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| Sep 21 • 10:30 | Taylor Harry Fritz |  | - |  | Pablo Cuevas | 0 | : | 2 |
| Sep 21 • 12:00 | Jiří Veselý |  | - |  | Gilles Simon | 2 | : | 0 |
| Sep 21 • 13:30 | Tommy Paul | | - |  | Kevin Anderson | 2 | : | 1 |
| Sep 21 • 15:00 | Tennys Sandgren | | - |  | Andrey Rublev | 0 | : | 2 |
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| Sep 22 • 10:00 | Cristian Garín |  | - |  | Kei Nishikori | 2 | : | 0 |
| Sep 22 • 10:30 | Roberto Bautista-Agut |  | - |  | Nikoloz Basilashvili | 2 | : | 0 |
| Sep 22 • 11:30 | Yoshihito Nishioka | | - |  | Dominik Koepfer | 1 | : | 2 |
| Sep 22 • 12:30 | Yannick Hanfmann | | - | | Gaël Monfils | 2 | : | 0 |
| Sep 22 • 13:15 | Lorenzo Sonego |  | - |  | Felix Auger Aliassime | 0 | : | 2 |
| Sep 22 • 14:00 | Philipp Kohlschreiber | | - | | Fabio Fognini | 1 | : | 2 |
| Sep 22 • 15:30 | Karen Khachanov | | - | | Jan-Lennard Struff | 2 | : | 1 |
| Sep 22 • 16:00 | Alexander Bublik |  | - | | Albert Ramos-Viñolas | 2 | : | 0 |
| Sep 22 • 17:00 | Dušan Lajović |  | - | | Adrian Mannarino | 2 | : | 0 |
| Sep 22 • 18:00 | Daniil Medvedev | | - | | Ugo Humbert | 0 | : | 2 |
| Sep 23 • 10:30 | Casper Ruud |  | - | | Benoît Paire | 1 | : | 0 |
| Sep 23 • 13:30 | Daniel Evans |  | - |  | Stefanos Tsitsipas | 0 | : | 2 |
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| Sep 23 • 12:00 | Cristian Garín | | - | | Yannick Hanfmann | 2 | : | 0 |
| Sep 23 • 14:00 | Tommy Paul | | - | | Andrey Rublev | 1 | : | 2 |
| Sep 23 • 15:10 | Alexander Bublik | | - | | Felix Auger Aliassime | 2 | : | 0 |
| Sep 23 • 18:30 | Roberto Bautista-Agut | | - | | Dominik Koepfer | 2 | : | 1 |
| Sep 24 • 12:30 | Karen Khachanov | | - | | Dušan Lajović | 0 | : | 2 |
| Sep 24 • 14:00 | Pablo Cuevas | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| Sep 24 • 15:30 | Ugo Humbert | | - | | Jiří Veselý | 2 | : | 0 |
| Sep 24 • 18:30 | Casper Ruud | | - | | Fabio Fognini | 2 | : | 0 |
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| Sep 25 • 11:30 | Roberto Bautista-Agut | | - | | Andrey Rublev | 0 | : | 2 |
| Sep 25 • 13:30 | Dušan Lajović | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| Sep 25 • 15:00 | Ugo Humbert | | - | | Casper Ruud | 1 | : | 2 |
| Sep 25 • 18:30 | Alexander Bublik | | - | | Cristian Garín | 1 | : | 2 |
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| Sep 26 • 13:30 | Casper Ruud | | - | | Andrey Rublev | 0 | : | 2 |
| Sep 26 • 15:30 | Cristian Garín | | - | | Stefanos Tsitsipas | 1 | : | 2 |
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| Sep 27 • 12:00 | Andrey Rublev | | - | | Stefanos Tsitsipas | 2 | : | 1 |
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