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| Sep 27 • 11:00 | Benjamin Bonzi |  | - |  | Emil Ruusuvuori | 3 | : | 1 |
| Sep 27 • 11:00 | Jannik Sinner |  | - |  | David Goffin | 3 | : | 0 |
| Sep 27 • 11:00 | Sebastian Korda |  | - | | Andreas Seppi | 3 | : | 1 |
| Sep 27 • 12:30 | Taylor Harry Fritz | | - |  | Tomáš Macháč | 3 | : | 2 |
| Sep 27 • 12:30 | Jurij Rodionov |  | - | | Jérémy Chardy | 3 | : | 2 |
| Sep 27 • 12:30 | Federico Coria |  | - |  | Jason Jung | 3 | : | 0 |
| Sep 27 • 12:30 | Elliot Benchetrit |  | - | | John Isner | 0 | : | 3 |
| Sep 27 • 12:30 | Daniel Evans |  | - |  | Kei Nishikori | 2 | : | 3 |
| Sep 27 • 12:30 | Pablo Andújar |  | - | | Stefano Travaglia | 0 | : | 3 |
| Sep 27 • 13:00 | Marco Cecchinato | | - |  | Alex De Minaur | 3 | : | 0 |
| Sep 27 • 15:40 | Borna Ćorić |  | - |  | Norbert Gombos | 1 | : | 3 |
| Sep 27 • 16:00 | Dominik Koepfer |  | - | | Antoine Hoang | 3 | : | 1 |
| Sep 27 • 16:30 | Benoît Paire | | - |  | Kwon Soon-woo | 3 | : | 0 |
| Sep 27 • 16:35 | Jordan Thompson | | - |  | Radu Albot | 0 | : | 3 |
| Sep 27 • 16:55 | Federico Delbonis | | - | | Juan Ignacio Londero | 2 | : | 3 |
| Sep 27 • 17:20 | Stanislas Wawrinka |  | - | | Andy Murray | 3 | : | 0 |
| Sep 27 • 18:45 | Corentin Moutet | | - | | Lorenzo Giustino | 2 | : | 3 |
| Sep 27 • 19:10 | Miomir Kecmanovic |  | - | | Diego Schwartzman | 0 | : | 3 |
| Sep 27 • 19:40 | Alexander Zverev | | - | | Dennis Novak | 3 | : | 0 |
| Sep 28 • 11:00 | Hugo Gaston | | - | | Maxime Janvier | 3 | : | 0 |
| Sep 28 • 11:00 | Yoshihito Nishioka | | - |  | Felix Auger Aliassime | 3 | : | 0 |
| Sep 28 • 11:00 | Reilly Opelka | | - | | Jack Sock | 0 | : | 3 |
| Sep 28 • 11:00 | Michael Mmoh | | - | | Pierre-Hugues Herbert | 0 | : | 3 |
| Sep 28 • 11:00 | Fabio Fognini | | - |  | Mikhail Kukushkin | 1 | : | 3 |
| Sep 28 • 11:00 | Pedro Martínez | | - | | Aleksandar Vukic | 3 | : | 0 |
| Sep 28 • 12:30 | Emilio Gómez |  | - | | Lorenzo Sonego | 2 | : | 3 |
| Sep 28 • 12:30 | Tommy Paul | | - | | James Duckworth | 3 | : | 0 |
| Sep 28 • 12:30 | Marin Čilić | | - | | Dominic Thiem | 0 | : | 3 |
| Sep 28 • 12:30 | Steven Diez | | - | | Mackenzie McDonald | 1 | : | 3 |
| Sep 28 • 14:00 | Jiří Veselý | | - | | Liam Broady | 3 | : | 1 |
| Sep 28 • 14:00 | Gaël Monfils | | - | | Alexander Bublik | 1 | : | 3 |
| Sep 28 • 14:00 | Casper Ruud |  | - | | Yuichi Sugita | 3 | : | 0 |
| Sep 28 • 14:30 | Kamil Majchrzak |  | - |  | Karen Khachanov | 0 | : | 3 |
| Sep 28 • 14:30 | Guido Pella | | - | | Salvatore Caruso | 3 | : | 1 |
| Sep 28 • 14:30 | John Millman | | - | | Pablo Carreño Busta | 0 | : | 3 |
| Sep 28 • 14:30 | Jan-Lennard Struff | | - | | Frances Tiafoe | 3 | : | 2 |
| Sep 28 • 14:30 | Filip Krajinović | | - | | Nikola Milojević | 1 | : | 3 |
| Sep 28 • 14:30 | Aljaž Bedene |  | - | | Arthur Rinderknech | 3 | : | 1 |
| Sep 28 • 16:00 | Daniel Elahi Galán |  | - | | Cameron Norrie | 3 | : | 2 |
| Sep 28 • 16:00 | Tennys Sandgren | | - | | Hubert Hurkacz | 3 | : | 2 |
| Sep 28 • 16:00 | Daniel Altmaier | | - | | Feliciano López | 3 | : | 0 |
| Sep 28 • 16:00 | Daniil Medvedev | | - |  | Márton Fucsovics | 1 | : | 3 |
| Sep 28 • 16:00 | Adrian Mannarino | | - | | Albert Ramos-Viñolas | 0 | : | 3 |
| Sep 28 • 16:00 | Egor Gerasimov |  | - | | Rafael Nadal | 0 | : | 3 |
