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| Mar 06 • 20:00 | Thanasi Kokkinakis |  | - |  | Marcos Giron | 2 | : | 0 |
| Mar 06 • 20:00 | Christopher O'Connell | | - |  | Jack Draper | 2 | : | 1 |
| Mar 06 • 21:00 | Alexander Shevchenko |  | - |  | Dominik Koepfer | 2 | : | 1 |
| Mar 06 • 21:00 | Yannick Hanfmann | | - |  | Pedro Cachín | 2 | : | 1 |
| Mar 06 • 21:30 | Christopher Eubanks | | - | | Brandon Nakashima | 0 | : | 2 |
| Mar 06 • 21:30 | Luca Van Assche |  | - |  | Matteo Arnaldi | 0 | : | 2 |
| Mar 06 • 22:30 | Taro Daniel |  | - |  | Daniel Elahi Galán | 2 | : | 0 |
| Mar 06 • 22:30 | Fábián Marozsán |  | - |  | Jurij Rodionov | 2 | : | 0 |
| Mar 06 • 23:00 | Andy Murray | | - |  | David Goffin | 2 | : | 0 |
| Mar 06 • 23:00 | Dušan Lajović |  | - |  | Emil Ruusuvuori | 2 | : | 0 |
| Mar 07 • 00:00 | Lucas Pouille | | - | | Daniel Altmaier | 2 | : | 0 |
| Mar 07 • 00:00 | Constant Lestienne | | - | | Denis Kudla | 2 | : | 1 |
| Mar 07 • 20:00 | Shintaro Mochizuki | | - | | Aleksandar Vukic | 0 | : | 2 |
| Mar 07 • 20:00 | Lorenzo Sonego | | - | | Miomir Kecmanovic | 2 | : | 0 |
| Mar 07 • 20:00 | Stanislas Wawrinka |  | - |  | Tomáš Macháč | 1 | : | 2 |
| Mar 07 • 23:15 | Gaël Monfils | | - | | Max Purcell | 2 | : | 0 |
| Mar 07 • 23:15 | Roman Safiullin | | - | | Daniel Evans | 2 | : | 1 |
| Mar 07 • 23:15 | Jakub Mensik | | - |  | Hong Seong-chan | 2 | : | 0 |
| Mar 07 • 23:30 | Borna Ćorić |  | - | | Sebastian Ofner | 2 | : | 1 |
| Mar 07 • 23:55 | Thiago Seyboth Wild |  | - | | Jeffrey John Wolf | 2 | : | 0 |
| Mar 08 • 00:00 | Ethan Quinn | | - | | Patrick Kypson | 0 | : | 2 |
| Mar 08 • 00:00 | Pavel Kotov | | - |  | Alejandro Tabilo | 1 | : | 2 |
| Mar 08 • 00:35 | Alex Michelsen | | - |  | Jaume Munar | 2 | : | 0 |
| Mar 08 • 01:00 | Arthur Fils | | - |  | Nuno Borges | 2 | : | 0 |
| Mar 08 • 02:00 | Fabio Fognini | | - | | Bernabe Zapata Miralles | 2 | : | 1 |
| Mar 08 • 03:00 | Milos Raonic |  | - |  | Sumit Nagal | 2 | : | 0 |
| Mar 08 • 04:25 | Shang Juncheng |  | - | | Jordan Thompson | 2 | : | 0 |
| Mar 08 • 21:30 | Aleksandar Kovacevic | | - | | Zhang Zhizhen | 1 | : | 2 |
| Mar 08 • 21:30 | Hugo Grenier | | - | | Alexandre Muller | 0 | : | 2 |
| Mar 08 • 23:00 | Nicolas Moreno de Alboran | | - |  | Lukáš Klein | 0 | : | 2 |
| Mar 08 • 23:00 | Flavio Cobolli | | - | | Roberto Carballés Baena | 0 | : | 2 |
| Mar 08 • 23:00 | Botic van de Zandschulp |  | - | | Denis Shapovalov | 0 | : | 2 |
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| Mar 08 • 20:00 | Alexander Shevchenko | | - | | Francisco Cerundolo | 0 | : | 1 |
| Mar 08 • 20:00 | Thanasi Kokkinakis | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 08 • 20:00 | Taro Daniel | | - | | Alex De Minaur | 0 | : | 2 |
| Mar 08 • 20:00 | Felix Auger Aliassime | | - | | Constant Lestienne | 2 | : | 0 |
| Mar 08 • 21:30 | Andrey Rublev | | - | | Andy Murray | 2 | : | 0 |
| Mar 08 • 21:30 | Alexander Zverev | | - | | Christopher O'Connell | 2 | : | 0 |
| Mar 08 • 23:00 | Lucas Pouille | | - |  | Stefanos Tsitsipas | 0 | : | 2 |
| Mar 08 • 23:00 | Ben Shelton | | - | | Jakub Mensik | 2 | : | 1 |
| Mar 08 • 23:00 | Fábián Marozsán | | - | | Nicolás Jarry | 2 | : | 1 |
| Mar 09 • 00:30 | Yannick Hanfmann | | - | | Tallon Griekspoor | 0 | : | 2 |
| Mar 09 • 00:30 | Alexander Bublik |  | - | | Shang Juncheng | 2 | : | 0 |
| Mar 09 • 02:00 | Brandon Nakashima | | - | | Jiří Lehečka | 1 | : | 2 |
| Mar 09 • 02:00 | Jan-Lennard Struff | | - | | Borna Ćorić | 2 | : | 1 |
| Mar 09 • 02:00 | Karen Khachanov | | - | | Thiago Seyboth Wild | 0 | : | 2 |
| Mar 09 • 03:00 | Matteo Arnaldi | | - | | Carlos Alcaraz | 1 | : | 2 |
| Mar 09 • 04:30 | Frances Tiafoe | | - | | Dušan Lajović | 2 | : | 0 |
