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| May 11 • 11:00 | Robin Haase |  | - |  | Jérémy Chardy | 0 | : | 2 |
| May 11 • 12:00 | Pablo Andújar |  | - |  | Radek Štěpánek | 1 | : | 2 |
| May 11 • 12:30 | Mikhail Kukushkin |  | - |  | João Sousa | 2 | : | 1 |
| May 11 • 15:05 | John Isner |  | - |  | Jürgen Melzer | 0 | : | 2 |
| May 11 • 15:40 | Jerzy Janowicz |  | - |  | Philipp Kohlschreiber | 1 | : | 2 |
| May 11 • 16:15 | Tommy Robredo | | - |  | Juan Mónaco | 2 | : | 0 |
| May 12 • 11:00 | Marcel Granollers | | - | | Feliciano López | 2 | : | 0 |
| May 12 • 11:00 | Federico Delbonis | | - |  | Ivan Dodig | 0 | : | 2 |
| May 12 • 12:00 | Grigor Dimitrov |  | - | | Édouard Roger-Vasselin | 2 | : | 1 |
| May 12 • 12:30 | Pablo Carreño Busta | | - | | Ivo Karlović | 1 | : | 2 |
| May 12 • 12:30 | Simone Bolelli |  | - | | Stefano Travaglia | 2 | : | 1 |
| May 12 • 14:00 | Paolo Lorenzi | | - | | Pere Riba | 0 | : | 2 |
| May 12 • 16:00 | Alejandro González |  | - | | Stéphane Robert | 1 | : | 2 |
| May 12 • 16:15 | Gilles Simon | | - | | Filippo Volandri | 2 | : | 0 |
| May 12 • 16:30 | Fabio Fognini | | - | | Lukáš Rosol | 0 | : | 2 |
| May 12 • 19:00 | Nicolas Mahut | | - |  | Mikhail Youzhny | 0 | : | 2 |
| May 12 • 21:00 | Alexandr Dolgopolov |  | - | | Jo-Wilfried Tsonga | 0 | : | 2 |
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| May 13 • 11:00 | Andrey Golubev | | - | | Fernando Verdasco | 2 | : | 0 |
| May 13 • 11:00 | Santiago Giraldo | | - | | Marin Čilić | 0 | : | 1 |
| May 13 • 11:00 | Kevin Anderson |  | - |  | Vasek Pospisil | 2 | : | 0 |
| May 13 • 12:30 | Andreas Seppi | | - | | Tommy Haas | 1 | : | 2 |
| May 13 • 12:30 | Dmitry Tursunov | | - | | Roberto Bautista-Agut | 2 | : | 0 |
| May 13 • 12:30 | Ernests Gulbis |  | - | | Alejandro Falla | 1 | : | 0 |
| May 13 • 14:00 | Marco Cecchinato | | - | | Igor Sijsling | 0 | : | 2 |
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| May 13 • 13:30 | Radek Štěpánek | | - |  | Novak Djokovic | 0 | : | 2 |
| May 13 • 15:00 | Stanislas Wawrinka |  | - | | Pere Riba | 2 | : | 0 |
| May 13 • 19:25 | Tommy Robredo | | - | | Philipp Kohlschreiber | 0 | : | 2 |
| May 13 • 19:30 | Milos Raonic | | - | | Simone Bolelli | 2 | : | 0 |
| May 13 • 20:00 | David Ferrer | | - | | Mikhail Kukushkin | 2 | : | 0 |
| May 14 • 11:00 | Jürgen Melzer | | - | | Marin Čilić | 2 | : | 1 |
| May 14 • 12:00 | Marcel Granollers | | - |  | Andy Murray | 0 | : | 2 |
| May 14 • 12:30 | Kevin Anderson | | - | | Jo-Wilfried Tsonga | 0 | : | 2 |
| May 14 • 12:30 | Lukáš Rosol | | - | | Ivan Dodig | 0 | : | 2 |
| May 14 • 13:30 | Jérémy Chardy | | - | | Roger Federer | 2 | : | 1 |
| May 14 • 14:00 | Andrey Golubev | | - | | Mikhail Youzhny | 0 | : | 1 |
| May 14 • 14:00 | Igor Sijsling | | - | | Tommy Haas | 0 | : | 2 |
| May 14 • 15:30 | Stéphane Robert | | - | | Ernests Gulbis | 1 | : | 2 |
| May 14 • 16:50 | Grigor Dimitrov | | - | | Ivo Karlović | 2 | : | 0 |
| May 14 • 19:30 | Rafael Nadal | | - | | Gilles Simon | 2 | : | 1 |
| May 14 • 19:30 | Dmitry Tursunov | | - | | Tomáš Berdych | 0 | : | 2 |
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| May 15 • 12:00 | Stanislas Wawrinka | | - | | Tommy Haas | 1 | : | 2 |
| May 15 • 12:00 | Milos Raonic | | - | | Jo-Wilfried Tsonga | 2 | : | 0 |
| May 15 • 13:30 | Jürgen Melzer | | - | | Andy Murray | 0 | : | 2 |
| May 15 • 14:30 | Ivan Dodig | | - | | Jérémy Chardy | 0 | : | 2 |
| May 15 • 15:30 | Grigor Dimitrov | | - | | Tomáš Berdych | 2 | : | 1 |
| May 15 • 16:00 | Rafael Nadal | | - | | Mikhail Youzhny | 2 | : | 1 |
| May 15 • 19:00 | David Ferrer | | - | | Ernests Gulbis | 2 | : | 0 |
| May 15 • 21:00 | Philipp Kohlschreiber | | - | | Novak Djokovic | 1 | : | 2 |
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| May 16 • 12:00 | Milos Raonic | | - | | Jérémy Chardy | 2 | : | 1 |
| May 16 • 14:00 | Tommy Haas | | - | | Grigor Dimitrov | 0 | : | 1 |
| May 16 • 16:00 | David Ferrer | | - | | Novak Djokovic | 1 | : | 2 |
| May 16 • 21:00 | Rafael Nadal | | - | | Andy Murray | 2 | : | 1 |
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| May 17 • 14:00 | Milos Raonic | | - | | Novak Djokovic | 1 | : | 2 |
| May 17 • 20:00 | Rafael Nadal | | - | | Grigor Dimitrov | 2 | : | 0 |
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| May 18 • 16:00 | Rafael Nadal | | - | | Novak Djokovic | 1 | : | 2 |
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