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| May 28 • 11:00 | Sebastian Ofner |  | - |  | Maxime Cressy | 3 | : | 0 |
| May 28 • 11:00 | Pedro Martínez |  | - |  | Tallon Griekspoor | 2 | : | 3 |
| May 28 • 11:00 | David Goffin |  | - |  | Hubert Hurkacz | 2 | : | 3 |
| May 28 • 11:00 | Karen Khachanov |  | - |  | Constant Lestienne | 3 | : | 2 |
| May 28 • 11:00 | Patrick Kypson | | - |  | Radu Albot | 1 | : | 3 |
| May 28 • 12:30 | Jiří Veselý |  | - |  | Stefanos Tsitsipas | 1 | : | 3 |
| May 28 • 12:30 | Márton Fucsovics |  | - | | Hugo Grenier | 3 | : | 1 |
| May 28 • 12:30 | Thanasi Kokkinakis |  | - |  | Daniel Evans | 3 | : | 0 |
| May 28 • 13:30 | Jason Kubler | | - |  | Facundo Díaz Acosta | 3 | : | 2 |
| May 28 • 13:40 | John Isner | | - |  | Nuno Borges | 2 | : | 3 |
| May 28 • 13:45 | Mackenzie McDonald | | - | | Sebastian Korda | 0 | : | 3 |
| May 28 • 14:45 | Matteo Arnaldi |  | - |  | Daniel Elahi Galán | 3 | : | 1 |
| May 28 • 15:45 | Roberto Carballés Baena | | - | | Emilio Nava | 3 | : | 0 |
| May 28 • 16:45 | Lorenzo Musetti | | - |  | Mikael Ymer | 3 | : | 0 |
| May 28 • 17:30 | Arthur Cazaux | | - | | Corentin Moutet | 1 | : | 3 |
| May 28 • 17:35 | Laslo Djere |  | - | | Andrey Rublev | 1 | : | 3 |
| May 28 • 17:55 | Ben Shelton | | - | | Lorenzo Sonego | 1 | : | 3 |
| May 28 • 18:45 | Alexander Shevchenko | | - |  | Oscar Otte | 3 | : | 1 |
| May 28 • 19:00 | Adrian Mannarino | | - | | Ugo Humbert | 0 | : | 3 |
| May 28 • 19:30 | Lucas Pouille | | - | | Jurij Rodionov | 3 | : | 0 |
| May 29 • 11:00 | Brandon Nakashima | | - |  | Denis Shapovalov | 2 | : | 3 |
| May 29 • 11:00 | Benoît Paire | | - | | Cameron Norrie | 2 | : | 3 |
| May 29 • 11:00 | Bernabe Zapata Miralles | | - | | Diego Schwartzman | 2 | : | 3 |
| May 29 • 11:00 | Shang Juncheng |  | - |  | Juan Pablo Varillas | 2 | : | 3 |
| May 29 • 11:00 | Ilya Ivashka |  | - | | Alex De Minaur | 1 | : | 3 |
| May 29 • 12:30 | Jack Draper | | - | | Tomás Martín Etcheverry | 0 | : | 1 |
| May 29 • 12:50 | Alexei Popyrin | | - | | Aslan Karatsev | 1 | : | 3 |
| May 29 • 12:55 | Roberto Bautista-Agut | | - | | Yibing Wu | 3 | : | 0 |
| May 29 • 13:00 | Felix Auger Aliassime | | - | | Fabio Fognini | 0 | : | 3 |
| May 29 • 13:15 | Stanislas Wawrinka |  | - | | Albert Ramos-Viñolas | 3 | : | 2 |
| May 29 • 13:35 | Christopher O'Connell | | - |  | Taro Daniel | 0 | : | 3 |
| May 29 • 14:00 | Novak Djokovic | | - | | Aleksandar Kovacevic | 3 | : | 0 |
| May 29 • 14:40 | Botic van de Zandschulp | | - | | Thiago Agustín Tirante | 1 | : | 3 |
| May 29 • 14:55 | Borna Ćorić |  | - | | Federico Coria | 3 | : | 1 |
| May 29 • 15:25 | Hamad Medjedovic | | - | | Marcos Giron | 1 | : | 3 |
| May 29 • 15:30 | Dominic Thiem | | - | | Pedro Cachín | 2 | : | 3 |
| May 29 • 17:15 | Carlos Alcaraz | | - | | Flavio Cobolli | 3 | : | 0 |
| May 29 • 17:15 | Arthur Fils | | - | | Alejandro Davidovich Fokina | 1 | : | 3 |
| May 29 • 17:20 | Jiří Lehečka | | - | | Jan-Lennard Struff | 3 | : | 2 |
| May 29 • 17:40 | Daniel Altmaier | | - | | Marc-Andrea Hüsler | 3 | : | 0 |
| May 29 • 17:45 | Filip Krajinović | | - | | Frances Tiafoe | 0 | : | 3 |
| May 29 • 18:10 | Zhang Zhizhen | | - | | Dušan Lajović | 1 | : | 0 |
| May 29 • 19:40 | Luca Van Assche | | - | | Marco Cecchinato | 3 | : | 0 |
| May 29 • 20:15 | Jannik Sinner | | - | | Alexandre Muller | 3 | : | 0 |
