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| Group B |
Oct 22 • 16:00 | Victoria Azarenka |  | - |  | Sara Errani | 2 | : | 0 |
| Group A |
Oct 22 • 18:45 | Serena Williams |  | - |  | Angelique Kerber | 2 | : | 0 |
| Group A |
Oct 22 • 20:20 | Agnieszka Radwanska |  | - |  | Petra Kvitova | 0 | : | 2 |
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| Group B |
Oct 23 • 16:05 | Li Na |  | - | | Sara Errani | 2 | : | 0 |
| Group B |
Oct 23 • 17:30 | Victoria Azarenka | | - |  | Jelena Jankovic | 0 | : | 2 |
| Group A |
Oct 23 • 19:00 | Serena Williams | | - | | Agnieszka Radwanska | 2 | : | 0 |
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| Group B |
Oct 24 • 16:00 | Li Na | | - | | Jelena Jankovic | 2 | : | 1 |
| Group A |
Oct 24 • 18:00 | Agnieszka Radwanska | | - | | Angelique Kerber | 0 | : | 2 |
| Group A |
Oct 24 • 20:30 | Serena Williams | | - | | Petra Kvitova | 2 | : | 0 |
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| Group B |
Oct 25 • 16:00 | Victoria Azarenka | | - | | Li Na | 0 | : | 2 |
| Group A |
Oct 25 • 17:30 | Petra Kvitova | | - | | Angelique Kerber | 2 | : | 1 |
| Group B |
Oct 25 • 19:10 | Sara Errani | | - | | Jelena Jankovic | 2 | : | 0 |
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| Oct 26 • 14:00 | Li Na | | - | | Petra Kvitova | 2 | : | 0 |
| Oct 26 • 15:30 | Serena Williams | | - | | Jelena Jankovic | 2 | : | 1 |
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| Oct 27 • 16:00 | Li Na | | - | | Serena Williams | 1 | : | 2 |
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