | Jan-Lennard Struff |  | - |  | Yoshihito Nishioka | 2 | : | 1 |
| Oct 28 • 14:35 | Cameron Norrie |  | - |  | Milos Raonic | 0 | : | 2 |
| Oct 28 • 15:00 | Jérémy Chardy |  | - |  | Sam Querrey | 2 | : | 1 |
| Oct 28 • 16:00 | Pablo Cuevas |  | - |  | Cristian Garín | 0 | : | 2 |
| Oct 28 • 17:15 | Benoît Paire | | - |  | Damir Džumhur | 2 | : | 0 |
| Oct 28 • 19:30 | Andrey Rublev |  | - | | Jo-Wilfried Tsonga | 1 | : | 2 |
| Oct 28 • 22:30 | Casper Ruud |  | - | | Adrian Mannarino | 0 | : | 2 |
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| Oct 29 • 11:00 | Dušan Lajović |  | - | | Corentin Moutet | 1 | : | 2 |
| Oct 29 • 11:00 | Frances Tiafoe | | - | | Taylor Harry Fritz | 1 | : | 2 |
| Oct 29 • 13:30 | Laslo Djere | | - |  | Alex De Minaur | 0 | : | 2 |
| Oct 29 • 14:00 | Kyle Edmund | | - |  | Ričardas Berankis | 2 | : | 0 |
| Oct 29 • 15:20 | Gilles Simon | | - | | Denis Shapovalov | 0 | : | 0 |
| Oct 29 • 16:30 | Grigor Dimitrov |  | - | | Ugo Humbert | 2 | : | 1 |
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| Oct 29 • 12:30 | Karen Khachanov | | - | | Jan-Lennard Struff | 1 | : | 2 |
| Oct 29 • 16:30 | Radu Albot | | - |  | Andreas Seppi | 2 | : | 0 |
| Oct 29 • 19:30 | Daniil Medvedev | | - | | Jérémy Chardy | 1 | : | 2 |
| Oct 29 • 21:00 | Alexander Zverev | | - | | Fernando Verdasco | 2 | : | 0 |
| Oct 30 • 11:00 | Milos Raonic | | - |  | Dominic Thiem | 1 | : | 2 |
| Oct 30 • 12:40 | Cristian Garín | | - | | John Isner | 2 | : | 0 |
| Oct 30 • 12:40 | Denis Shapovalov | | - | | Fabio Fognini | 2 | : | 1 |
| Oct 30 • 14:00 | Taylor Harry Fritz | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
| Oct 30 • 14:10 | David Goffin |  | - | | Grigor Dimitrov | 0 | : | 2 |
| Oct 30 • 15:10 | Roberto Bautista-Agut | | - | | Alex De Minaur | 0 | : | 2 |
| Oct 30 • 15:30 | Gaël Monfils | | - | | Benoît Paire | 2 | : | 0 |
| Oct 30 • 15:40 | Stanislas Wawrinka |  | - | | Marin Čilić | 2 | : | 0 |
| Oct 30 • 17:20 | Novak Djokovic | | - | | Corentin Moutet | 2 | : | 0 |
| Oct 30 • 18:20 | Kyle Edmund | | - |  | Diego Schwartzman | 2 | : | 0 |
| Oct 30 • 19:40 | Adrian Mannarino | | - | | Rafael Nadal | 0 | : | 2 |
| Oct 30 • 21:20 | Jo-Wilfried Tsonga | | - | | Matteo Berrettini | 2 | : | 0 |
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| Oct 31 • 11:00 | Jérémy Chardy | | - | | Cristian Garín | 1 | : | 2 |
| Oct 31 • 12:30 | Grigor Dimitrov | | - | | Dominic Thiem | 2 | : | 0 |
| Oct 31 • 14:00 | Alex De Minaur | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| Oct 31 • 15:00 | Novak Djokovic | | - | | Kyle Edmund | 2 | : | 0 |
| Oct 31 • 17:00 | Alexander Zverev | | - | | Denis Shapovalov | 1 | : | 2 |
| Oct 31 • 17:00 | Jan-Lennard Struff | | - | | Jo-Wilfried Tsonga | 1 | : | 2 |
| Oct 31 • 19:30 | Stanislas Wawrinka | | - | | Rafael Nadal | 0 | : | 2 |
| Oct 31 • 21:00 | Gaël Monfils | | - | | Radu Albot | 2 | : | 1 |
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| Nov 01 • 14:00 | Cristian Garín | | - | | Grigor Dimitrov | 0 | : | 2 |
| Nov 01 • 15:30 | Novak Djokovic | | - | | Stefanos Tsitsipas | 2 | : | 0 |
| Nov 01 • 19:30 | Denis Shapovalov | | - | | Gaël Monfils | 2 | : | 0 |
| Nov 01 • 21:00 | Jo-Wilfried Tsonga | | - | | Rafael Nadal | 0 | : | 2 |
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| Nov 02 • 14:00 | Novak Djokovic | | - | | Grigor Dimitrov | 2 | : | 0 |
| Nov 02 • 16:30 | Denis Shapovalov | | - | | Rafael Nadal | 0 | : | 0 |
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| Nov 03 • 15:00 | Novak Djokovic | | - | | Denis Shapovalov | 2 | : | 0 |
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