| May 30 • 11:00 | Giovanni Mpetshi Perricard | | - | | Genaro Alberto Olivieri | 2 | : | 3 |
| May 30 • 11:00 | Andrea Vavassori | | - | | Miomir Kecmanovic | 3 | : | 2 |
| May 30 • 11:00 | Tommy Paul | | - | | Dominic Stricker | 3 | : | 0 |
| May 30 • 11:00 | Nicolás Jarry |  | - |  | Hugo Dellien | 3 | : | 0 |
| May 30 • 11:00 | Elias Ymer | | - |  | Casper Ruud | 0 | : | 3 |
| May 30 • 11:00 | Yoshihito Nishioka | | - | | Jeffrey John Wolf | 3 | : | 2 |
| May 30 • 11:20 | Max Purcell | | - | | Jordan Thompson | 3 | : | 1 |
| May 30 • 12:15 | Alexander Bublik |  | - | | Giulio Zeppieri | 2 | : | 3 |
| May 30 • 12:15 | Alexander Zverev | | - |  | Lloyd Harris | 3 | : | 0 |
| May 30 • 12:15 | Hugo Gaston | | - |  | Alex Molcan | 0 | : | 3 |
| May 30 • 13:00 | Thiago Seyboth Wild |  | - | | Daniil Medvedev | 3 | : | 2 |
| May 30 • 14:45 | Emil Ruusuvuori |  | - | | Gregoire Barrere | 3 | : | 2 |
| May 30 • 14:50 | Holger Rune |  | - | | Christopher Eubanks | 3 | : | 1 |
| May 30 • 16:00 | Francisco Cerundolo | | - | | Jaume Munar | 3 | : | 1 |
| May 30 • 17:10 | Quentin Halys | | - | | Guido Pella | 2 | : | 3 |
| May 30 • 17:30 | Richard Gasquet | | - | | Arthur Rinderknech | 1 | : | 3 |
| May 30 • 17:50 | Michael Mmoh | | - | | Taylor Harry Fritz | 0 | : | 3 |
| May 30 • 18:10 | Timofey Skatov | | - |  | Grigor Dimitrov | 0 | : | 3 |
| May 30 • 18:20 | Thiago Moura Monteiro | | - | | Yannick Hanfmann | 2 | : | 3 |
| May 30 • 20:15 | Gaël Monfils | | - | | Sebastián Báez | 3 | : | 2 |
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| May 31 • 11:00 | Fabio Fognini | | - | | Jason Kubler | 3 | : | 0 |
| May 31 • 11:00 | Sebastian Ofner | | - | | Sebastian Korda | 3 | : | 0 |
| May 31 • 11:00 | Roberto Carballés Baena | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| May 31 • 13:10 | Lorenzo Sonego | | - | | Ugo Humbert | 3 | : | 0 |
| May 31 • 13:15 | Stanislas Wawrinka | | - | | Thanasi Kokkinakis | 2 | : | 3 |
| May 31 • 14:00 | Diego Schwartzman | | - | | Nuno Borges | 3 | : | 0 |
| May 31 • 14:40 | Matteo Arnaldi | | - | | Denis Shapovalov | 1 | : | 3 |
| May 31 • 16:15 | Roberto Bautista-Agut | | - | | Juan Pablo Varillas | 2 | : | 3 |
| May 31 • 16:20 | Carlos Alcaraz | | - | | Taro Daniel | 3 | : | 1 |
| May 31 • 16:30 | Karen Khachanov | | - | | Radu Albot | 3 | : | 0 |
| May 31 • 16:55 | Tallon Griekspoor | | - | | Hubert Hurkacz | 2 | : | 3 |
| May 31 • 17:35 | Luca Van Assche | | - | | Alejandro Davidovich Fokina | 0 | : | 3 |
| May 31 • 17:40 | Lucas Pouille | | - | | Cameron Norrie | 0 | : | 3 |
| May 31 • 18:00 | Corentin Moutet | | - | | Andrey Rublev | 1 | : | 3 |
| May 31 • 19:30 | Lorenzo Musetti | | - | | Alexander Shevchenko | 3 | : | 0 |
| May 31 • 20:15 | Novak Djokovic | | - | | Márton Fucsovics | 3 | : | 0 |
| Jun 01 • 11:00 | Borna Ćorić | | - | | Pedro Cachín | 3 | : | 2 |
| Jun 01 • 11:00 | Tomás Martín Etcheverry | | - | | Alex De Minaur | 3 | : | 0 |
| Jun 01 • 11:45 | Giulio Zeppieri | | - | | Casper Ruud | 1 | : | 3 |
| Jun 01 • 12:30 | Jannik Sinner | | - | | Daniel Altmaier | 2 | : | 3 |
| Jun 01 • 12:30 | Emil Ruusuvuori | | - | | Grigor Dimitrov | 0 | : | 3 |
| Jun 01 • 12:30 | Yoshihito Nishioka | | - | | Max Purcell | 3 | : | 1 |
| Jun 01 • 14:00 | Thiago Agustín Tirante | | - | | Zhang Zhizhen | 0 | : | 3 |