| Sep 29 • 11:00 | Cristian Garín |  | - | | Philipp Kohlschreiber | 3 | : | 1 |
| Sep 29 • 11:00 | Ugo Humbert | | - | | Marc Polmans | 1 | : | 3 |
| Sep 29 • 11:00 | Lloyd Harris |  | - | | Alexei Popyrin | 3 | : | 0 |
| Sep 29 • 11:00 | Vasek Pospisil | | - | | Matteo Berrettini | 0 | : | 3 |
| Sep 29 • 12:20 | Harold Mayot | | - | | Alejandro Davidovich Fokina | 0 | : | 3 |
| Sep 29 • 12:25 | Dušan Lajović | | - | | Gianluca Mager | 3 | : | 1 |
| Sep 29 • 13:00 | Sam Querrey | | - | | Andrey Rublev | 2 | : | 3 |
| Sep 29 • 13:15 | Hugo Dellien |  | - |  | Ričardas Berankis | 0 | : | 3 |
| Sep 29 • 13:15 | Laslo Djere | | - | | Kevin Anderson | 0 | : | 3 |
| Sep 29 • 14:00 | Quentin Halys | | - | | Marcos Giron | 2 | : | 3 |
| Sep 29 • 14:30 | Jaume Munar | | - |  | Stefanos Tsitsipas | 2 | : | 3 |
| Sep 29 • 14:50 | Steve Johnson | | - | | Roberto Carballés Baena | 0 | : | 3 |
| Sep 29 • 15:00 | Yasutaka Uchiyama | | - | | Attila Balazs | 0 | : | 3 |
| Sep 29 • 15:00 | Henri Laaksonen | | - |  | Pablo Cuevas | 1 | : | 3 |
| Sep 29 • 15:10 | Novak Djokovic | | - |  | Mikael Ymer | 3 | : | 0 |
| Sep 29 • 15:20 | Thiago Moura Monteiro |  | - |  | Nikoloz Basilashvili | 3 | : | 1 |
| Sep 29 • 16:10 | Roberto Bautista-Agut | | - | | Richard Gasquet | 3 | : | 0 |
| Sep 29 • 16:20 | Andrej Martin | | - |  | João Sousa | 3 | : | 0 |
| Sep 29 • 17:00 | Denis Shapovalov | | - | | Gilles Simon | 3 | : | 1 |
| Sep 29 • 17:00 | Gregoire Barrere | | - |  | Grigor Dimitrov | 0 | : | 3 |
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| Sep 30 • 11:00 | Radu Albot | | - | | Taylor Harry Fritz | 0 | : | 3 |
| Sep 30 • 11:00 | Stanislas Wawrinka | | - | | Dominik Koepfer | 3 | : | 1 |
| Sep 30 • 11:00 | Hugo Gaston | | - | | Yoshihito Nishioka | 3 | : | 1 |
| Sep 30 • 11:00 | Sebastian Korda | | - | | John Isner | 3 | : | 1 |
| Sep 30 • 12:30 | Lorenzo Giustino | | - | | Diego Schwartzman | 0 | : | 3 |
| Sep 30 • 12:30 | Norbert Gombos | | - | | Jurij Rodionov | 3 | : | 1 |
| Sep 30 • 13:00 | Jack Sock | | - | | Dominic Thiem | 0 | : | 3 |
| Sep 30 • 14:00 | Alexander Bublik | | - | | Lorenzo Sonego | 0 | : | 3 |
| Sep 30 • 14:00 | Casper Ruud | | - | | Tommy Paul | 3 | : | 2 |
| Sep 30 • 14:00 | Juan Ignacio Londero | | - | | Marco Cecchinato | 1 | : | 3 |
| Sep 30 • 14:00 | Mikhail Kukushkin | | - | | Pedro Martínez | 0 | : | 3 |
| Sep 30 • 14:00 | Kei Nishikori | | - | | Stefano Travaglia | 2 | : | 3 |
| Sep 30 • 14:00 | Mackenzie McDonald | | - | | Rafael Nadal | 0 | : | 3 |
| Sep 30 • 14:30 | Benoît Paire | | - | | Federico Coria | 1 | : | 3 |
| Sep 30 • 16:00 | Alexander Zverev | | - | | Pierre-Hugues Herbert | 3 | : | 2 |
| Sep 30 • 16:00 | Benjamin Bonzi | | - | | Jannik Sinner | 0 | : | 3 |
| Oct 01 • 11:00 | Cristian Garín | | - | | Marc Polmans | 3 | : | 1 |
| Oct 01 • 11:00 | Jiří Veselý | | - | | Karen Khachanov | 1 | : | 3 |
| Oct 01 • 11:00 | Márton Fucsovics | | - | | Albert Ramos-Viñolas | 3 | : | 0 |
| Oct 01 • 11:00 | Marcos Giron | | - | | Thiago Moura Monteiro | 0 | : | 3 |
| Oct 01 • 11:00 | Denis Shapovalov | | - | | Roberto Carballés Baena | 2 | : | 3 |
| Oct 01 • 12:30 | Jan-Lennard Struff | | - | | Daniel Altmaier | 0 | : | 3 |
| Oct 01 • 12:30 | Andrej Martin | | - | | Grigor Dimitrov | 0 | : | 3 |
| Oct 01 • 14:00 | Novak Djokovic | | - | | Ričardas Berankis | 3 | : | 0 |