| Mar 09 • 20:00 | Patrick Kypson | | - | | Ugo Humbert | 0 | : | 2 |
| Mar 09 • 20:00 | Cameron Norrie | | - | | Lorenzo Sonego | 2 | : | 0 |
| Mar 09 • 20:00 | Adrian Mannarino | | - | | Tomáš Macháč | 2 | : | 0 |
| Mar 09 • 20:00 | Milos Raonic | | - |  | Holger Rune | 0 | : | 0 |
| Mar 09 • 21:30 | Zhang Zhizhen | | - | | Luca Nardi | 1 | : | 2 |
| Mar 09 • 21:30 | Arthur Fils | | - | | Alejandro Davidovich Fokina | 2 | : | 0 |
| Mar 09 • 21:30 | Alexandre Muller | | - |  | Grigor Dimitrov | 0 | : | 2 |
| Mar 09 • 22:00 | Taylor Harry Fritz | | - | | Alejandro Tabilo | 2 | : | 0 |
| Mar 09 • 23:00 | Roman Safiullin | | - | | Sebastian Korda | 0 | : | 2 |
| Mar 09 • 23:00 | Fabio Fognini | | - | | Sebastián Báez | 0 | : | 2 |
| Mar 09 • 23:00 | Lorenzo Musetti | | - | | Denis Shapovalov | 2 | : | 1 |
| Mar 09 • 23:30 | Novak Djokovic | | - | | Aleksandar Vukic | 2 | : | 1 |
| Mar 10 • 03:00 | Tommy Paul | | - | | Alex Michelsen | 2 | : | 0 |
| Mar 10 • 03:00 | Casper Ruud |  | - | | Lukáš Klein | 2 | : | 0 |
| Mar 10 • 04:30 | Gaël Monfils | | - |  | Hubert Hurkacz | 2 | : | 1 |
| Mar 10 • 05:00 | Daniil Medvedev | | - | | Roberto Carballés Baena | 2 | : | 0 |
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| Mar 10 • 19:00 | Frances Tiafoe | | - | | Stefanos Tsitsipas | 0 | : | 2 |
| Mar 10 • 19:00 | Thiago Seyboth Wild | | - | | Fábián Marozsán | 0 | : | 2 |
| Mar 10 • 20:30 | Alexander Bublik | | - | | Alex De Minaur | 0 | : | 2 |
| Mar 10 • 21:00 | Felix Auger Aliassime | | - | | Carlos Alcaraz | 0 | : | 2 |
| Mar 10 • 22:30 | Jan-Lennard Struff | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 10 • 23:30 | Andrey Rublev | | - | | Jiří Lehečka | 0 | : | 2 |
| Mar 11 • 02:00 | Alexander Zverev | | - | | Tallon Griekspoor | 2 | : | 0 |
| Mar 11 • 04:00 | Ben Shelton | | - | | Francisco Cerundolo | 2 | : | 1 |
| Mar 11 • 19:00 | Cameron Norrie | | - | | Gaël Monfils | 1 | : | 2 |
| Mar 11 • 19:00 | Lorenzo Musetti | | - | | Holger Rune | 0 | : | 2 |
| Mar 11 • 20:30 | Tommy Paul | | - | | Ugo Humbert | 2 | : | 0 |
| Mar 11 • 20:30 | Casper Ruud | | - | | Arthur Fils | 2 | : | 0 |
| Mar 11 • 22:00 | Adrian Mannarino | | - | | Grigor Dimitrov | 0 | : | 2 |
| Mar 11 • 22:00 | Taylor Harry Fritz | | - | | Sebastián Báez | 2 | : | 0 |
| Mar 12 • 02:00 | Novak Djokovic | | - | | Luca Nardi | 1 | : | 2 |
| Mar 12 • 03:30 | Daniil Medvedev | | - | | Sebastian Korda | 2 | : | 1 |
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| Mar 12 • 19:00 | Jiří Lehečka | | - | | Stefanos Tsitsipas | 2 | : | 0 |
| Mar 12 • 21:00 | Fábián Marozsán | | - | | Carlos Alcaraz | 0 | : | 2 |
| Mar 12 • 22:15 | Alexander Zverev | | - | | Alex De Minaur | 2 | : | 1 |
| Mar 13 • 02:00 | Ben Shelton | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 13 • 19:00 | Casper Ruud | | - | | Gaël Monfils | 2 | : | 1 |
| Mar 13 • 20:30 | Luca Nardi | | - | | Tommy Paul | 0 | : | 2 |
| Mar 13 • 22:00 | Daniil Medvedev | | - | | Grigor Dimitrov | 2 | : | 0 |
| Mar 14 • 02:00 | Taylor Harry Fritz | | - | | Holger Rune | 1 | : | 2 |
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| Mar 14 • 19:00 | Jiří Lehečka | | - | | Jannik Sinner | 0 | : | 2 |
| Mar 14 • 20:30 | Tommy Paul | | - | | Casper Ruud | 2 | : | 1 |
| Mar 14 • 23:00 | Alexander Zverev | | - | | Carlos Alcaraz | 0 | : | 2 |
| Mar 15 • 02:00 | Daniil Medvedev | | - | | Holger Rune | 2 | : | 0 |
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| Mar 16 • 21:30 | Jannik Sinner | | - | | Carlos Alcaraz | 1 | : | 2 |
| Mar 16 • 22:50 | Tommy Paul | | - | | Daniil Medvedev | 1 | : | 2 |
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| Mar 17 • 22:05 | Daniil Medvedev | | - | | Carlos Alcaraz | 0 | : | 2 |
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