| Jun 01 • 14:00 | Aslan Karatsev | | - | | Frances Tiafoe | 1 | : | 3 |
| Jun 01 • 14:00 | Guido Pella | | - | | Thiago Seyboth Wild | 1 | : | 3 |
| Jun 01 • 14:30 | Genaro Alberto Olivieri | | - | | Andrea Vavassori | 3 | : | 1 |
| Jun 01 • 14:30 | Tommy Paul | | - | | Nicolás Jarry | 1 | : | 3 |
| Jun 01 • 14:30 | Marcos Giron | | - | | Jiří Lehečka | 3 | : | 0 |
| Jun 01 • 16:00 | Francisco Cerundolo | | - | | Yannick Hanfmann | 3 | : | 0 |
| Jun 01 • 16:00 | Arthur Rinderknech | | - | | Taylor Harry Fritz | 1 | : | 3 |
| Jun 01 • 17:00 | Alexander Zverev | | - | | Alex Molcan | 3 | : | 0 |
| Jun 01 • 20:15 | Holger Rune | | - | | Gaël Monfils | 0 | : | 0 |
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| Jun 02 • 11:00 | Karen Khachanov | | - | | Thanasi Kokkinakis | 3 | : | 1 |
| Jun 02 • 12:30 | Lorenzo Sonego | | - | | Andrey Rublev | 3 | : | 2 |
| Jun 02 • 14:00 | Fabio Fognini | | - | | Sebastian Ofner | 2 | : | 3 |
| Jun 02 • 14:30 | Lorenzo Musetti | | - | | Cameron Norrie | 3 | : | 0 |
| Jun 02 • 14:45 | Novak Djokovic | | - | | Alejandro Davidovich Fokina | 3 | : | 0 |
| Jun 02 • 16:00 | Diego Schwartzman | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Jun 02 • 16:00 | Juan Pablo Varillas | | - | | Hubert Hurkacz | 3 | : | 2 |
| Jun 02 • 16:45 | Carlos Alcaraz | | - | | Denis Shapovalov | 3 | : | 0 |
| Jun 03 • 11:00 | Zhang Zhizhen | | - | | Casper Ruud | 1 | : | 3 |
| Jun 03 • 11:00 | Yoshihito Nishioka | | - | | Thiago Seyboth Wild | 3 | : | 2 |
| Jun 03 • 12:30 | Nicolás Jarry | | - | | Marcos Giron | 3 | : | 1 |
| Jun 03 • 12:30 | Borna Ćorić | | - | | Tomás Martín Etcheverry | 0 | : | 3 |
| Jun 03 • 13:15 | Holger Rune | | - | | Genaro Alberto Olivieri | 3 | : | 0 |
| Jun 03 • 14:30 | Francisco Cerundolo | | - | | Taylor Harry Fritz | 3 | : | 1 |
| Jun 03 • 16:00 | Daniel Altmaier | | - | | Grigor Dimitrov | 0 | : | 3 |
| Jun 03 • 20:15 | Alexander Zverev | | - | | Frances Tiafoe | 3 | : | 1 |
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| Jun 04 • 11:00 | Karen Khachanov | | - | | Lorenzo Sonego | 3 | : | 1 |
| Jun 04 • 12:30 | Novak Djokovic | | - | | Juan Pablo Varillas | 3 | : | 0 |
| Jun 04 • 14:30 | Carlos Alcaraz | | - | | Lorenzo Musetti | 3 | : | 0 |
| Jun 04 • 16:30 | Sebastian Ofner | | - | | Stefanos Tsitsipas | 0 | : | 3 |
| Jun 05 • 12:15 | Nicolás Jarry | | - | | Casper Ruud | 0 | : | 3 |
| Jun 05 • 14:30 | Holger Rune | | - | | Francisco Cerundolo | 3 | : | 2 |
| Jun 05 • 17:30 | Tomás Martín Etcheverry | | - | | Yoshihito Nishioka | 3 | : | 0 |
| Jun 05 • 20:15 | Grigor Dimitrov | | - | | Alexander Zverev | 0 | : | 3 |
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| Jun 06 • 13:45 | Novak Djokovic | | - | | Karen Khachanov | 3 | : | 1 |
| Jun 06 • 20:15 | Carlos Alcaraz | | - | | Stefanos Tsitsipas | 3 | : | 0 |
| Jun 07 • 15:00 | Alexander Zverev | | - | | Tomás Martín Etcheverry | 3 | : | 1 |
| Jun 07 • 20:15 | Holger Rune | | - | | Casper Ruud | 1 | : | 3 |
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| Jun 09 • 14:45 | Carlos Alcaraz | | - | | Novak Djokovic | 1 | : | 3 |
| Jun 09 • 17:30 | Casper Ruud | | - | | Alexander Zverev | 3 | : | 0 |
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| Jun 11 • 14:30 | Novak Djokovic | | - | | Casper Ruud | 3 | : | 0 |
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