| Oct 01 • 14:15 | Guido Pella | | - | | Pablo Carreño Busta | 0 | : | 3 |
| Oct 01 • 14:30 | Daniel Elahi Galán | | - | | Tennys Sandgren | 3 | : | 0 |
| Oct 01 • 14:50 | Nikola Milojević | | - | | Aljaž Bedene | 1 | : | 3 |
| Oct 01 • 16:00 | Pablo Cuevas | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Oct 01 • 17:00 | Roberto Bautista-Agut | | - | | Attila Balazs | 3 | : | 0 |
| Oct 01 • 17:00 | Alejandro Davidovich Fokina | | - | | Andrey Rublev | 1 | : | 3 |
| Oct 01 • 17:10 | Dušan Lajović | | - | | Kevin Anderson | 2 | : | 3 |
| Oct 01 • 18:00 | Lloyd Harris | | - | | Matteo Berrettini | 1 | : | 3 |
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| Oct 02 • 11:00 | Casper Ruud | | - | | Dominic Thiem | 0 | : | 3 |
| Oct 02 • 12:30 | Lorenzo Sonego | | - | | Taylor Harry Fritz | 3 | : | 0 |
| Oct 02 • 12:30 | Stanislas Wawrinka | | - | | Hugo Gaston | 2 | : | 3 |
| Oct 02 • 12:30 | Pedro Martínez | | - | | Sebastian Korda | 0 | : | 3 |
| Oct 02 • 14:20 | Federico Coria | | - | | Jannik Sinner | 0 | : | 3 |
| Oct 02 • 15:00 | Diego Schwartzman | | - | | Norbert Gombos | 3 | : | 0 |
| Oct 02 • 15:25 | Alexander Zverev | | - | | Marco Cecchinato | 3 | : | 0 |
| Oct 02 • 16:30 | Stefano Travaglia | | - | | Rafael Nadal | 0 | : | 3 |
| Oct 03 • 11:00 | Roberto Bautista-Agut | | - | | Pablo Carreño Busta | 1 | : | 3 |
| Oct 03 • 11:00 | Daniel Altmaier | | - | | Matteo Berrettini | 3 | : | 0 |
| Oct 03 • 11:00 | Kevin Anderson | | - | | Andrey Rublev | 0 | : | 3 |
| Oct 03 • 12:30 | Márton Fucsovics | | - | | Thiago Moura Monteiro | 3 | : | 0 |
| Oct 03 • 13:00 | Aljaž Bedene | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| Oct 03 • 14:00 | Cristian Garín | | - | | Karen Khachanov | 1 | : | 3 |
| Oct 03 • 14:30 | Roberto Carballés Baena | | - | | Grigor Dimitrov | 0 | : | 2 |
| Oct 03 • 16:45 | Novak Djokovic | | - | | Daniel Elahi Galán | 3 | : | 0 |
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| Oct 04 • 12:30 | Alexander Zverev | | - | | Jannik Sinner | 1 | : | 3 |
| Oct 04 • 12:30 | Sebastian Korda | | - | | Rafael Nadal | 0 | : | 3 |
| Oct 04 • 14:30 | Lorenzo Sonego | | - | | Diego Schwartzman | 0 | : | 3 |
| Oct 04 • 16:00 | Hugo Gaston | | - | | Dominic Thiem | 2 | : | 3 |
| Oct 05 • 11:00 | Márton Fucsovics | | - | | Andrey Rublev | 1 | : | 3 |
| Oct 05 • 12:30 | Grigor Dimitrov | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Oct 05 • 14:55 | Novak Djokovic | | - | | Karen Khachanov | 3 | : | 0 |
| Oct 05 • 16:00 | Pablo Carreño Busta | | - | | Daniel Altmaier | 3 | : | 0 |
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| Oct 06 • 14:20 | Diego Schwartzman | | - | | Dominic Thiem | 3 | : | 2 |
| Oct 06 • 17:50 | Jannik Sinner | | - | | Rafael Nadal | 0 | : | 3 |
| Oct 07 • 15:00 | Andrey Rublev | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Oct 07 • 17:30 | Novak Djokovic | | - | | Pablo Carreño Busta | 3 | : | 1 |
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| Oct 09 • 14:50 | Diego Schwartzman | | - | | Rafael Nadal | 0 | : | 3 |
| Oct 09 • 17:00 | Novak Djokovic | | - | | Stefanos Tsitsipas | 3 | : | 2 |
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| Oct 11 • 15:00 | Novak Djokovic | | - | | Rafael Nadal | 0 | : | 3 |
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